| MSDS | : | CHLOROBEN DE | | CAS | : | 7647-01-0 | | NAME | : | ing 6:immed med attn. md note:corrosive. if ingested,
ing 7: neutralize w/baking soda/washing soda.pick up
ing 8:earth.pump into salvage tank.flush area w/ h*2o to
ing 9:in marked contrs for recovery/disp.do not get h*2o
ing 10: sewers, waterways & watersheds. reportable qty:5000
hndlg/stor prec:objects.prot contrs from dam/breakage.use
ing 12:where hydrogen might be generated.store away from
ing 13:or other chloride resistant matls. hygiene
hydrogen chloride. ld50 rat oral 700 mg/kg, rabbit dermal
matl to avoid:amines,carbonates, & other alkaline matls.
ing 2:oleum, propiolactone, sulfuric acid, vinyl acetate,
ing 3: carbon tetrachloride. haz decomp prod: prod decomp
ing 4: give anything to an unconcious person. call md
ing 5:artif resp, mouth to mouth pref. if brthg dfclt:give
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===================== Product Identification =====================
MSDS NAME:CHLOROBEN DE
NIIN:00N012590
MSDS Number: BQPJT
=== Responsible Party ===
Company:CHLOROBEN CHEMICAL CORPORATION
Address:1035 BELLEVILLE TURNPIKE
City:KEARNY
State:NJ
ZIP:07032
Country:US
Info Phone Num:201-997-1700
Emergency Phone Num:201-997-1700 (8AM-5PM);302-834-4536
Preparer's Name:NICHOLAS A STUFANO
CAGE:HO771
=== Contractor Identification ===
Company:CHLOROBEN CHEMICAL CORPORATION
Address:1035 BELLEVILLE TURNPIKE
Box:City:KEARNY
State:NJ
ZIP:07032
Country:US
Phone:201-997-1700
CAGE:HO771
Company:CLOROBEN CHEMICAL CORP
Address:1035 BELLEVILLE TURNPIKE
Box:City:KEARNY
State:NJ
ZIP:07032-4410
Country:US
Phone:201-997-1700
CAGE:58101
============= Composition/Information on Ingredients =============
Name:ING 6:IMMED MED ATTN. MD NOTE:CORROSIVE. IF INGESTED,
GASTRIC LAVAGE W/ EXTREME CAUTN. SPILL PROC:THEN (SEE ING 8)
RTECS #:9999999ZZ
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 7: NEUTRALIZE W/BAKING SODA/WASHING SODA.PICK UP
NEUTRAL WASTE FOR PROPER DISP.LG SPILLS:DIKE SPILL W/SAND/ (ING 9)
RTECS #:9999999ZZ
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 8:EARTH.PUMP INTO SALVAGE TANK.FLUSH AREA W/ H*2O TO
HOLDING AREA.NEUT W/ LIME/SODA ASH.PLACE MATL (SEE ING 10)
RTECS #:9999999ZZ
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 9:IN MARKED CONTRS FOR RECOVERY/DISP.DO NOT GET H*2O
INSIDE CONTRS.NOTIFY APPROP AUTH.KEEP OUT OF (SEE ING 11)
RTECS #:9999999ZZ
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 10: SEWERS, WATERWAYS & WATERSHEDS. REPORTABLE QTY:5000
LBS. WASTE DISP METH:PRIOR TO DISP.
RTECS #:9999999ZZ
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:HNDLG/STOR PREC:OBJECTS.PROT CONTRS FROM DAM/BREAKAGE.USE
ONLY NON-SPK TOOLS IN AREAS AROUND METAL OBJECTS (ING 13)
RTECS #:9999999ZZ
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 12:WHERE HYDROGEN MIGHT BE GENERATED.STORE AWAY FROM
CHILDREN.OTHER PROT EQUIP:FIBERGLASS OR OTHER HYDROGEN (ING 14)
RTECS #:9999999ZZ
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 13:OR OTHER CHLORIDE RESISTANT MATLS. HYGIENE
PRACT:BEFORE REUSE. DESTROY FOOTWEAR THAT CANNOT BE DECONTAMINATED.
RTECS #:9999999ZZ
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:HYDROGEN CHLORIDE. LD50 RAT ORAL 700 MG/KG, RABBIT DERMAL
>5010 MG/KG; LC50 RAT INHAL 3124 PPM/1 HR.
CAS:7647-01-0
RTECS #:MW4025000
Fraction by Wt: 32%
Other REC Limits:N/K
OSHA PEL:5 PPM CEILING
ACGIH TLV:5 PPM CEILING
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:MATL TO AVOID:AMINES,CARBONATES, & OTHER ALKALINE MATLS.
MERCURIC SULFATE, ACETIC ANHYDRIDE, CHLOROSULFONIC ACID,(ING 3)
RTECS #:9999999ZZ
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 2:OLEUM, PROPIOLACTONE, SULFURIC ACID, VINYL ACETATE,
CALCIUM PHOSPHIDE, SILVER PERCHLORATE, FORMALDEHYDE, (ING 4)
RTECS #:9999999ZZ
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 3: CARBON TETRACHLORIDE. HAZ DECOMP PROD: PROD DECOMP
INTO HYDROGEN AND CHLORINE. FIRST AID PROC: NEVER (ING 5)
RTECS #:9999999ZZ
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 4: GIVE ANYTHING TO AN UNCONCIOUS PERSON. CALL MD
IMMED. INHAL:REMOVE TO FRESH AIR. BREATHING STOPPED: GIVE (ING 6)
RTECS #:9999999ZZ
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ING 5:ARTIF RESP, MOUTH TO MOUTH PREF. IF BRTHG DFCLT:GIVE
O*2. KEEP AFFECTED PERSON WARM & AT REST. GET (SEE ING 7)
RTECS #:9999999ZZ
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:N/K
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CORROSIVE.RPTD CONTACT W/DILUTE
SOLN/CONC VAPOR MAY LEAD TO DERM.CHRONIC EXPOSURE TO LOW
CONCENTRATIONS CAUSES DISCOLORATION AND EROSION OF TEETH, SKIN
TENDERNESS, NOSE & GUM BLEEDING.MAY CAUSE PERMAN ENT VISUAL
IMPAIRMENT.CAUSES INFLAM/ULCERS OF NOSE,THROAT.OVEREXPOS MAY RESULT
IN LARYNGITIS,BRONCH,PULM EDEMA & DEATH.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:SEVERE IRRITATION, BURNS, POSSIBLE
BLINDNESS. SKIN:SEVERE BURNS. INGEST:SEVERE BURNS OF MUCOUS
MEMBRANE, MOUTH, LIP DISCOLORATION, PAIN, DIFFICULTY SWALLOWING,
THIRST, NAUSEA, VOMIT, DIARRHEA. IN HAL:SEVERE UPPER RESPIRATORY
IRRITATIONW/COUGHING, BURNING, CHOKING.
Medical Cond Aggravated by Exposure:DIGESTIVE DISORDERS AND RESPIRATORY
CONDITIONS SUCH AS ASTHMA, CHRONIC BRONCHITIS AND EMPHYSEMA MAY
WORSEN AND FLARE UP. PEOPLE WITH SENSITIVE SKIN MAY SUFFER
PROLONGED IRRITATION.
======================= First Aid Measures =======================
Eyes:IMMED IRRIGATE W/RUNNING H*2O FOR @ LEAST 15 MIN.HOLD
LIDS APART.GET MED ATTN IMMED.SKIN:IMMED FLUSH W/LG AMTS OF H*2O
FOR @ LEAST 15 MIN.WASH W/SOAP, H*2O.USE SFTY SHOWER IMMED IF BODY,
CLTHG CO NTAM. COVER AFFECTED AREA W/MOIST MILK OF MAGNESIA, BAKING
SODA.GET IMMED MED ATTN. INGEST:DO NOT INDUCE VOM/GIVE
BICARBONATE.FLUSH MOUTH W/LG AMTS OF H*2O.DRINK @ LEAST 3 GLASSES
OF H*2O/MILK.(ING 4)
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:USE WATER SPRAY OR FOAM AS SUITABLE FOR SURROUNDING
FIRE. DO NOT GET WATER INSIDE CONTAINER.MATL ITSELF IS
NONFLAMMABLE.
Fire Fighting Procedures:FIREFIGHTERS EXPOS TO HCL VAPORS SHOULD WEAR
NIOSH/MSHA APPRVD SCBA BRTHG APPARATUS AND FULL PROT ACID-RESISTANT
CLTHG. THOROUGHLY DECONTAMINATE EQUIP AFTER USE
Unusual Fire/Explosion Hazard:PROD IS NONFLAMMABLE. HOWEVER WHEN PROD
COMES IN CONT W/MOST METALS, HYDROGEN, A HIGHLY FLAM & EXPLO GAS
MAY BE GENERATED. PROD WILL REACT W/VARIOUS (SEE SUPP)
================== Accidental Release Measures ==================
Spill Release Procedures:ELIM ALL IGNIT SOURCES. KEEP UPWIND. SHUT OFF
LEAK IF POSS W/O RISK. WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT
CLOTHING INCLUDING BOOTS. SMALL SPILLS:IMMED FLUSH AREA W/H*2O. IF
DRAINAGE NOT AVAIL, DILU TE WITH 2 TO 5 TIMES ITS VOLUME OF WATER.
(ING 7)
Neutralizing Agent:BAKING SODA OR WASHING SODA.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTR CLSD,OUT OF SUN,IN CLEAN,
COOL,WELL-VENTED AREA W/ ACID-RESIST FLOOR & APPRVD DRAINAGE.KEEP
FROM OTHER CHEM,COPPER/CHROMIUM PLATED (ING 12)
Other Precautions:DO NOT USE PROD BEFORE/AFTER/WITH ANY OTHER CHEM OR
CHEM PROD.VIOLENT RXN MAY OCCUR.DO NOT TRANSFER PROD TO ANY OTHER
CONTR.DO NOT GET IN EYES OR ON SKIN/CLTHG.DO NOT TAKE
INTERNALLY.AVOID BREATHING V APORS.DO NOT MIX W/ANY CHEM (SUP DATA)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPRVD FULL FACE EQUIP WHEN
AIRBORNE EXPOSURE LIMITS MAY BE EXCEEDED.CONSULT RESPIRATOR
MANUFACTURER TO DETERMINE APROPRIATE TYPE EQUIPMENT FOR GIVEN
APPLICATION.
Ventilation:LOC EXHST VENT TO KEEP AIR CONC BELOW PERMISSIBLE AIRBORNE
EXPOS LIMITS.SEE NFPA STD 91 FOR DISGN OF EXHST SYS.
Protective Gloves:IMPERVIOUS GLOVES
Eye Protection:CHEM SAFETY GOG,FULL LENGTH FACESHIELDS.
Other Protective Equipment:IMPERVIOUS PROT CLTHG/CHEM SFTY
BOOTS.PROVIDE SFTY SHOWER/EYE BATH. USE ONLY
PVC/POLYETHYLENE/POLYPROPYLENE/(SEE ING 13)
Work Hygienic Practices:DO NOT WEAR CONT LENSES. DO NOT GET IN EYES, ON
SKIN/CLTHG. WASH THORO AFTER HNDLG. WASH CONTAM PROT CLTHG (SEE ING
14)
Supplemental Safety and Health
RTE OF ENTRY:INGEST .MP:LIQ TO -63F,-52.78C.VP:26 MMHG @ 25C,77F.EXPLO
HAZ:MATLS TO GENERATE HEAT & LG QTIES OF DENSE,WHITE
FUMES.IMPROPERLY COOLED CONTR MAY EXPLODE IN HEAT OF FIRE. OTHER
PREC: OR CHEM PRODUCT.DO NOT REUSE CONTAINER.POISON! MAY BE FATAL
IF SWALLOWED/INHALED. CAUSES SEV BURNS TO ALL HUMAN TISSUE.
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:182F,83.3C
Melt/Freeze Pt:M.P/F.P Text:SEE SUPP
Decomp Temp:Decomp Text:N/K
Vapor Pres:SEE SUPP
Vapor Density:>1 (AIR=1)
Spec Gravity:1.16 (WATER=1)
Evaporation Rate & Reference:N/K
Solubility in Water:COMPLETE
Appearance and Odor:YELLOW, NONVISCOUS LIQUID WITH SHARP, PUNGENT,
SUFFOCATING ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
METALS:ZINC, ALUMINUM, MAGNESIUM, IRON,STRONG OXIDIZERS. ALKALI &
ALKALINE SUBSTANCES: METAL OXIDES, HYDROXIDES, (ING 2)
Stability Condition to Avoid:HEAT
Hazardous Decomposition Products:FLAM HYDROGEN GAS PRODUCED BY RXN
W/MOST METAL.CHLORINE GAS MAY BE RELEASED BY MIXING W/STRONG
OXIDIZER.@ HI TEMP,(ING4)
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISP MUST BE IAW ALL LOC, STATE,FED REGS
.PROD,CONTR CAN BECOME HAZ WASTES. RCRA NUMBER:D002. DISP OF CONTAM
SAWDUST, VERMICULITE/POROUS SURF IN APPRVD HAZ WASTE MANAGEMENT
FACILITY.DO NOT REUSE CONTR.TRIPLE RINSE EMPTY CONTR, PUNCTURE
(ING 11)
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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