===================== Product Identification =====================
MSDS NAME:REGULAR UNLEADED GASOLINE
NIIN:01-207-7039
MSDS Number: BQQHT
=== Responsible Party ===
Company:DIAMOND SHAMROCK REFINING AND MARKETING CO
Address:9830 COLONNADE BLVD
Box:696000
City:SAN ANTONIO
State:TX
ZIP:78269-6000
Country:US
Info Phone Num:512-641-8601
Emergency Phone Num:512-641-8800
CAGE:3P045
=== Contractor Identification ===
Company:DIAMOND SHAMROCK REFINING AND MARKETING CO
Address:9830 COLONNADE BLVD
Box:696000
City:SAN ANTONIO
State:TX
ZIP:78269-6000
Country:US
Phone:210-641-8601
CAGE:3P045
============= Composition/Information on Ingredients =============
Name:GASOLINE ( PERCENTAGE INCLUDES INGREDIENT #1 TO #11)
CAS:8006-61-9
RTECS #:LX3300000
Fraction by Wt: 100%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:300 PPM/500 STEL
ACGIH TLV:300 PPM/500STEL;9293
Name:BUTANE
CAS:106-97-8
RTECS #:EJ4200000
Fraction by Wt: <9%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:800 PPM
ACGIH TLV:800 PPM; 9293
Name:PENTANE
CAS:109-66-0
RTECS #:RZ9450000
Fraction by Wt: <2%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM/750 STEL
ACGIH TLV:600 PPM/750STEL;9293
Name:HEXANE (N-HEXANE)
CAS:110-54-3
RTECS #:MN9275000
Fraction by Wt: <3%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:500 PPM
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:HEXANE ISOMERS ( OTHER THAN N-HEXANE )
Fraction by Wt: <6.5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:500 PPM
ACGIH TLV:500 PPM
Name:BENZENE (SARA III)
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: <3.5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1PPM/5STEL;1910.1028
ACGIH TLV:10 PPM; A2; 9293
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: <9%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:ETHYL BENZENE (SARA III)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: <2%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM/125 STEL
ACGIH TLV:100 PPM/125STEL 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:XYLENES (O-,M-,P- ISOMERS) (SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: <8%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:TRIMETHYL BENZENE (SARA III)
CAS:25551-13-7
RTECS #:DC3220000
Fraction by Wt: <3%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:25 PPM
ACGIH TLV:25 PPM; 9293
Name:METHYL TERT-BUTYL ETHER (SARA III)
CAS:1634-04-4
RTECS #:KN5250000
Fraction by Wt: 0-11%
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE-INHALATION:IRRITATION OF UPPER
RESPIRATORY TRACT, CENTRAL NERVOUS SYSTEM DEPRESSION.
EYE:IRRITATION. SKIN:DEFATING, IRRITATION. INGESTION:GI
DISTURBANCES, CNS DEPRESSION. CHRONIC: DERMATITIS, PN EUMOTITIS,
POLYNEUROPATHY, PULMONARY EDEMA, AND KIDNEY DAMAGE.
Explanation of Carcinogenicity:CONTAINS B [71-43-2] WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Effects of Overexposure:COUGHING, DIFFICULTY IN BREATHING, NAUSEA,
VOMTING, FATIGUE, DIZZINESS, HEADACHES, UNCONSCIOUSNESS, AND EYE
IRRITATION, DRY SKIN.
Medical Cond Aggravated by Exposure:PERSONS WITH A SKIN AND PULMONARY
DISORDERS SHOULD USE CAUTION WHEN HANDLING OR USING THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER.
GET MEDICAL ATTENTION IF IRRITATION PERSISTS. INHALATION:REMOVE TO
FRESH AIR & RESTORE BREATHING IF NECESSARY. GET MEDICAL ATTENTION.
EYE: IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION. INGESTION: GET IMMEDIATE
MEDICAL ATTENTION. DO NOT INDUCE VOMITING. NOTHING BY MOUTH IF
UNCONSCIOUS.
===================== Fire Fighting Measures =====================
Flash Point:<-40F,<-40C
Autoignition Temp:Autoignition Temp Text:495F
Lower Limits:1.0%
Upper Limits:8.0%
Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. USE
WATER FOG TO COOL SRROUNDING CONTAINERS.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL
FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:CONTAINERS WILL EXPLODE IN FIRE. VAPORS
HEAVIER THAN AIR AND MAY TRAVEL A CONSIDERABLE DISTANCE TO SOURCE
OF IGNITION AND FLASH BACK.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE SOURCES OF IGNITION & WEAR PROTECTIVE
EQUIPMENT. MINOR: ABSORB MATERIAL WITH CLAY, VERMICULITE, OR
SIMILAR ABSORBENT MATERIAL. PLACE IN DISPOSAL CONTAINERS. MAJOR:
DIKE & CONTAIN SPILL. SHUT OF F LEAKS. REMOVE LIQUID BY VACUUM OR
ABSORBENT.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, VENTILATED WORK AREA.
KEEP CONTAINERS CLOSED WHEN NOT IN USE. FLAMMABLE LIQUID; EMPTY
CONTAINERS CAN BE HAZARDOUS.
Other Precautions:THE SELECTION OF PERSONAL PROTECTIVE EQUIPMENT SHOULD
BE MADE BY THE MATERIAL USER BASED ON THE PARTICULAR CONDITIONS
WHERE THE MATERIAL IS TO BE USED TOGETHER WITH INFORMATION
CONTAINED IN THIS MSDS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED RESPIRATOR. AIR-SUPPLIED OR
FILTERING TYPE WITH ORGANIC VAPOR CARTRIDGES ARE RECOMMENDED.
Ventilation:LOCAL AND MECHANICAL EXHAUST RECOMMENDED. AVOID OPEN
ELECTRICAL SOURCES NEAR PRODUCT VAPOR AREAS.
Protective Gloves:NEOPRENE, NITRILE, OR POLYVINYL ALCOHOL
Eye Protection:USE CHEMICAL SAFETY GOGGLES & FACESHIELD
Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER.
Work Hygienic Practices:DO NOT TAKE INTERNALLY. AVOID SKIN CONTACT.
WASH SKIN AFTER USING PRODUCT. DO NOT EAT, DRINK OR SMOKE IN WORK
AREA.
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:F1
Boiling Pt:B.P. Text:80.0F,26.7C
Vapor Pres:9-15 PSI
Vapor Density:3-4
Spec Gravity:O.68-0.76
Evaporation Rate & Reference:<1 (ETHER=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORED LIQUID WITH PUNGENT GASOLINE ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND
OTHER HYDROCARBON COMPOUNDS DURING COMBUSTION.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE MAY BE BURNED IN AN APPROVED INCINERATOR
OR DISPOSED OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND
FEDERAL LAWS AND REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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