===================== Product Identification =====================
MSDS NAME:CALCO MID-GRADE UNLEADED GASOLINE
NIIN:01-282-2844
MSDS Number: BQQJG
=== Responsible Party ===
Company:CHEVRON ENVIRONMENTAL HEALTH CENTER INC.
Address:15299 SAN PABLO AVE.
Box:4054
City:RICHMOND
State:CA
ZIP:94804-0054
Country:US
Info Phone Num:415-233-3737
Emergency Phone Num:415-233-3737
CAGE:0AHD1
=== Contractor Identification ===
Company:CHEVRON ENVIRONMENTAL HEALTH CENTER INC
Address:15299 SAN PABLO AVE
Box:4054
City:RICHMOND
State:CA
ZIP:94804
Country:US
Phone:800-582-3835
CAGE:0AHD1
============= Composition/Information on Ingredients =============
Name:GASOLINE (INCLUDES THE FOLLOWING INGREDIENTS)
CAS:8006-61-9
RTECS #:LX3300000
Fraction by Wt: 100%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:300 PPM/500 STEL
ACGIH TLV:300 PPM/500STEL;9293
Name:BENZENE (SARA III)
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: < 4.9%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1PPM/5STEL;1910.1028
ACGIH TLV:10 PPM; A2; 9293
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:ETHYL BENZENE (SARA III)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: < 2.4%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM/125 STEL
ACGIH TLV:100 PPM/125STEL 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:P-XYLENE (P-DIMETHYLBENZENE) (SARA III)
CAS:106-42-3
RTECS #:ZE2625000
Fraction by Wt: < 2.3%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:M-XYLENE (M-DIMETHYLBENZENE) (SARA III)
CAS:108-38-3
RTECS #:ZE2275000
Fraction by Wt: < 6.3%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/15OSTEL;9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:O-XYLENE (O-DIMETHYLBENZENE) (SARA III)
CAS:95-47-6
RTECS #:ZE2450000
Fraction by Wt: < 3.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: < 9.5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:HEXANE (N-HEXANE)
CAS:110-54-3
RTECS #:MN9275000
Fraction by Wt: < 5.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:500 PPM
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:CYCLOHEXANE (SARA III)
CAS:110-82-7
RTECS #:GU6300000
Fraction by Wt: < 2.4%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:300 PPM
ACGIH TLV:300 PPM, 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:METHYL TERT-BUTYL ETHER (SARA III)
CAS:1634-04-4
RTECS #:KN5250000
Fraction by Wt: < 15.0%
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:ETHYL ALCOHOL (ETHANOL)
CAS:64-17-5
RTECS #:KQ6300000
Fraction by Wt: < 10.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM; 9293
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 ORAL (RATS) > 5 ML/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYE IRRITATION, VISION IMPAIRMENT,
SKIN IRRITATION, NERVOUS SYSTEM DISTURBANCES, COMA, DEATH,
PULMONARY EDEMA, BRONCHITIS, ASPIRATION HAZARD.
Explanation of Carcinogenicity:CONTAINS B [71-43-2] WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Effects of Overexposure:EYE PAIN/SWELLING/REDNESS, BLURRED VISION, SKIN
CRACKING/DEFATTING/DRYNESS, HEADACHE, DIZZINESS, LOSS OF APPETITE,
WEAKNESS, LOSS OF COORDINATION, LOSS OF CONSCIOUSNESS, CONVULSIONS,
DELIRIUM, HALLUCI NATIONS, LUNG INJURY.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
Eyes: IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES WHILE
HOLDING EYELIDS OPEN. IF IRRITATION PERSISTS, SEE PHYSICIAN. SKIN:
WASH WITH SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. IF
SYMPTOMS DEVELO P, SEE PHYSICIAN. INGESTION: GIVE WATEROR MILK TO
DRINK. DO NOT INDUCE VOMITING. CONTACT PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:<-49F,<-45C
Lower Limits:1.4 %
Upper Limits:7.6 %
Extinguishing Media:FIRE FIGHTING FOAM, ALCOHOL RESISTANT TYPE (AR)
AFFF, CARBON DIOXIDE, DRY CHEMICAL
Fire Fighting Procedures:EXTREME FIRE HAZARD! DO NOT ENTER ANY ENCLOSED
OR CONFINED FIRE SPACE WITHOUT PROPER PROTECTIVE EQUIPMENT. THIS
MAY INCLUDE SCBA AND FULL PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard:LIQUID EVAPORATES QUICKLY EVEN AT LOW
TEMPERATURES AND FORMS VAPRS WHICH CAN CATCH FIRE AND BURN WITH
EXPLOSIVE VIOLENCE. VAPORS MAY TRAVEL TO REMOTE IGNITIONS
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. USE SORBENT
MATERIALS OR PUMPING. REMOVE CONTAMINATED SOIL WHERE FEASIBLE.
RELEASES OF PRODUCT SHOULD BE PREVENTED FROM CONTAMINATING SOIL AND
WATER AND FROM ENTERING D RAINAGE AND SEWER SYSTEMS. REPORT SPILLS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT USE OR STORE NEAR FLAME, SPARKS
OR HOT SURFACES. USE ONLY IN WELL VENTILATED AREA. KEEP CONTAINER
CLOSED. DO NOT TRANSFER LIQUID TO UNLABELED.
Other Precautions:DO NOT WELD, HEAT OR DRILL CONTAINER. REPLACE CAP OR
BUNG. EMPTIED CONTAINER STILL CONTAINS HAZARDOUS OR EXPLOSIVE VAPOR
OR LIQUID. USE ONLY AS A MOTOR FUEL. DO NOT USE FOR CLEANING,
PRESSURE APPLIANC E FUEL OR ANY OTHER SUCH USE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT NORMALLY REQUIRED. IF OPERATING CONDITIONS
CREATE AIRBORNE CONCENTRATIONS WHICH EXCEED THE RECOMMENDED
EXPOSURE STANDARDS, USE AN APPROVED RESPIRATOR. REFER TO OSHA
BENZENE STANDARD TO DETERMINE T YPE OF RESPIRATOR.
Ventilation:USE THIS MATERIAL ONLY IN WELL VENTILATED AREAS.
Protective Gloves:NOT NORMALLY REQUIRED.
Eye Protection:CHEMICAL GOGGLES
Other Protective Equipment:AVOID FREQUENTLY REPEATED SKIN CONTACT BY
WEARING PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT
AND BEFORE EATING DRINKING OR SMOKING.
Supplemental Safety and Health
NOTE TO PHYSICIAN: INGESTION OF THIS PRODUCT OR SUBSEQUENT VOMITING CAN
RESULT IN ASPIRATION OF LIGHT HYDROCARBON LIQUID WHICH CAN CAUSE
PNEUMONITIS.
================== Physical/Chemical Properties ==================
HCC:F1
Boiling Pt:B.P. Text:77.0F,25.0C
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Pres:5-15 PSI
Vapor Density:3-4
Spec Gravity:0.7 - 0.8
Viscosity:NOT GIVEN
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:NEGLIGIBLE
Appearance and Odor:ORANGE TO BRONZE LIQUID, HYDROCARBON ODOR
Percent Volatiles by Volume:99+
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, SUCH AS CHLORATES, NITRATES, PEROXIDES, ETC.
Stability Condition to Avoid:SPARKS, STATIC ELECTRICITY, OPEN FLAMES
Hazardous Decomposition Products:CARBON DIOXIDE, WATER VAPOR, CARBON
MONOXIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR
LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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