LD50 LC50 Mixture:LD100 (ORAL,RAT): 464 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:MAY BE FATAL IF INHALED. HARMFUL
IF SWALLOWED. MAY BE HARMFUL IF ABSORBED THROUGH SKIN. MATERIAL IS
EXTREMELY DESTRUCTIVE TO TISSUE OF MUCOUS MEMBRANES AND UPPER
RESPIRATORY TRACT, EYES AND SKIN . INHALATION MAY BE FATAL AS A
RESULT OF SPASM, INFLAMMATION AND EDEMA OF LARYNX AND BRONCHI,
CHEMICAL (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: PNEUMONITIS AND PULMONARY EDEMA.
SYMPTOMS OF EXPOSURE MAY INCLUDE BURNING SENSATION, COUGHING,
WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND
VOMITING. TO THE BEST OF OUR KN OWLEDGE, THE CHEMICAL, PHYSICAL,
AND TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYE: IMMED FLUSH W/COPIOUS AMTS OF WATER FOR AT LST 15 MINS.
ASSURE ADEQ FLUSHING BY SEPARATING EYELIDS W/FINGERS. SEEK MED
ADVICE.SKIN: IMMED FLUSH W/COPIOUS AMTS OF WATER FOR AT LST 15 MINS
WHILE RE MOVING CONTAMD CLTHG & SHOES. WASH CONTAMD CLTHG BEFORE
REUSE. DISCARD CONTAMD SHOES. INHAL: REMOVE TO FRESH AIR. IF NOT
BRTHG GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. INGEST: WASH
OUT (SUPDAT)
===================== Fire Fighting Measures =====================
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE
FOAM. DO NOT USE WATER.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
Spill Release Procedures:EVACUATE AREA. WEAR NIOSH/MSHA APPROVED SCBA,
RUBBER BOOTS AND HEAVY RUBBER GLOVES. ABSORB ON SAND OR VERMICULITE
AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA AND
WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP TIGHTLY CLOSED. DO NOT ALLOW
CONTACT WITH WATER. AIR SENSITIVE. STORE IN A COOL DRY PLACE.
HANDLE AND STORE UNDER NITROGEN.
Other Precautions:CORR.LACHRYMATOR. HARMFUL VAP. HIGHLY TOX.CAUSES
BURNS. DO NOT BRTH DUST. AVOID PRLNGD/RPTD EXPOS. VERY TOX BY
INHAL,IN CONT W/SKIN & IF SWALLOWED. DO NOT GET IN EYES, ON
SKIN/CLTHG.IF YOU FEEL UNWELL , SEEK MED ADVICE (SHOW LBL WHERE
POSS).
Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:CHEM WORK GOG/FULL LGTH FACESHLD .
Other Protective Equipment:OTHER PROTECTIVE CLOTHING. SAFETY SHOWER AND
EYE BATH.
Work Hygienic Practices:DO NOT BREATHE VAPOR. DO NOT GET IN EYES, ON
SKIN, ON CLOTHING. AVOID PRLNGD/RPTD EXPOSURE. WASH THOROUGHLY
AFTER HNDLG.
Supplemental Safety and Health
VP: 9.6 @ 20C; 50 @ 55C. FIRST AID PROC:MOUTH W/WATER PROVIDED PERSON
IS CONSCIOUS. CALL PHYS. WASTE DISP METH:CAN BE CNTRLD BY RATE OF
ADDN. DISP I/A/W FED, ST & LOC REGS.MATLS TO AVOID: FORMS COMPLEX
W/UREA THAT DECOMPOSES VIOLENTLY >90C.IT FORMS COMPLEXES W/DISULFUR
DINITRIDE & TETRASULFUR TETRANITRIDE (ING 2)
Waste Disposal Methods:SML QTYS:CAUTIOUSLY ADD TO LRG STIRRED EXCESS OF
WATER. ADJUST PH TO NEUT, SEPARATE ANY INSOLUBLE SOLIDS/LIQS &
PACKAGE THEM FOR HAZ-WASTE DISP.FLUSH AQUEOUS SOLN DOWN DRAIN
W/PLENTY OF WATER.HYDROLYS IS & NEUT RXNS MAY GEN HEAT & FUMES
WHICH (SUPDAT)
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.