===================== Product Identification =====================
MSDS NAME:HYDRAZINE 7% CATALYZED
NIIN:00N008826
MSDS Number: BCRCQ
=== Responsible Party ===
Company:DREW INDUSTRIAL DIVISION
Address:ONE DREW PLAZA
City:BOONTON
State:NJ
ZIP:07005
Info Phone Num:201-263-7600/TELEX 136444
Emergency Phone Num:606-324-1133
CAGE:FO386
=== Contractor Identification ===
Company:DREW CHEMICAL CORP,DIV OF ASHLAND CHEMICAL CO
Address:ONE DREW CHEMICAL PLAZA
Box:City:BOONTON
State:NJ
ZIP:07005
Country:US
Phone:606-324-1133
CAGE:52454
Company:DREW INDUSTRIAL DIVISION
Address:ONE DREW PLAZA
City:BOONTON
State:NJ
ZIP:07005
Phone:(201) 263-7600
CAGE:FO386
============= Composition/Information on Ingredients =============
Name:HYDRAZINE (SARA III)
CAS:302-01-2
RTECS #:MU7175000
Fraction by Wt: 7%
Other REC Limits:0.04 MG/M3 (NIOSH)
OSHA PEL:S, 1 PPM
ACGIH TLV:S, 0.1 PPM, A2; 9293
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
LD50 LC50 Mixture:N/K
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE OVEXPSR:EYES-CAN CAUS SEVER
IRRI,REDNSS,TEAR,BLUR VISION,LIQ CAN CAUS SEVER/PERM EYE
DAM.SKIN-CAN CAUS RED,IRRI,DERMAT,POSS SENS.HYDRAZIN IS TOX VIA SKN
ABSORP,MAY CAUS DELAY/CUM EFT.SYM MAY INC L DIZZ & NAUS.EXTEN SKN
ABSOR CAN RESULIN KID&LIV DAM,BLOOD CHNG&CENTR NERV SYS
DEPRE.BRTH-CAN CAUS(SGN&SYM OF OVEXPSR)
Explanation of Carcinogenicity:HYDRAZINE:IARC:PROB HMN CARC;ACGIH:SUSP
HMN CARC;NTP:HYDRAZ & HYDRAZ SULFA-MAY REASO BE ANTIC TO BE
CARCINOGEN
Effects of Overexposure:DAM TO NAS & RESP PASS.SWALL-RESUL IN SEVER DAM
TO MUCOU MEMBRA.CHRONIC:HYDRAIS STRNG IRRI TO EY,SKN & MUCO
MEMBR,SKIN SENS,CONVUL,HEPATOTOX & MOD HEMOLYT AGENT.HYDRAZIN HAS
BEEN SHWN TO CAUS CANCER I N LAB ANIM EXPO ORAL,INTRAPERITON/BY
INHAL.WARN PROPER ARE NOT ADEQUA FOR PRLNG EXPOSURE.
Medical Cond Aggravated by Exposure:N/K
======================= First Aid Measures =======================
First Aid:EY:IMM FL W/PLEN WTR FOR 15 MIN,LIFT UP&LOW LID OCCA.GET MED
ATTN.IF PHYS NOT IMM AVAI,CONTIN FL W/WTR.INHAL:RMV TO FRE
AIR.SUPPO BRTH(GIVE O*2/ART RESP)KEEP PER WARM,QUIET&GET MED
ATTN.INGES:IM M DRNK 2 GLAS OF WTR&INDU VOM BY GIV IPECAC SYR/BY
PLAC FING AT BCK THRO.NVR GIV ANYTHNG BY MOU TO UNCON PERS.GET MED
ATTN.SKN:IMM FL EXPO AREA W/WTR FOR 15 MIN.GET MED ATTN.RMV CONTAM
CLTHNG.
===================== Fire Fighting Measures =====================
Lower Limits:4.7
Upper Limits:99.0
Extinguishing Media:WATER FOG
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROT
EQPT NVR USE WELD/CUT TRCH ON/NEAR DRUM(EVEN EMPTY)BECAUS PROD(EVEN
RESIDU)CAN IGNIT EXPLO. (UNUS FR EXPLO HAZ)
Unusual Fire/Explosion Hazard:FLAMMA AIR-VAPOR MIX MAY FORM-HYDRAZINE
CAN IGN SPONTAN WHN DISPER IN AIR & WHN IN CONT W/POROUS MATL SUCH
AS EARTH,ASBES,WOOD/CLOTH(RAGS SHLD NEV BE USED).
================== Accidental Release Measures ==================
Spill Release Procedures:SM SPLL:EVAC AREA.COV SPLL W/SODA ASH/SO
BICAR.MX&SPRA W/WTR.IF EFFERVESC,WAIT TIL REAC COMPLE.SCO INTO LGE
BEAK.LGE SPLL:WEAR PROT EQPT.ELIM ALL IGN SCE.EVAC AREA.STP SPLL AT
SCE,DKE AREA OF SPLL,PMP LIQ TO SALV TNK.RMAIN LIQ MAY TAK UP ON
(SUP DAT)
Neutralizing Agent:SM SPLL:CAUT ADD = VOL CAL HYPOCHOR,ADD MORE
WTR,STIR,ALLOW STND 1 HOUR(SUP DAT)
====================== Handling and Storage ======================
Handling and Storage Precautions:CONTACT NEHC IN REQARD TO FOLLOW:LGE
AMT STOR,OUTDOOR STOR,INDOOR STOR.SHIP BOARD STOR:UPON
RECEIPT,HYDRAZ STCK SOLN MUST BE STOR IN CABINET (SUP DAT)
Other Precautions:CNTNR OF THS MATL MAY BE HAZ WHN EMPT,CNTNR RETAI
PROD RESI(VAP,LIQ,&/SOL),AL HAZ PRECAU MST BE OBSER.NTE:STOR&SPLL
PROC&SAF EQPT ARE PRESENT FOR SHPBOA ENVIR.CONSU SHP OPER PROC TECH
MAN FOR ADDIT DT AILS.FOR SHORE PRECAUTIONS,CNTCT MEHC.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:PROVIDE SUFFICIENT MECHANICAL(GENERAL AND/LOCAL
EXHAUST)VENTILATE TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:RESIS GLOV SCH AS:POLYVINYL CHLORIDE
Eye Protection:CHEM WORK GOGGLES & FACE SHIELD
Other Protective Equipment:IMPERVIOUS FULL-BODY PROTECTIVE
CLOTHING.APRON,SHOE COVERS,SHOWER/EYE-WASH STATION & TESTER.
Work Hygienic Practices:N/K
Supplemental Safety and Health
SPLL/RELE PROC:SND,CLY,EART,FLO ABSO,/OTH ABSO NATL&SHOV INTO CNTNR.NEU
AGEN:LGE SPLL:MX W/= VOL SODA ASH&ADD WTR-FRM SLUR IN LGE CNTNR.ADD
CAL HYPCHLOR,ADD MOR WTR,LET STND 2HRS.HND/STOR PRECA:PRVD.O NLY
HYDRAZ MAY BE STOR HERE.STOR UPRIG,DO NOT FREEZ,DO NOT STOR IN DIR
SNLGH/ALLOW DIRCONT W/HEAT SURF.KEEP LOCKED.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212F/100C
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:17.50 MMHG
Vapor Density:HV THN AIR
Spec Gravity:1.005
pH:10.0
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:N/K
Appearance and Odor:COLORLESS LIQUID
Percent Volatiles by Volume:>99
Corrosion Rate:
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS,LEAD,COPPER OR THEIR ALLOYS,ORGANIC
MATERIALS,EXCESSIVE HEAT,STRONG MINERAL ACIDS.
Stability Condition to Avoid:N/K
Hazardous Decomposition Products:N/K
==================== Disposal Considerations ====================
Waste Disposal Methods:SM SPLL:DILUTE&NEUTRALIZE(SEE NEU AGENT).FLUSH
DWN DRAIN W/EXCESS WTR IAW APPLIC REGULATIONS.LGE
SPLL:NEUTRALIZE(SEE NEU AGENT)& WASH DWN DRAIN W/EXCESS WTR IAW
APPLIC REGULATIONS.CONTAMINATED ABSOR M AY BE DEPOS IN LANDFILL IAW
LOCAL,STATE& FED REGU
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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