first aid proc:admin oxygen. admin artf resp if victim is ing 18:med attn. do not induce vomit. should vomit occur, ing 19:aspiration of vomitus into lungs. spill proc:prot. dike/impound spilled liq. cover spill ing 21:sparking tools to sweep/shovel into cntnrs. cover ing 22:sorbent/sweep cycle until spill has dried up. rinse ing 23:sewer/soak them up w/absorb matl. do not discharge ing 24:cleanup wastes to lakes, streams, ponds or sewer. msds toxicity property">
calcium oxide; (calcium oxide (lime)) silica, crystalline - quartz; (silicon dioxide) talc (powder), containing no asbestos fibers; (talc calcium carbonate (limestone) stoddard solvent; (mineral spirits (stoddard type)). vp:2 @ benzene, 2,4-diisocyanato-1-methyl-; (2,4-toluene ing 7:ld50:(oral,rat) >5800 mg/kg. volatile organic compounds: 81.6 g/l excluding water & supdat:prlng &/or rptd overexp to free resp silica may ing 10:could also cntn particles of titanium dioxide, ing 11:cathonate. chronic overexp to dust of these ing 12:rptd expos to isocyanates can lead to skin/resp ing 13:reddening, swell, rash/blisters & in such ing 14:asthma & nonspecific asthmatic cndtns. rpts have ing 15:nerv sys dmg. solvs are also reported to cause ing 16:inhal contents (process often called "sniffing") may first aid proc:admin oxygen. admin artf resp if victim is ing 18:med attn. do not induce vomit. should vomit occur, ing 19:aspiration of vomitus into lungs. spill proc:prot. dike/impound spilled liq. cover spill ing 21:sparking tools to sweep/shovel into cntnrs. cover ing 22:sorbent/sweep cycle until spill has dried up. rinse ing 23:sewer/soak them up w/absorb matl. do not discharge ing 24:cleanup wastes to lakes, streams, ponds or sewer. msds toxicity property">
titanium oxide; (titanium dioxide) calcium oxide; (calcium oxide (lime)) silica, crystalline - quartz; (silicon dioxide) talc (powder), containing no asbestos fibers; (talc calcium carbonate (limestone) stoddard solvent; (mineral spirits (stoddard type)). vp:2 @ benzene, 2,4-diisocyanato-1-methyl-; (2,4-toluene ing 7:ld50:(oral,rat) >5800 mg/kg. volatile organic compounds: 81.6 g/l excluding water & supdat:prlng &/or rptd overexp to free resp silica may ing 10:could also cntn particles of titanium dioxide, ing 11:cathonate. chronic overexp to dust of these ing 12:rptd expos to isocyanates can lead to skin/resp ing 13:reddening, swell, rash/blisters & in such ing 14:asthma & nonspecific asthmatic cndtns. rpts have ing 15:nerv sys dmg. solvs are also reported to cause ing 16:inhal contents (process often called "sniffing") may first aid proc:admin oxygen. admin artf resp if victim is ing 18:med attn. do not induce vomit. should vomit occur, ing 19:aspiration of vomitus into lungs. spill proc:prot. dike/impound spilled liq. cover spill ing 21:sparking tools to sweep/shovel into cntnrs. cover ing 22:sorbent/sweep cycle until spill has dried up. rinse ing 23:sewer/soak them up w/absorb matl. do not discharge ing 24:cleanup wastes to lakes, streams, ponds or sewer.
LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYES:MOD IRRIT. MAY CAUSE
TEARING, REDDENING OF EYES & REVERSIBLE CORNEAL INJURY. SKIN:SEV
IRRIT. PROD MAY CNTN TRACE AMTS OF ISOCYANATE, CLASS OF CMPDS
GENRLY REGARDED AS PRIMARY IRRITS. CONT W /PROD MAY CAUSE DERM,
ALLERGIC RESPONSES & IN SENSITIVE INDIVIDUALS, REDNESS, SWELL &
BLISTERS. INHAL: (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:SEV IRRIT. EXPOS TO CONC OF AIRBORNE
ISOCYANATES ABOVE TLV MAY PRDCE IRRIT OF RESP TRACT, COUGH, CHEST
DISCOMFORT, SHORTNESS OF BREATH. INDIVIDUALS W/HISTORY OF EXPOS TO
ISOCYANATES CAN DEVEL OP MORE SEV SYMPS, SUCH AS BRONCH, BRONCH
SPASMS & PULM EDEMA (FLUID IN LUNGS). FOR MOST INDIVIDUALS THESE
EFTS (SUPDAT)
Medical Cond Aggravated by Exposure:PREEXISTING RESPIRATORY OR SKIN
CONDITION(S) MAY BE AGGRAVATED BY EXPOSURE.
======================= First Aid Measures =======================
Eyes:FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS. IF NEC,
GENTLY HOLD EYELIDS OPEN DURING FLUSH. OBTAIN IMMED MED ATTN.
SKIN:REMOVE CONTAM CLTHG & SHOES. WASH AFFECTED AREA(S) THORO
W/SOAP & WATER. WIP E/FLUSH AFFECTED SKIN W/ISOPROPYL ALCOHOL
(RUBBING ALCOHOL). WASH AGAIN THORO W/SOAP & WATER. IF IRRIT
PERSISTS, SEEK MED ATTN. INHAL:MOVE VICTIM INTO FRESH AIR. IF
VICTIM HAS DFCLTY BRTHG; (ING 18)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:145F,63C
Lower Limits:0.9%
Upper Limits:7%
Extinguishing Media:WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON
DIOXIDE.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
CNTNRS EXPOS TO FIRE SHOULD BE KEPT COOL W/WATER SPRAY. WATER
STREAM DIRECTED INTO FIRE MAY CAUSE (SUPDAT)
Unusual Fire/Explosion Hazard:COMBUST CLASS III A. CLSD CNTNRS MAY
EXPLODE DUE TO BUILD UP OF PRESS WHEN EXPOS TO HEAT. THERMAL
DECOMP/COMBUST OF PROD MAY GENERATE IRRIT &/OR TOX (SUPDAT)
Spill Release Procedures:VENTILATE AREA & REMOVE ALL SOURCES OF IGNIT.
EVACUATE UNNEC PERS. WIPE UP SM SPILLS W/RAGS/TOWELS. PUT SPENT
RAGS/TOWELS IN LOOSELY COVERED CNTNRS IN WELL-VENTILATED AREA. LG
SPILLS SHOULD BE HNDLD C AREFULLY. PUT ON NIOSH/MSHA APPRVD
RESP(ING 21)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT BREATHE VAPS. AVOID CONT
W/EYES, SKIN & CLTHG. KEEP CNTNR CLSD WHEN NOT IN USE. KEEP OUT OF
REACH OF CHILDREN. DO NOT TAKE INTERNALLY.
Other Precautions:WEAR PROT CLTHG AT ALL TIMES. USE ONLY W/ADEQ VENT.
PROD DOES NOT CNTN DUST AS PRDCD/GENERATE DUST IN NORM USE. DUST
GENERATED BY ABNORM ACTIVITIES, SUCH AS SANDING/GRINDING, COULD
CNTN SM AMT (<0.1%) OF RESP SILICON DIOXIDE (QUARTZ) DUST.
Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATORY PROTECTION
WHEN PRODUCT IS MIXED OR APPLIED IN POORLY VENTILATED AREA OR IF
WORKPLACE LEVELS OF INGREDIENTS EXCEED TLV. FOLLOW APPLICABLE
FEDERAL, STATE & LOCAL RE GULATIONS.
Ventilation:USE LOCAL EXHAUST (E.G., OPEN WINDOWS, FANS) AS NEEDED TO
KEEP VAPOR/DUST LEVELS BELOW RECOMMENDED LIMITS.
Protective Gloves:NATRL/BUTYL RUB, SUPPORTED PVA/ (SUPDAT)
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . CLEAN PROT CLTHG TO COVER ARMS & LEGS
(SUPDAT)
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
FIRE FIGHT PROC:FROTHING W/SUBSEQUENT SPREAD OF FIRE. EXPLO HAZ:GASES.
VAP IS HVR/AIR & MAY TRAVEL ALONG GROUND/FLOOR & BE IGNITED AT
LOCATIONS DIST FROM SOURCE. PROT GLOVES:NITRILE GLOVES. AVOID NEOP
RENE. OTHER PROT EQUIP:& KEEP EXPOS TO MIN. EFTS OF OVEREXP:ARE
REVERSIBLE. INGEST:MAY CAUSE IRRIT. CHRONIC: (ING 10)
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT W/WATER, ALCOHOLS, AMINES, STRONG OXIDANTS, STRONG BASES
OR ACIDS.
Stability Condition to Avoid:CONTACT W/WATER VAPOR. SOURCES OF
IGNITION. LONG TERM EXPOSURE TO ELEVATED TEMPERATURES.
Hazardous Decomposition Products:OXIDES OF CARBON & NITROGEN, HYDROGEN
CYANIDE GAS, OTHER ACRID & TOXIC FUMES.
Conditions to Avoid Polymerization:CONTACT W/MOISTURE OR OTHER
MATERIALS THAT REACT W/ISOCYANATES MAY CAUSE POLYMERIZATION.
Waste Disposal Methods:REVIEW ALL LOCAL, STATE & FEDERAL REGULATIONS
CONCERNING HEALTH & POLLUTION FOR APPROPRIATE DISPOSAL PROCEDURES.
DO NOT INCINERATE CLOSED CONTAINERS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.