===================== Product Identification =====================
MSDS NAME:METHACRYLIC ACID
NIIN:00N058770
MSDS Number: BXFKS
=== Responsible Party ===
Company:EI DUPONT DE NEMOURS & CO., (INC).
Address:BARCLAY MILL PLAZA P18-1213
City:WILMINGTON
State:DE
ZIP:19898-0018
Country:US
Info Phone Num:800-441-7515
Emergency Phone Num:800-424-9300(CHEMTREC)
CAGE:EO716
=== Contractor Identification ===
Company:DU PONT E I DE NEMOURS & CO INC IMAGING SYS DEPT
Address:BARLEY MILL PLZ 22-1356
Box:80022
City:WILMINGTON
State:DE
ZIP:19880-0022
Country:US
Phone:302-992-2012
CAGE:82348
Company:EI DUPONT DE NEMOURS CO/AUTOMOTIVE PRODS
Address:1007 MARKET ST
City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:(800) 441-7515
CAGE:EO716
============= Composition/Information on Ingredients =============
CAS:79-41-4
RTECS #:OZ2975000
OSHA PEL:S, 20 PPM
ACGIH TLV:20 PPM
Name:SUPDAT:BULLETIN E-53033. WASH THOROUGHLY AFTER HANDLING AND
BEFORE EATING OR SMOKING.
RTECS #:9999999ZZ
OSHA PEL:S, 20 PPM
ACGIH TLV:20 PPM
Name:EYE PROT:AND FULL LENGTH FACE SHIELD .
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION:MAY CAUSE EYE, NOSE, THROAT
AND RESPIRATORY IRRITATION. SKIN/EYE:CORROSIVE TO THE SKIN AND EYE.
MAY CAUSE PERMANENT EYE INJURY. MAY CAUSE SKIN SENSITIZATION.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR. IF DFCLTY IN BRTHG, ADMIN OXYG. IF
NOT BRTHG, GIVE ARTF RESP. IF BRTHG DFCLTY PERSISTS/OCCURS LATER,
CONSULT MD. SKIN:WASH W/SOAP & WATER. IF IRRIT OCCURS, CONTACT MD.
EYES: IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MIN; CALL MD.
INGEST:DO NOT INDUCE VOMIT. IMMED GIVE 2 GLASSES OF WATER/ACTIVATED
CHARCOAL SLURRY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERSON.
CALL MD.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:154F,68C
Lower Limits:1.6%
Upper Limits:8.8%
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. WATER FROM FOG NOZZS MAY BE USED TO PVNT PRESS BUILD-UP. FIGHT
FIRES FROM SAFE DIST/PROTECTED AREAS.
Unusual Fire/Explosion Hazard:SEALED CONTAINERS EXPOSED TO ELEVATED
TEMPERATURES MAY RUPTURE EXPLOSIVELY DUE TO POLYMERIZATION. VAPORS
ARE HEAVIER THAN AIR AND MAY TRAVEL TO IGNITION SOURCE.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. VENTILATE AREA. REMOVE SOURCES
OF IGNITION. PREVENT SKIN CONTACT AND BREATHING OF VAPOR. CONFINE
AND ABSORB WITH DRY SODIUM CARBONATE OR ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:PERMIT AIR SPACE TO EXIST INSIDE STOR
CNTNRS. MATL STORED MORE THAN 3 MONTHS SHOULD HAVE INHIBITOR LEVEL
CHECKED & MAINTAINED AT ORIGINAL LEVEL.
Other Precautions:PROD FREEZES @ 61F,. TO THAW BEFORE USING, DRUMS
SHOULD BE PLACES IN WARM ROOM ( @ LST 65F) FOR SEVERAL DAYS, &
ROLLED TO MELT & MIX CONTENTS. AVOID LOC OVERHEATING WHICH MIGHT
INITIATE UNCONTROLLED P OLYM. DO NOT USE FLAME/LIVE (SUPP DATA)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:DO NOT BREATHE VAPORS OR MISTS. WHEN LEVELS
EXCEED 20 PPM, WEAR NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING
APPARATUS. FOLLOW THE RESPIRATOR MANUFACTURERS DIRECTIONS FOR
RESPIRATOR USE.
Ventilation:PROVIDE SUFFICIENT VENT IN VOL & PATTERN TO KEEP CONTAMS
BELOW APPLIC OSHA REQS & OTHER SUGGESTED EXPOS LIMS.
Protective Gloves:NEOPRENE GLOVES ARE RECOMMENDED.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(ING 3)
Other Protective Equipment:EYE BATH & SFTY SHOWER MEETING ANSI DESIGN
CRITERIA . COVERALLS AND BOOTS ARE RECOMMENDED.
Work Hygienic Practices:PROTECTIVE CREAMS:DO NOT USE FOR PROTECTION.
MAY BE USED FOR EASE OF CLEAN UP.
Supplemental Safety and Health
BP:322F,161C @ 760MM. CNDTNS (POLYM):INHIBITORS & STOR STAB. AVOID
FREEZING THAT MAY RSLT IN UNEVEN DISTRIBUTION OF INHIBITOR. OTHER
PREC:STEAM. BE SURE TO VENT DRUMS WHEN EMPTYING. OBSERVE LBL PREC.
KEEP AWAY FROM HEAT, SPKS, FLAME & DIRECT SUNLIGHT. CLOSE CNTNR
AFTER EACH USE. GROUND CNTNRS WHEN POURING. SEE (ING 2)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:SUPP DATA
Melt/Freeze Pt:M.P/F.P Text:61.0F,16.1C
Vapor Pres:SEE INGS
Vapor Density:2.97 @ 60F
Evaporation Rate & Reference:0.07 (BUAC=1)
Solubility in Water:INFINITE
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:100.0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
REDUCING AND OXIDIZING AGENTS. MATERIAL HAS STRONG SOLVENT PROPERTIES
AND CAN SOFTEN PAINT OR RUBBER.
Stability Condition to Avoid:HEAT AND IGNITION SOURCES; PRODUCT IS
STRONGLY ACIDIC-AVOID CONTACT WITH MILD STEEL OR ALKALIS.
Hazardous Decomposition Products:CO, CO*2, SMOKE.
Conditions to Avoid Polymerization:EXCESSIVE HEAT, STOR IN ABSENCE OF
INHIBITOR; INADVERTENT ADDN OF CATALYST. SEE BULLETIN E-53033 FOR
DETAILS ON (SUPDAT)
==================== Disposal Considerations ====================
Waste Disposal Methods:EPA CHARACTERISTIC HAZARD WASTE. DO NOT ALLOW
MATERIAL TO CONTAMINATE GROUND WATER SYSTEMS. INCINERATE IN A
FACILITY WHICH COMPLIES WITH FEDERAL, STATE AND LOCAL REQUIREMENTS.
DO NOT INCINERATE IN CLO SED CONTAINERS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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