LD50 LC50 Mixture:ORAL LD50 (RAT) IS 1190 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE; INHALATION MAY BE HARMFUL; MAY
CAUSE SEVERE DAMAGE TO RESPIRATORY MUCOUS MEMBRANES, INFLAMATION &
EDEMA OF LARYNX, CHEMICAL PNEUMOCONIOSIS, PULMONARY EDEMA. CONTACT
MAY CAUSE SEVERE IRRITATION OR BURNS TO SKIN & EYES. MAY BE
HARMFULIF INGESTED. CHRONIC: NONE SPECIFIED BY MANUFACTURER.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:INHALED-COUGHING, WHEEZING, CHEST PAIN, SORE
THROAT, SHORTNESS OF BREATH, HEADACHE. EYES-PAIN, REDNESS, TEARING,
BURNING SENSATION. SKIN-REDNESS, BURNS, PAIN. INGESTED-NAUSEA,
VOMITING.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:SKIN/EYES-FLUSH WITH LOTS OF WATER FOR AT LEAST 15 MINUTES
WHILE REMOVE CONTAMINATED CLOTHES & SHOES. INHALED-REMOVE TO FRESH
AIR. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING; OXYGEN IF
BREATHING DIF FICULT. INGESTED-IF CONSCIOUS, WASH OUTMOUTH WITH
WATER. CALL A DOCTOR.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER SPRAY.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE GEAR. PREVENT CONTACT WITH SKIN & EYES. STRONG
OXIDIZING AGENT.
Unusual Fire/Explosion Hazard:CONTACT WITH OTHER MATERIAL MAY CAUSE
FIRE. EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
Spill Release Procedures:EVACUATE AREA. WEAR SELF-CONTAINED BREATHING
APPARATUS AND PROTECTIVE CLOTHING TO INCLUDE RUBBER BOOTS & HEAVY
RUBBER GLOVES. COVER WITH DRY LIME OR SODA ASH. PICK UP AND PLACE
IN A CONTAINER AND HOLD FOR WASTE DISPOSAL.
Neutralizing Agent:DRY LIME OR SODA ASH.
====================== Handling and Storage ======================
Handling and Storage Precautions:USE ONLY IN CHEMICAL HOOD. KEEP
TIGHTLY CLOSED. STORE IN A COOL, DRY PLACE. KEEP AWAY FROM
INCOMPATIBLE MATERIALS.
Other Precautions:DO NOT GET IN EYES OR ON SKIN OR CLOTHES. AVOID
PROLONGED OR REPEATED EXPOSURE. AVOID BREATHING DUST.
Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE
OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR. USE
IN ACCORDANCE WITH 29 CFR 1910.134 AND MANUFACTURER'S
RECOMMENDATIONS.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:NEOPRENE.
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES.
Other Protective Equipment:OTHER PROTETCIVE CLOTHING, EYE WASH STATION
& SAFETY SHOWER.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
MSDS PRESENTED BY CAGE 0X801 FOR CONTRACT NUMBER SP0420-95-PA229.
Waste Disposal Methods:DISSOLVE IN 1)WATER;2)ACID SOLUTION;3)OXIDIZED
TO A WATER SOLUBLE STATE. PRECIPITATE A SSULFIE, ADJUST PH TO 7.
FILTER PRECIPITATES & DISPOSE OF AS HAZWASTE. DESTROY EXCESS
SULFIDE W/SODIUM HYPOCHLORI TE. NEUTRALIZE BEFORE FLUSHING DOWN
DRAIN.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.