===================== Product Identification =====================
MSDS NAME:CAREFREE RECHARGEABLE BATTERY,CF 6 V 5
NIIN:01-223-1466
MSDS Number: BZBDR
=== Responsible Party ===
Company:EAGLE-PINCHER INDUSTRIES
Address:BETHEL RD
Box:130
City:SENECA
State:MO
ZIP:64865
Country:US
Info Phone Num:417-776-2256
Emergency Phone Num:417-776-2256
CAGE:81855
=== Contractor Identification ===
Company:EAGLE-PICHER INDUSTRIES, INC.
Address:C AND PORTER STS
Box:47
City:JOPLIN
State:MO
ZIP:64801
Country:US
Phone:417-623-8000
CAGE:81855
============= Composition/Information on Ingredients =============
Name:LEAD (SARA 313) (CERCLA)
CAS:7439-92-1
RTECS #:OF7525000
Fraction by Wt: 50%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE 1910.1025
ACGIH TLV:0.15MG/M3 DUST; 9495
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:LEAD OXIDE, (RED LEAD OXIDE); PERCENTAGE OF INGREDIENTS 2
AND 3: 25.
CAS:1314-41-6
RTECS #:OG5425000
Fraction by Wt: SEE ING
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE 1910.1025
ACGIH TLV:0.15 MG/M3
Name:LEAD OXIDE (LITHARGE)
CAS:1317-36-8
RTECS #:OG1750000
Fraction by Wt: SEE # 2%
Other REC Limits:NONE RECOMMENDED
Name:SULFURIC ACID (SARA 302/313) (CERCLA); 38%
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 16%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3/3 STEL; 9495
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT RELEVANT.
Routes of Entry: Inhalation:NO Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, CNS, LUNG, GI
TRACT. ACUTE- LEAD MAY CAUSE GI UPSET, DIARRHEA, CRAMPING &
FATIGUE. SULFURIC ACID MAY CAUSE EYE, SKIN & RESPIRATORY TRACT
IRRITATION, BURNS, CORNEAL & LUNG DAMA GE. CHRONIC- LEAD MAY CAUSE
ANEMIA, KIDNEY & NERVOUS SYSTEM DAMAGE. ACID CAN CAUSE BRONCHITIS,
EROSION OF TOOTH ENAMEL.
Explanation of Carcinogenicity:CONTAINS LEAD
Effects of Overexposure:GI UPSET, LOSS OF APPETITE, DIARRHEA,
CONSTIPATION, CRAMPING, LACK OF SLEEP, FATIGUE, EYE, SKIN AND
RESPIRATORY TRACT IRRITATION, BURNS, CORNEAL AND LUNG DAMAGE
Medical Cond Aggravated by Exposure:LEAD AND ITS COMPOUNDS CAN
AGGRAVATE CHRONIC FORMS OF KIDNEY, LIVER AND NEUROLOGIC DISEASES.
CONTACT OF SULFURIC ACID WITH SKIN MAY AGGRAVATE DISEASES SUCH AS
ECZEMA. ACID MIST AGGRAVATES LUNG DISEASE
======================= First Aid Measures =======================
First Aid:OBTAIN MEDICAL ATTENTION IN ALL CASES OF EXPOSURE.
EYES/SKIN:FLUSH WITH WATER FOR 15 MINUTES. KEEP EYELIDS OPEN.
INHALATION:MOVE TO FRESH AIR. INGESTION:DO NOT INDUCE VOMITING. IF
CONSCIOUS, DRINK LAR GE AMOUNT OF WATER OR MILK FOLLOWED BY MILK OF
MAGNESIA, BEATEN EGGS OR VEGETABLE OIL.
===================== Fire Fighting Measures =====================
Flash Point:NON-FLAMMABLE
Extinguishing Media:USE CARBON DIOXIDE, SAND, HALON/DRY CHEMICAL. WATER
APPLIED TO ELECTROLYTE GENERATES HEAT AND CAUSES IT TO SPATTER.
Fire Fighting Procedures:WEAR ACID-RESISTANT CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:BATTERY CELLS MAY RUPTURE WHEN EXPOSED TO
EXCESSIVE HEAT. THIS COULD RESULT IN RELEASE OF CORROSIVE
MATERIALS. HYDROGEN GAS, IF PRESENT, IS EXPLOSIVE/FLAMMABLE.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENTS. REMOVE
COMBUSTIBLES & IGNITION SOURCES (H2 MAY BE PRESENT). CONTAIN BY
DIKING AND COVER SPILL WITH SODA ASH OR QUICKLIME. MIX WELL. CHECK
THAT MIXTURE IS NEUTRAL. COLLECT A ND PLACE IN A DRUM. DO NOT FLUSH
TO SEWER.
Neutralizing Agent:SODA ASH (SODIUM CARBONATE), QUICKLIME (CALCIUM
OXIDE)
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE NEAR EYEWASH FOUNTAIN AND SAFETY
SHOWER. STORAGE AREA SHOULD BE EQUIPPED WITH A DRAIN WHICH CAPTURES
SPILLS OF ACID FOR PROPER DISPOSAL.
Other Precautions:KEEP TERMINALS COVERED. AVOID SHORTING BATTERIES. DO
NOT CRACK OR OVERCHARGE BATTERIES. KEEP LIGHTED CIGARETTES, SPARKS,
AND FLAMES AWAY FROM CHARGING BATTERIES. KEEP OUT OF REACH OF
CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT REQUIRED UNDER NORMAL USE. USE
NIOSH-APPROVED ACID-MIST FILTER RESPIRATOR IF 1 MG/M3 TWA IS
EXCEEDED (ACID).
Ventilation:ADEQUATE GENERAL VENTILATION
Protective Gloves:RUBBER
Eye Protection:SPLASH-PROOF CHEMICAL GOGGLES
Other Protective Equipment:RUBBER APRON AND BOOTS. EYES WASH STATION
AND SAFETY SHOWER. USE ACID-PROOF CLOTHING FOR MAJOR SPILLS.
Work Hygienic Practices:REMOVE METALLIC JEWELRY-SHOCK POTENTIAL. WASH
THOROUGHLY AFTER HANDLING AND BEFORE EATING AND DRINKING.
Supplemental Safety and Health
THIS PRODUCT IS AN ARTICLE UNDER OSHA, PER MSDS.
================== Physical/Chemical Properties ==================
HCC:Z4
NRC/State Lic Num:NOT RELEVANT
Spec Gravity:NOT RELEVANT
Viscosity:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:NOT RELEVENT
Appearance and Odor:BATTERY CONTAINING SULFURIC ACID AND LEAD.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
SOLVENTS MAY DISSOLVE BATTERY CASE MATERIAL.
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES, OVERCHARGING,
SMOKING, SPARKS
Hazardous Decomposition Products:LEAD OXIDE, HYDROGEN, SULFUR DIOXIDE,
SULFUR TRIOXIDE, METAL FUMES
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE AS HAZARDOUS WASTE. OBSERVE ALL FEDERAL,
STATE AND LOCAL ENVIRONMENTAL REGULATIONS FOR ACID OR LEAD SCRAP.
SEND BATTERIES TO LEAD SMELTER FOR RECLAMATION FOLLOWING APPLICABLE
FEDERAL, STATE AN D LOCAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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