===================== Product Identification =====================
MSDS NAME:ACETONE,SYNTHETIC,00259
NIIN:00-184-4796
MSDS Number: BDGXV
=== Responsible Party ===
Company:DOW CHEMICAL U.S.A.
Address:CHEMICAL AND METALS DEPARTMENT
City:MIDLAND
State:MI
ZIP:48674
Country:US
Info Phone Num:517-636-4400
Emergency Phone Num:517-636-4400
CAGE:96717
=== Contractor Identification ===
Company:DOW CHEMICAL CO
Address:100 LARKIN CENTER
Box:City:MIDLAND
State:MI
ZIP:48674
Country:US
Phone:800-258-2436
CAGE:96717
============= Composition/Information on Ingredients =============
Name:ACETONE (SARA III)
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 99.5%
OSHA PEL:1000PPM
ACGIH TLV:750PPM/1000STEL;9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT) IS >6000 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, RESPIRATORY,
CNS. ACUTE- EYE:WILL INJURE EYE IF NOT REMOVED PROMPTLY. SKIN:MAY
CAUSE DRYING/FLAKING. INHALE:MAY CAUSE RESPIRATORY TRACT
IRRITATION, ANESTHETIC OR NARCOTIC EFFE CTS. ORAL:LOW TOXICITY.
CHRONIC- DRYNESS, DEFATTING.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:HEADACHE, DIZZINESS, DROWSINESS, NAUSEA,
DRYING, CRACKING & DEFATTING OF SKIN, EYE IRRITATION,
GASTROINTESTINAL IRRITATION, RESPIRATORY TRACT IRRITATION
Medical Cond Aggravated by Exposure:PERSONS WITH CHRONIC RESPIRATORY OR
SKIN DISEASES MAY BE AT AN INCREASED RISK FROM EXPOSURE.
======================= First Aid Measures =======================
First Aid:CALL A DOCTOR IF SYMPTOMS PERSIST. EYE:IMMEDIATELY FLUSH WITH
WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH OFF IN
FLOWING WATER OR SHOWER. INHALED:REMOVE TO FRESH AIR. PROVIDE
CPR/OXYGEN IF N EEDED. ORAL:IF CONSCIOUS & LARGE AMOUNTSARE
INGESTED, INDUCE VOMITING. CALL A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:-4F,-20C
Autoignition Temp:Autoignition Temp Text:869F
Lower Limits:2.6
Upper Limits:12.8
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, ALCOHOL RESISTANT
FOAM. USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
Fire Fighting Procedures:WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING
APPARATUS OPERATED IN POSITIVE PRESSURE MODE. EXTINGUISH ONLY IF
FLOW CAN BE STOPPED (UNMANNED HOSE)/LET IT BURN.
Unusual Fire/Explosion Hazard:CONTAINERS MAY EXPLODE DUE TO EXTREME
HEAT. DISPERSE VAPORS AND SPILLS WITH WATER AND PROTECT PERSONNEL.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. VENTILATE AREA.
ELIMINATE SOURCES OF IGNITION. STOP LEAK IF POSSIBLE. CONTAIN
LIQUID WITH SAND/EARTH. RECOVER BY PUMPING (EXPLOSION
PROOF)/NON-FLAMMABLE ABSORBENT MATERIALS. PREVENT LIQUID FROM
ENTERING SEWERS, WATERWAYS.
Neutralizing Agent:NOT RELEVANT
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE AT AMBIENT TEMPERATURES, IN WELL
VENTILATED AREA AWAY FROM SPARKS, FLAMES, OTHER SOURCES OF IGNITION
& INCOMPATIBLE SUBSTANCES.
Other Precautions:AVOID BREATHING VAPORS. AVOID CONTACT WITH EYES &
SKIN. SHOULD BE STORED IN CONTAINERS WHICH MEET THE GROUNDING &
BONDING GUIDELINES SPECIFIED BY NFPA. KEEP OUT OF REACH OF
CHILDREN. WASH THOROUGHLY A FTER HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED CHEMICAL CARTRIDGE
RESPIRATOR/POWERED AIR-PURIFYING RESPIRATOR. FOR EMERGENCY USE
SELF-CONTAINED BREATHING APPARATUS/SUPPLIED-AIR RESPIRATOR WITH
FULL FACEPIECE OPERATED IN POSITIVE PRE SSURE MODE.
Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:BUTYL IF REPEATED CONTACT POSSIBLE
Eye Protection:CHEMICAL GOGGLES
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER.
INDUSTRIAL-TYPE WORK CLOTHING, APRON, AND BOOTS IF SPILLS OR
SPLASHING CAN OCCUR.
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:F2
NRC/State Lic Num:NOT RELEVENT
Boiling Pt:B.P. Text:133F,56C
Vapor Pres:181.7 68F
Vapor Density:2.0
Spec Gravity:0.7880
Solubility in Water:COMPLETELY MISCIBLE
Appearance and Odor:CLEAR, COLORLESS, VOLATILE LIQUID WITH A SWEETISH
ODOR
Percent Volatiles by Volume:99.5
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NITRIC PLUS ACETIC ACIDS AND NITRIC PLUS SULFURIC ACIDS
Stability Condition to Avoid:HIGH HEAT, SPARKS, STATIC ELECTRICITY, HOT
SURFACES, OPEN FLAMES AND OTHER SOURCES OF IGNITION
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:BURN IN INCINERATOR. ENSURE CONFORMITY TO LOCAL,
STATE AND FEDERAL DISPOSAL REGULATIONS. RUN-OFF TO SEWER MAY CREATE
FIRE OR EXPLOSION HAZARD. EPA "HAZARDOUS WASTE" (IGNITIBLE), IF
DISCARDED D001. RQ IS 5000 POUNDS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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