Search   
MSDS  
:
 3034 PAPI R 27 POLYMERIC MDI
CAS  
:
 26447-40-5
9016-87-9
NAME  
:
 1,1'-methylenebis(isocyanato-benzene), diphenylmethane
higher oligomers of mdi, polymethylene polyphenylene
Catalog of Chemical Suppliers, Buyers, Custom Synthesis Companies And Equipment Manufacturers
[ 3034 PAPI R 27 POLYMERIC MDI 26447-40-5 9016-87-9 ]
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=====================  Product Identification  =====================

MSDS NAME:3034 PAPI R 27 POLYMERIC MDI
NIIN:00F049677
MSDS Number: BZWJP
=== Responsible Party ===
Company:DOW CHEMICAL U S A
Address:2030 DOW CTR
City:MIDLAND
State:MI
ZIP:48674-5000
Country:US
Info Phone Num:800-258-2436/517-636-4400
Emergency Phone Num:517-636-4400/800-258-2436
CAGE:71983
=== Contractor Identification ===
Company:DOW CHEMICAL U.S.A.
City:MIDLAND
State:MI
ZIP:48674
Country:US
Phone:517-636-4400
CAGE:71983

=============  Composition/Information on Ingredients  =============

Name:1,1'-METHYLENEBIS(ISOCYANATO-BENZENE), DIPHENYLMETHANE
    DIISOCYANATE       *96-2*
CAS:26447-40-5
Fraction by Wt: 40-50%

Name:HIGHER OLIGOMERS OF MDI, POLYMETHYLENE POLYPHENYLENE
    POLYISOCYANATE
CAS:9016-87-9
RTECS #:TR0350000

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:ORAL LD50(RAT): >10000 MG/KG
Routes of Entry: Inhalation:YES  Skin:NO  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: ALERGIC
    REACTION, IRRITATION. INHALATION: IRRITATION OF UPPER RESPIRATORY
    TRACT & LUNGS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION & RESPIRATORY SENSITIZATION.

=======================  First Aid Measures  =======================

Eyes: IRRIGATE W/WATER IMMEDIATELY FOR 15 MINS. SKIN: WASH
    OFF W/FLOWING WATER/SHOWER. INHALATION: REMOVE TO FRESH AIR. IF NOT
    BREATHING, GIVE CPR. IF BREATHING IS DIFFICULT GIVE OXYGEN. NOTE TO
    PHYSI CIAN: NO SPECIFIC ANTIDOTE. SUPPORTIVE CARE. THE
    MANIFESTATIONS OF RESPIRATORY SYMPTOMS, INCLUDING PULMONARY EDEMA,
    RESULTING FROM ACUTE EXPOSURE MAY BE DELAYED. OBTAIN MEDICAL
    ATTENTION IN ALL CASES.

=====================  Fire Fighting Measures  =====================

Flash Point Method:PMCC
Flash Point:>400F
Extinguishing Media:CO2, DRY CHEMICAL, FOAM, HALON 1211.
Fire Fighting Procedures:WEAR POSITIVE PRESSURE SCBA & FULL PROTECTIVE
    CLOTHING. DOWN-WIND PERSONNEL MUST BE EVACUATED.
Unusual Fire/Explosion Hazard:DON'T RESEAL CONTAMINATED CONTAINERS AS
    PRESSURE BUILD UP MAY RUPTURE THEM.

==================  Accidental Release Measures  ==================

Spill Release Procedures:EVACUATE & VENTILATE. DIKE TO PREVENT ENTRY
    INTO WATER SYSTEM. WEAR FULL PROTECTIVE EQUIPMENT INCLUDING
    POSITIVE PRESSURE SCBA. MAJOR: IF TEMPORARY CONTROL OF ISOCYANATE
    VAPOR IS REQUIRED, USE A BLANK ET OF PROTEIN FOAM.	   (SEE SUPP)

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:WHEN RESPIRATORY PROTECTION IS REQUIRED, USE
    APPROVED SUPPLIED AIR RESPIRATOR. WHERE EXPOSURE GUIDELINE MAY BE
    GREATLY EXCEEDED, USE AN APPROVED POSITIVE PRESSURE SCBA.
Ventilation:GENERAL &/LOCAL EXHAUST VENTILATION TO CONTROL AIRBORNE
    LEVELS BELOW EXPOSURE GUIDLINES.
Protective Gloves:RECOMMENDED
Eye Protection:SAFETY GLASSES, CHEMICAL GOGGLES.
Other Protective Equipment:BOOTS, APRON/FULL BODY SUIT.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
    REUSE. WASH W/SOAP & WATER.
Supplemental Safety and Health
SPILL MINOR: ABSORB W/SAWDUST/OTHER ABSORBENTSHOVEL INTO SUITABLE
    UNSEALED CONTAINERS. DECONTAMINATE FLOOR.

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:392F
Vapor Pres:<1
Vapor Density:8.6
Spec Gravity:1.2
Solubility in Water:REACTS
Appearance and Odor:BROWN LIQUID

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
WATER, ACID, BASE ALKALIES, AMMONIA & ALCOHOLS, METAL COMPOUNDS,
    SURFACE ACTIVE MATERIALS.
Stability Condition to Avoid:ATMOSPHERIC MOISTURE
Hazardous Decomposition Products:ISOCYANATE VAPOR & MIST, CO2, CO,
    NITROGEN OXIDES & TRACES OF HYDROGEN CYANIDE.

====================  Disposal Considerations  ====================

Waste Disposal Methods:EMPTY DRUMS SHOULD BE FILLES W/WATER. LET EMPTY
    DRUM STAND FOR 48 HOURS. DRUMS SHOULD BE DRAINED, TRIPLE RINSED &
    HOLED/CRUSHED TO PREVENT REUSE. DISPOSE/INCINERATE, DRAIN & RINSE
    IAW/FEDERAL, STATE &  LOCAL REGULATIONS.

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.

*** END OF RECORD ***
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857645 TRIS(HYDROXYMETHYL)AMINOMETHANE HYDROCHLORIDE,99% 1185-53-1
21942 LEAK DETECTING BATTERY CLEANER 111-76-2
102-71-6
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19442 NON CHLORINATED BRAKE WASH 64742-89-8
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MATTING ADHESIVE 78-93-3
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VERMATEK 1.AA 57-13-6
51378701 ROCK DRILL OIL 7782-50-5
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21969 POWER PLUS II CARB,CHOKE & THROTTLE BODY CLEANER 78-93-3
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EASY-OFF OVEN, GRILL & STAINLESS STEEL CLEANER 1310-73-2
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700040 AQUA-SAFE 34590-94-8
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HIGH TEMPERATURE MOLD MAKER (C-1) RESIN 25068-38-6
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ARDROX 9D75
SPBI8-2Y CUSTOM OIL STANDARD-SINGLE ELEMENT SOLUTION 94-02-0
104-75-6
149-57-5
8042-47-5
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D12 & D3 SPECTROMETRIC CALIBRATION STANDARDS 7439-89-6
7429-90-5
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7439-92-1
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14265-1 BELIEVE MASS TRANSIT VEHICLE CLEANER 68439-46-3
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6-7912 SILICONE FLUID 63148-62-9
5865 DECORATOR H & T NEUTRAL BASE 57-55-6
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SCOTCH-CORE SC-250 K SYNTACTIC FILM 65997-17-3
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HT80-1-16 CARBOL-FUCHSIN SOLUTION 67-68-5
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67-63-0
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64-17-5
KX-72 BLACK TONER FOR TONER KIT 25767-47-9
1317-61-9
25085-53-4
UNOPETTE BRAND TEST
MICARTA 108-95-2
50-00-0
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