ing 15:several cases. resp support w/mech vent & positive vent:may be listed. refer to indus vent - a manual for rec eye prot:& full length faceshield . silica, crystalline - quartz; (silica, crystalline) antimony trioxide (sara 313) (cercla) titanium oxide; (titanium dioxide) ethylene glycol (sara 313) (cercla). vp:1 @ 20c. lel:3%. volatile organic compounds: less water & nprs - 0.83 supdat:rats revealed significant incr in benign & malignant ing 6:tio*2 dust. normal clearance mechs of lungs may have ing 7:have contributed to tumor form. these rslts may not ing 8:lims are observed. at tlv tio*2 mfr concludes that first aid proc:irrit persists. notes to md:principal tox ing 10:& metabolic acidosis. ethanol is antidotal & its ing 11:of ethylene glycol in liver. ethanol should be given ing 12:rate of about 10 ml ethanol per hr. desired ing 13:hemodialysis may be reqd. pulm edema w/hypoxemia has ing 14:w/ethylene glycol. mech of prod has not been
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INGEST:SWALLOWING OF ETHYLENE
GLYCOL MAY CAUSE ABDOM DISCOMFORT/PAIN, DIZZ, MALAISE, LUMBAR PAIN,
OLIGURIA, UREMIA & CNS DEPRESS. SEV KIDNEY DMG FOLLOWS SWALLOWING
OF LG VOLS OF ETHYLENE GLYCOL. MAY BE FATAL. INHAL:MAY CAUSE RESP
IRRIT. EYE:MAY CAUSE IRRIT. SKIN:MAY CAUSE DEFAT & IRRIT. CHRONIC:
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ:IARC
MONOGRAPHS, SUPP, VOL 7, PG 341, 1987:GRP 2A. NTP 7TH ANNUAL RPT ON
CARCINS, (SUPP DATA)
Effects of Overexposure:HLTH HAZ:RPTD & PRLNG OCCUP OVEREXP TO
CRYSTALLINE SILICA MAY CAUSE SILICOSIS, A PROGRESSIVELY DISABLING
LUNG DISEASE. ETHYLENE GLYCOL HAS BEEN SHOWN TO PRDCE DOSE-RELATED
BIRTH DEFECTS IN RATS & MICE WHEN GIVEN BY MOUTH AT HIGH CONCS.
BECAUSE THERE IS NO CURRENTLY AVAIL INFO TO SUGGEST THAT ETHYLENE
GLYCOL (SUPP DATA)
Medical Cond Aggravated by Exposure:PREEXISTING RESPIRATORY CONDITIONS
MAY BE AGGRAVATED BY EXPOSURE TO CRYSTALLINE SILICA.
======================= First Aid Measures =======================
First Aid:INGEST:IF SWALLOWED, IMMED GIVE 1-2 GLASSES OF WATER & CALL
POIS CTL CTR, HOSPITAL EMER ROOM/MD FOR WAY TO INDUCE VOMIT. (NEVER
GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERS). INHAL:REMOVE TO FRESH
AIR. EYES:FLUSH W/LG AMTS OF WATER, LIFTING UPPER & LOWER LIDS
OCCAS. CONTINUE FOR AT LST 15 MINS. GET MED ATTN. SKIN:REMOVE
CONTAM CLTHG. WASH AFFECTED AREA W/SOAP & WATER. OBTAIN MED ATTN IF
(ING 10)
===================== Fire Fighting Measures =====================
Lower Limits:SEE ING 4
Upper Limits:SEE ING 4
Extinguishing Media:USE NFPA CLASS A FIRE EXTINGS (WATER/MULTI PURPOSE
DRY CHEM) DESIGNED TO EXTING A NFPA CLASS A COMBUSTIBLE FIRE.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
Spill Release Procedures:CONFINE IN SMALL AREA; USE ABSORBENT TO CLEAN
UP. PLACE IN CONTAINER FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:PROTECT FROM FREEZING OR EXTREMELY
HIGH TEMPERATURES.
Other Precautions:DO NOT TAKE INTERNALLY. CLOSE CONTAINER AFTER EACH
USE. KEEP AWAY FROM CHILDREN. DO NOT BREATHE SANDING DUST.
Respiratory Protection:IF APPLIED BY SPRAYING, USE APPROPRIATE,
PROPERLY FITTED NIOSH/MSHA APPROVED RESPIRATOR TO REMOVE SPRAY
MIST. REFER TO OSHA 29 CFR 1910.134 "RESPIRATORY PROTECTION".
Ventilation:PROVIDE LOC EXHST VENT IN SUFFICIENT VOL & PATTERN SO AS TO
MAINTAIN EXPOS BELOW NUISANCE DUST LIMS & PELS WHICH(ING 17)
Protective Gloves:IMPERMEABLE GLOVES (NEOPRENE).
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(ING 18)
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . NOT LIKELY TO BE NEEDED.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLAN OF CARCIN:1994:ANTIC TO BE CARCIN. ANTIMONY TRIOXIDE:IARC
MONOGRAPHS ON EVAL OF CARCIN RISK OF CHEMS TO MAN, VOL 47, PG 291,
1989:GRP 2B. ANIMAL:NEOPLASTIC, CVS & LUNG EFTS. EFTS OF
OVEREXP:CAU SES BIRTH DEFECTS IN HUMANS, IT IS CONSIDERED ANIMAL
TERATOGEN. DRY TITANIUM DIOXIDE IN 24-MONTH INHAL STUDY W/ (ING 6)
Boiling Pt:B.P. Text:>162F,>72C
Vapor Pres:SEE ING 4
Vapor Density:HVR/AIR
Spec Gravity:1.3
Evaporation Rate & Reference:SLOWER THAN DIETHYL ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:63
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BURNING, INCLUDING WHEN HEATED BY
WELDING OR CUTTING, WILL PRODUCE SMOKE, CARBON MONOXIDE & CARBON
DIOXIDE.
Waste Disposal Methods:DISPOSE I/A/W FEDERAL, STATE & LOCAL LAWS. AS
PRODUCED, THIS PRODUCT IS NOT A WASTE. IF DISCARDED AS IS, IT IS
NOT CLASSIFIED A HAZARDOUS WASTE UNDER RCRA.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.