===================== Product Identification =====================
MSDS NAME:SODIUM HYPOCHLORITE, INDUSTRIAL
NIIN:00N068468
MSDS Number: CBHVN
=== Responsible Party ===
Company:EXCELEX CORP
Address:2929 STOREY LANE
City:DALLAS
State:TX
ZIP:75220
Country:US
Info Phone Num:214-352-5766
Emergency Phone Num:800-424-9300(CHEMTREC)
Preparer's Name:ALEX GASKA
CAGE:JO254
=== Contractor Identification ===
Company:EXCELEX CORP
Address:2929 STOREY LANE
City:DALLAS
State:TX
ZIP:75220
Country:US
Phone:214-352-5766
CAGE:JO254
============= Composition/Information on Ingredients =============
Name:SODIUM HYPOCHLORITE; (INDUSTRIAL BLEACH CONTAINING ING 2)
(CERCLA). BP:230F,110C. LD50:(ORAL,RAT) 5 G/KG BODY WT.
CAS:7681-52-9
RTECS #:NH3486300
Fraction by Wt: <13.06%
OSHA PEL:N/K
ACGIH TLV:N/K
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:SODIUM HYDROXIDE; (NAOH) (CERCLA). %:0.05-0.85.
CAS:1310-73-2
RTECS #:WB4900000
Fraction by Wt: <0.85%
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3, C
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:HNDLG/STOR PREC:BLEACH IF SPILLAGE OCCURS.
RTECS #:9999999ZZ
Name:OTHER PREC:HNDLG OF HOUSEHOLD BOTTLED BLEACH REQS SFTY
REQUIREMENTS AS STATED ON LBLS. FULL PROT SHOULD BE (ING 5)
RTECS #:9999999ZZ
Name:ING 4:PROVIDED WHEN HNDLG BULK SHIPMENTS OF CONC, INDUS
BLEACH SOLNS. EPA PESTICIDE REGS APPLIC & REGISTRATION (ING 6)
RTECS #:9999999ZZ
Name:ING 5:AS A PESTICIDE REQUIRED WHEN USED FOR DISINFECTION
PURPOSES. THIS PROD IS LISTED ON TOX SUBSTANCES CONTROL (ING 7)
RTECS #:9999999ZZ
Name:ING 6:ACT (TSCA) INVENTORY OF CHEMICAL SUBSTANCES.
CORROSIVE MATERIAL.
RTECS #:9999999ZZ
Name:EYE PROT:& FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ
Name:OTHER PROT EQUIP:FROM ANY SPLASHING CONDITIONS. USE RUBBER
PROTECTIVE SHOES IF SPILLS OCCUR.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:FUMES FROM SPILLS ARE VERY IRRITATING
TO MUCOUS MEMBRANES. VERY LITTLE HAZARD FROM PROPERLY STORED
SOLUTION. EYE CONTACT:SEVERE IRRITATION. SKIN CONTACT:IRRITANT,
REDDENING OF SKIN, SKIN DAMAGE. INGES TION:CAUSES IRRITATION OF
MEMBRANES OF MOUTH, THROAT & STOMACH PAIN & POSSIBLE ULCERATION.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYE:COPIOUS WASH W/WATER FOR AT LEAST 15 MINUTES. CONSULT
SPECIALIST IMMED. SKIN:WASH AFFECTED AREA W/PLENTY OF WATER. IF
IRRIT PERSISTS, CONTACT MD. INGEST:IF ACCIDENTALLY SWALLOWED, DRINK
WATER, MIL K & OBTAIN MED ATTN. DO NOT USE BAKING SODA OR ACIDIC
ANTIDOTES. INHAL:REMOVE PERSON TO FRESH AIR.
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
AVOID FUMES FROM SPILLED/EXPOS LIQ, DILUTE COPIOUSLY, VENTILATE.
ACID CONTAM WILL PRDCE VERY IRRIT (SUPDAT)
Unusual Fire/Explosion Hazard:BLEACH DECOMPOSES WHEN HEATED; DECOMP
PROD MAY CAUSE CNTNRS TO RUPTURE/EXPLODE. VIGOROUS RXN POSS W/ORG
MATLS/OXIDIZING AGENTS; MAY RSLT IN A FIRE.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH W/WATER TO DILUTE AS MUCH AS POSS, AVOID
HEAT & CONTAM W/ACID MATLS. DO NOT USE COMBUST MATLS SUCH AS
SAW-DUST TO ABSORB HYPOCHLORITE. AQUATIC TOX:NOT ESTABLISHED, BUT
IF NOT DILUTE MAY SERIOUSL Y AFFECT AQUATIC LIFE. DO NOT ALLOW
(SUPP DATA)
Neutralizing Agent:REDUCING AGENTS SUCH AS BISULFITES/FERROUS SALT
SOLNS; SOME HEAT WILL BE PRDCD.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN VENTED, CLSD, CLEAN, NON-CORR
CNTNRS IN COOL, DRY LOCATION, AWAY FROM DIRECT SUNLIGHT & NOT
ADJACENT TO CHEMS WHICH MAY REACT W/ (ING 3)
Other Precautions:IF SHIPPED, MUST COMPLY W/DOT, ETC, SHIPPING REGS
W/CLSD CNTNRS BECOME HEATED, CNTNRS SHOULD BE VENTED TO RELS DECOMP
PRODS (MAINLY OXYG UNDER NORMAL DECOMP). DO NOT MIX/CONTAM
W/AMMONIA, HYDROCARBONS , ACIDS, ALCOHOLS, ETHERS. NORMAL(ING 4)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHEN FUMES ARE PRESENT USE NIOSH/MSHA APPROVED
RESPIRATOR W/ACID TYPE CANISTER.
Ventilation:NO SPECIAL VENT REQUIRED UNLESS BLEACH IS EXPOSED TO DECOMP
CNDTN; I.E., SPILLS OR ACIDIC CONDITIONS.
Protective Gloves:RUBBER OR PLASTIC GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS (ING 8)
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . USE RUBBER APRON, ETC TO PROT BODY (ING 9)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
SPEC GRAV:50 GPL:1.08; 100 GPL:1.14; 140 GPL:1.21 (H*2O=1). %
VOLAT:VARIABLE - WATER VAP PLUS PRODS OF DECOMP. FIRE FIGHT
PROC:FUMES SIMILAR TO CHLORINE GAS. HAZ DECOMP PROD:PRODS, WHICH
DEPENDS UPON PH, TEMP & TIME, ARE SODIUM CHLORIDE, SODIUM CHLORATE
& OXYG. SPILL PROC:SPILLED MATL TO ENTER SEWERS/STREAMS.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:230F,110C
Spec Gravity:SUPP DATA
pH:12
Solubility in Water:COMPLETE
Appearance and Odor:LIGHT YELLOW-GREEN; PUNGENT LIKE CHLORINE.
Percent Volatiles by Volume:SUPDAT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTAM W/HEAVY METALS (ACT AS CATALYSTS), REDUCING AGENTS,
ORGANICS, ETHER, AMMONIA, ACIDS.
Stability Condition to Avoid:STABILITY DECR W/CONC, HEAT, LIGHT EXPOS,
DECR IN PH & CONTAM W/HEAVY METALS, SUCH AS, NICKEL, COBALT, COPPER
& IRON.
Hazardous Decomposition Products:HYPOCHLOROUS ACID (HOCL), CHLORINE,
HYDROCHLORIC ACID. COMPOSITION DEPENDS UPON TEMP & DECR IN PH.
ADDNL DECOMP (SUPDAT)
==================== Disposal Considerations ====================
Waste Disposal Methods:REDUCE W/CHEMICALS LISTED AS NEUTRALIZERS. KEEP
ON ALKALINE SIDE & DILUTE W/COPIOUS QUANTITIES OF WATER. MAIN END
PROD IS SALT WATER. (NACL) DISPOSE OF I/A/W LOCAL, STATE & FEDERAL
REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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