=====================  Product Identification  =====================

MSDS NAME:TPH-5M, DIESEL RANGE ORGANICS 1-GRO/DRO IN (SUPDAT)
NIIN:00N070356
MSDS Number: CBLQT
=== Responsible Party ===
Company:CHEM SERVICE INC
Box:3108
City:WEST CHESTER
State:PA
ZIP:19381
Country:US
Info Phone Num:610-692-3026
Emergency Phone Num:610-692-3026
CAGE:84898
=== Contractor Identification ===
Company:CHEM SERVICE INC
Box:3108
City:WEST CHESTER
State:PA
ZIP:19381
Country:US
Phone:215-692-3026
CAGE:84898
Company:CHEM SERVICE, INC
Address:660 TOWER LN
Box:599
City:WEST CHESTER
State:PA
ZIP:19301-9650
Country:US
Phone:610-692-3026
CAGE:8Y898

=============  Composition/Information on Ingredients  =============

Name:METHANE, DICHLORO-; (METHYLENE CHLORIDE) (SARA 313)
    (CERCLA)   LD50: (ORAL, RAT) 2136 MG/KG
CAS:75-09-2
RTECS #:PA8050000
OSHA PEL:500 PPM
ACGIH TLV:50 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Name:DECANE; (N-DECANE) %WT: 2000  G/ML
CAS:124-18-5
RTECS #:HD6550000
Fraction by Wt: <0.1%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Name:TETRADECANE; (N-TETRADECANE) %WT: 2000  G/ML
CAS:629-59-4
RTECS #:XB8000000
Fraction by Wt: <0.1%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Name:N-OCTADECANE %WT: 2000  G/ML
CAS:593-45-3
Fraction by Wt: <0.1%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Name:DOCOSANE; (N-DOCOSANE) %WT: 2000  G/ML
CAS:629-97-0
Fraction by Wt: <0.1%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Name:HEXACOSANE; (N-HEXACOSANE) %WT: 2000  G/ML
CAS:630-01-3
Fraction by Wt: <0.1%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Name:DODECANE; (N-DODECANE) %WT: 2000  G/ML
CAS:112-40-3
RTECS #:JR2125000
Fraction by Wt: <0.1%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Name:HEXADECANE; (N-HEXADECANE) %WT: 2000  G/ML
CAS:544-76-3
RTECS #:ML9200000
Fraction by Wt: <0.1%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Name:EICOSANE; (N-EICOSANE) %WT: 2000  G/ML
CAS:112-95-8
Fraction by Wt: <0.1%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Name:N-TETRACOSANE %WT: 2000  G/ML
CAS:646-31-1
Fraction by Wt: <0.1%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Name:N-OCTACOSANE %WT: 2000  G/ML
CAS:630-02-4
Fraction by Wt: <0.1%
OSHA PEL:N/K 
ACGIH TLV:N/K 

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:SEE INGREDIENT 1
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:YES    IARC:YES	  OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATERIALS HAVE PRODUCED
    SENSITIZATION OF THE MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS &
    COULD HAVE A SIMILAR EFFECT IN HUMANS. ADRENOMIMETICS (EG,
    EPINEPHRINE) MAY BE CONTRA-INDICATED EXC EPT FOR LIFE-SUSTAINING
    USES IN HUMANS ACUTELY/CHRONICALLY EXPOSED TO CHLOROCARBONS . ALL 
    (EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE: IARC MONO, SUPP, VOL
    7, PG 194, 1987;GROUP 2B. NTP 7TH ANNUAL REPORT ON CARCINS,
    1994:ANTIC TO BE CARCIN. ANIMAL: LUNG, LIVER, SALIVARY, MAMMARY
    GLAND (TUMORS).
Effects of Overexposure:HLTH HAZ: CHEMS SHOULD BE CONSIDERED HAZ. AVOID
    DIRECT PHYSICAL CONTACT! METHYLENE CHLORIDE: MAY BE HARMFUL BY
    INHAL, INGEST OR SKIN ABSORPTION. CAN CAUSE EYE IRRIT. CAN CAUSE
    SKIN IRRIT. DUST &/OR VA PS CAN CAUSE IRRIT TO RESP TRACT. CAN BE
    IRRIT TO MUC MEMBS. EXPOSURE CAN CAUSE LIVER DAMAGE.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:ANTIDOTE IS SUBSTANCE INTENDED TO COUNTERACT EFT OF POISON.
    IT SHOULD BE ADMIN ONLY BY MD/TRAINED EMER PERS. MED ADVICE CAN BE
    OBTAINED FROM POIS CTL CTR. EYES: FLUSH CONTINUOUSLY W/WATER FOR AT
    LEAST  15-20 MIN. SKIN: FLUSH W/WATER FOR 15-20 MIN. IF NO BURNS
    HAVE OCCURRED-USE SOAP & WATER TO CLEANSE SKIN. INHAL: REMOVE TO
    FRESH AIR. ADMIN OXYGEN IF HAVING DFCLTY BRTHG. IF BRTHG HAS
    STOPPED ADMIN A RTF RESP. IF IN CARD ARREST ADMIN CPR. CONTINUE
    LIFE SUPPORT MEASURES UNTIL MED ASSIST HASARRIVED. REMOVE & WASH
    CONTAMD CLTHG. IF EXHIBITING SIGNS OF SHOCK - KEEP WARM & QUIET.
    CONT POIS CTR IMMED IF  NEC. DO NOT ADMIN LIQS OR (SUP DAT)

=====================  Fire Fighting Measures  =====================

Flash Point:NON-FLAMMABLE
Lower Limits:13.0%
Upper Limits:23.0%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
    AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
    INCLUDE HCL AND PHOSGENE .

==================  Accidental Release Measures  ==================

Spill Release Procedures:EVACUATE AREA. WEAR APPROPRIATE OSHA REGULATED
    EQUIP. VENTILATE AREA. ABSORB ON VERMICULITE OR SIMILAR MATERIAL.
    SWEEP UP & PLACE IN AN APPROPRIATE CONTAINER. HOLD FOR DISPOSAL.
    WASH CONTAMINATED SURF ACES TO REMOVE ANY RESIDUES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:AVOID CONTACT W/SKIN, EYES & CLTHG. DO
    NOT BREATHE VAPS. KEEP TIGHTLY CLOSED. STORE UNDER REFRIGERATION.
    STORE ONLY WITH COMPATIBLE CHEMICALS.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
    VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
    UV RADIATION MAY CAUSE THE FORMATION OF HCL AND/OR PHOSGENE .

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:USE APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:THIS CHEMICAL SHOULD BE HANDLED ONLY IN A HOOD.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . USE
    APPROPRIATE OSHA/MSHA APPROVED SAFETY EQUIPMENT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
TRADE NAME/PART #: METHYLENE CHLORIDE. FIRST AID PROC: INDUCE VOMIT TO
    UNCON OR CONVULSING PERS. IF VOMIT-WATCH CLOSELY TO MAKE SURE
    AIRWAY DOES NOT BECOME OBSTRUCTED BY VOMIT. GET MED ATTN IF NEC.

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:104F,40C
Melt/Freeze Pt:M.P/F.P Text:-139F,-95C
Vapor Pres:350 @ 20C
Vapor Density:2.9
Spec Gravity:1.3255
Evaporation Rate & Reference:27.5 (BUTYL ACETATE=1)
Solubility in Water:SLIGHTLY SOLUBLE
Appearance and Odor:COLORLESS LIQUID; ETHER LIKE ODOR.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
METHYLENE CHLORIDE: INCOMPATIBLE WITH STRONG BASES. INCOMPATIBLE WITH
    STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:SENSITIVE TO HEAT. DO NOT USE
    MAGNESIUM/ALUMINUM OR THEIR ALLOYS AS CONTAINERS.
Hazardous Decomposition Products:HCL, PHOSGENE . DECOMPOSITION
    LIBERATES TOXIC FUMES. DECOMPOSITION PRODUCTS ARE CORROSIVE.
    VOLATILE.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
    STATE AND LOCAL REGULATIONS . BURN IN A CHEMICALS INCINERATOR
    EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.

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