===================== Product Identification =====================
MSDS NAME:LESS THAN 500 PPM CARBON MONOXIDE, LESS (SUPDAT)
NIIN:00N073537
MSDS Number: CCNVP
=== Responsible Party ===
Company:AIR LIQUIDE AMERICA CORP
Address:2121 N CALIFORNIA BLVD
City:WALNUT CREEK
State:CA
ZIP:94596
Country:US
Info Phone Num:415-977-6500
Emergency Phone Num:800-231-1355:800-424-9300(CHEMTREC)
CAGE:AIRLI
=== Contractor Identification ===
Company:AIR LIQUIDE AMERICA CORPORATION
Box:3047
City:HOUSTON
State:TX
ZIP:77253
Country:US
Phone:713-896-2140
CAGE:AIRLI
Company:LIQUID AIR CORP ONE CALIFORNIA PLAZA
Address:2121 N. CALIFORNIA BLVD
Box:City:WALNUT CREEK
State:CA
ZIP:94596
Country:US
Phone:415-977-6500
CAGE:18260
============= Composition/Information on Ingredients =============
Name:CARBON MONOXIDE (CO) BP:-312.75F (-191.53C) <500 PPM
CAS:630-08-0
RTECS #:FG3500000
OSHA PEL:50 PPM
ACGIH TLV:25 PPM; 9495
Name:METHANE (CH*4) BP:-258.6F (-161.4C)
CAS:74-82-8
RTECS #:PA1490000
Fraction by Wt: <2.5%
OSHA PEL:N/K
ACGIH TLV:ASPHYXIANT; 9495
Name:OXYGEN (O*2) BP:-297.3F (-182.9C)
CAS:7782-44-7
RTECS #:RS2060000
Fraction by Wt: 18-21%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:NITROGEN (N*2) BP: -320.5F (-195.8C)
CAS:7727-37-9
RTECS #:QW9700000
Fraction by Wt: BALANCE
OSHA PEL:N/K
ACGIH TLV:ASPHYXIANT; 9495
Name:FIRST AID PROC:ADMINISTERING OF THE OXYGEN AT AN ELEVATED
PRES (UP TO 2.5 ATM) HAS SHOWN TO BE BENEFICIAL AS (ING 6)
RTECS #:9999999ZZ
Name:ING 5:HAS TREATMENT IN A HYPERTONIC CHAMBER. THE MD SHOULD
BE INFORMED THAT THE PATIENT HAS INHALED CARBON MONOXIDE.
RTECS #:9999999ZZ
Name:WASTE DISP METH:FOR EMERGENCY DISPOSAL, CONTACT THE CLOSEST
LIQUID AIR CORPORATION LOCATION. DISPOSAL MUST BE (ING 8)
RTECS #:9999999ZZ
Name:ING 7:IN ACCORDANCE WITH FEDERAL, STATE & LOCAL REGULATIONS
RTECS #:9999999ZZ
Name:HNDLG/STOR PREC:THE DISCHARGE RATE OF PRODUCT FROM THE
CYLINDER. USE A CHECK VALVE OR TRAP IN THE DISCHARGE LINE(ING 10)
RTECS #:9999999ZZ
Name:ING 9:TO PVNT HAZ BACK FLOW INTO THE CYLINDER. CLOSE VALVE
AFTER EACH USE & WHEN EMPTY. PROTECT CYLINDERS FROM (ING 11)
RTECS #:9999999ZZ
Name:ING 10:PHYSICIAL DMG. STORE IN COOL, DRY, WELL-VENT AREA
AWAY FROM HEAVILY TRAFFICKED AREAS & EMER EXITS. DO NOT(ING 12)
RTECS #:9999999ZZ
Name:ING 11:ALLOW TEMP WHERE CYLINDERS ARE STORED TO EXCEED 125F
(52C). FULL & EMPTY CYLINDERS SHOULD BE SEGREGATED. (ING 13)
RTECS #:9999999ZZ
Name:ING 12:USE A "FIRST IN - FIRST OUT" INVENTORY SYS TO
PREVENT FULL CYLINDERS BEING STORED FOR EXCESSIVE PERIODS (ING 14)
RTECS #:9999999ZZ
Fraction by Wt: NO
Name:ING 13:OF TIME. THESE MIXTURES ARE NONCORROSIVE & MAY BE
USED WITH ALL MATERIALS OF CONSTRUCTION. MOISTURE (ING 15)
RTECS #:9999999ZZ
Name:ING 14:CAUSES METAL OXIDES WHICH ARE FORMED WITH AIR TO BE
HYDRATED SO THAT THEY INCREASE IN VOLUME AND LOSE (ING 16)
RTECS #:9999999ZZ
Name:ING 15:THEIR PROTECTIVE ROLE (RUST FORMATION).
CONCENTRATIONS OF SO*2, CL*2, SALT, ETC. IN THE MOISTURE (ING 17)
RTECS #:9999999ZZ
Name:ING 16:ENHANCES THE RUSTING OF METALS IN AIR. DOT 39
CYLINDER MAY NOT BE REUSED OR REFILLED (49 CFR). NEVER (ING 18)
RTECS #:9999999ZZ
Name:ING 17:TRANSPORT THESE CYLINDERS IN TRUNKS OF VEHICLES,
ENCLOSED VANS, TRUCK CABS/IN PASSENGER COMPARTMENTS. (ING 19)
RTECS #:9999999ZZ
Name:ING 18:TRANSPORT THEM "CONTAINED" IN OPEN FLATBED OR OPEN
PICK-UP TYPE VEHICLES.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CARBON MONOXIDE APPEARS ON THE NAVY
LISTING OF OCCUP CHEM REPROD HAZ. SEEK CONSULTATION FROM APPROP
HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG &
EXPOS INFO . BRTHG THIS GAS MIX FOR SEVERAL HR COULD CAUSE SLIGHT
HDCH & POSSIBILY SLIGHT, DIZZ & DISCOMFORT. CARBON MONOXIDE IS
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:COLORLESS & ODORLESS SO THAT THERE IS
NO WARNING OF ITS PRESENCE. CARBON MONOXIDE ACTS AS A CHEM
ASPHYXIANT BY REDUCING THE OXYGEN TRANSPORT PROPERTIES OF THE
BLOOD. IT REACTS W/HEMOGLOBIN FO RMING CARBOXYHEMOGLOBIN THUS
PREVENTINGTHE HEMOGLOBIN FROM TRANSPORTING OXYGEN. PERSONS IN ILL
HEALTH WHERE (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:PROMPT MED ATTN MANDATORY IN ALL CASES OF OVEREXP TO CARBON
MONOXIDE. INGEST:CALL MD IMMED . EYES:IMMED FLUSH W/PORTABLE H*2O
FOR A MIN OF 15 MIN, SEEK ASSISTANCE FROM MD . SKIN:FLUSH W/CO
PIOUS AMTS OF H*2O. CALL MD . INHAL:CONSCIOUS PERS SHOULD BE
ASSISTED TO AN UNCONTAMINATED AREA & BE TREATED W/SUPP OXYGEN.
QUICK REMOVAL FROM THE CONTAMD AREA IS MOST IMPORTANT. THE (ING 5)
===================== Fire Fighting Measures =====================
Extinguishing Media:NONFLAMMABLE GAS MIXTURES. MEDIA SUITABLE FOR
SURROUNDING FIRE
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . IF CYLINDERS ARE INVOLVED IN A FIRE, SAFELY RELOCATE OR
KEEP COOL WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:THESE MIXTURES AT HIGH PRESSURES WILL
ACCELERATE THE BURNING OF MATERIALS TO A GREATER RATE THAN THEY
BURN AT ATMOSPHERIC PRESSURE.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE ALL PERSONNEL FROM AFFECTED AREA. USE
APPROPRIATE PROTECTIVE EQUIPMENT. IF LEAK IS IN CONTAINER OR
CONTAINER VALUE, CONTACT THE CLOSEST LIQUID AIR CORPORATION
LOCATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:USE A PRESS REDUCING REGULATOR WHEN
CONNECTING CYLINDER TO LOWER PRESS (<500 PSIG) PIPING/SYS. DO NOT
HEAT CYLINDER BY ANY MEANS TO INCREASE (ING 9)
Other Precautions:NEVER TRANSPORT THESE CYLS IN TRUCKS OF VEHICLES,
ENCLSD VANS, TRUCK CABS/IN PASSANGER COMPARTMENTS. TRANSPORT THEM
"CONTAINED" IN OPEN FLATBED/OPEN PICK-UP TYPE VEHICLES. REPORTING
UNDER SARA, TITLE III, SECTION 313 NOT REQUIRED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:POSITIVE PRESSURE AIR LINE WITH NIOSH APPROVED
MASK OR SELF-CONTAINED BREATHING APPARATUS SHOULD BE AVAILABLE FOR
EMERGENCY USE.
Ventilation:HOOD WITH FORCED VENTILATION. LOCAL EXHAUST: TO PREVENT
ACCUMULATION ABOVE THE TWA FOR CARBON MONOXIDE.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA. . SAFETY SHOES.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR'S TRADE NAME/PART #: THAN 2.5% METHANE AND 18-21% OXYGEN IN
NITROGEN. VP: 70F (21.1C)=ABOVE THE CRITICAL TEMPERATURES FOR ALL
COMPONENTS. SPEC GRAV: 0.980-0.992 @ 70F (21.1C). EFTS OF OVEREXP:
SUC H ILLNESS WOULD BE AGGRAVATED BY EXPOS TO THESE MIX SHOULD NOT
BE ALLOWED TO WORK W/HNDL THESE PRODS.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:SEE INGREDS
Vapor Pres:SUPDAT
Spec Gravity:SUPDAT
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS, ODORLESS GAS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:DO NOT ATTEMPT TO DISPOSE OF WASTE/UNUSED
QUANTITIES. RETURN IN THE SHIPPING CONTAINER PROPERLY LABELED, WITH
ANY VALVE OUTLET PLUGS/CAPS SECURED & VALVE PROTECTION CAP IN PLACE
TO LIQUID AIR CORPORAT ION FOR PROPER DISPOSAL. (ING 7)
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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