===================== Product Identification =====================
MSDS NAME:458481, VENTILATION SMOKE TUBE KIT
NIIN:00N073577
MSDS Number: CCNXC
=== Responsible Party ===
Company:MINE SAFETY APPLIANCES CO
Box:426
City:PITTSBURGH
State:PA
ZIP:15230
Country:US
Info Phone Num:412-967-3000
Emergency Phone Num:412-967-3000
CAGE:8F723
=== Contractor Identification ===
Company:MINE SAFETY APPLIANCES CO
Address:121 GAMMA DR
Box:426
City:PITTSBURGH
State:PA
ZIP:15230-0426
Country:US
Phone:724-733-9270
CAGE:8F723
============= Composition/Information on Ingredients =============
Name:AMPOULE #1 CONSISTING OF INGS # 2 & 4. APPEAR/ODOR:WHITE
GRANULES, VINEGAR ODOR.
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ACETIC ACID (CERCLA). BP:103F,39C. SPEC GRAV:1.05 (H*2O=1).
VP:14.8 @ 20C. SOL IN H*2O:SOLUBLE. FL PT:103F,39C. (ING 3)
CAS:64-19-7
RTECS #:AF1225000
Fraction by Wt: 50%
OSHA PEL:10 PPM
ACGIH TLV:10 PPM/15 STEEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ING 2:LEL:4%. UEL:19.9%. LD50:(ORAL,RAT) 3310 MG/KG
RTECS #:9999999ZZ
Name:SILICA GEL
CAS:63231-67-4
RTECS #:VV7322000
Fraction by Wt: 50%
OSHA PEL:80 MG/M3 / % SIO2
ACGIH TLV:10 MG/M3
Name:AMPOULE #2 CONSISTING OF INGS 6 & 8. APPEAR/ODOR:GRAY TO
BLACK GRANULES, AMMONIA ODOR.
OSHA PEL:N/K
ACGIH TLV:N/K
Name:1,2-ETHANEDIAMINE; (1,2 DIAMINOETHANE) (SARA 302) (CERCLA).
BP:93.0F,33.9C. SPEC GRAV:0.90 (H*2O=1). VP:10 @ 20C.(ING 7)
CAS:107-15-3
RTECS #:KH8575000
Fraction by Wt: 50%
OSHA PEL:10 PPM
ACGIH TLV:S, 10 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ING 6:SOL IN H*2O:SOLUBLE. FL PT:93.0F,33.9C. LEL:4.2%.
UEL:14.%. LD50:(ORAL,RAT) 1160 MG/KG
RTECS #:9999999ZZ
Name:PUMICE
CAS:1332-09-8
Fraction by Wt: 50%
OSHA PEL:10 PPM (MFR)
ACGIH TLV:10 MG/M3 (MFR)
Name:SUPDAT:BOTH AMPOULES W/IN TUBE ARE CRUSHED. IF BOTH
AMPOULES ARE CRUSHED, PLACE TUBE W/CONTENTS INTO BUCKET (ING 10)
RTECS #:9999999ZZ
Name:ING 9:SO THAT TUBE IS IMMERSED. IF TUBE CNTNS UNBROKEN
AMPOULE, CRUSH IT (W/IN TUBE) & IMMERSE TUBE & ITS (ING 11)
RTECS #:9999999ZZ
Name:ING 10:CONTENTS IN BUCKET. IF UNBROKEN AMOULE HAS BEEN
RELEASED FROM TUBE, REPLACE IT IN TUBE, CRUSH IT (ING 12)
RTECS #:9999999ZZ
Name:ING 11:(W/IN TUBE), & IMMERSE TUBE W/CONTENTS IN BUCKET. IN
ALL CASES LET TUBE SOAK OVERNIGHT. PUT ON RUBB (ING 13)
RTECS #:9999999ZZ
Name:ING 12:GLOVES & SPLASHPROOF GOGGS. FILTER SOLIDS FROM WATER
& DISPOSE TO TRASH. FILTERED WATER CAN BE RELEASED TO DRAIN.
RTECS #:9999999ZZ
Name:OTHER PREC:APPROX 0.4 GMS ACETIC ACID SORBED ON SILICA GEL
& 1 W/APPROX 0.3 GMS ETHYLENEDIAMINE SORBED ON (ING 15)
RTECS #:9999999ZZ
Name:ING 14:PUMICE. WHEN AMPOULES ARE MANUALLY CRUSHED,
ASPIRATED AIR FLOW CAUSES MIXING OF RELEASED VAPS WHICH (ING 16)
RTECS #:9999999ZZ
Name:ING 15:REACT FORMING ETHYLENEDIAMINE ACETATE SMOKE. NO TLV
IS LISTED FOR ETHYLENEDIAMINE ACETATE.
RTECS #:9999999ZZ
Name:EYE PROT:& FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS 1 & 4
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:ACETIC ACID:IRRITATION OF EYES,
MUCOUS MEMBRANES, SKIN. SPLASHES PRODUCE EYE & SKIN BURNS.
INGESTION OF 1 CM*3 GLACIAL ACID PRODUCED PERFORATION OF THE
ESOPHAGUS. ETHYLENEDIAMINE:IRRITATION OF E YE, MUCOUS MEMBRANES,
SKIN. TARGET ORGANS:ACETIC ACID:EYES, NOSE THROAT, SKIN.
ETHYLENEDIAMINE:EYES, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:NOSE, THROAT, SKIN, LIVER, KIDNEYS.
CHRONIC:NONE LISTED BY MANUFACTURER.
Medical Cond Aggravated by Exposure:NO INFORMATION.
======================= First Aid Measures =======================
First Aid:SKIN:FLUSH W/COPIOUS AMTS OF WATER. CALL MD . INHAL:REMOVE
VICTIM FROM EXPOS. IF BRTHG IS DFCLT, ADMIN OXYG. GET MED ATTN
IMMED. IF BRTHG HAS STOPPED, GIVE ARTF RESP. GET MED ATTN IMMED.
EYES:RE MOVE VICTIM FROM EXPOS. FLUSH W/WATER FOR @ LST 15 MINS
HOLDING EYES OPEN & RAISING EYELIDS TO FLUSH UNDERLID AREAS. SEE
PHYS IMMED. INGEST:IF TUBE CONTENTS ARE SOME HOW INGESTED & IF
VICTIM (SUPDAT)
===================== Fire Fighting Measures =====================
Flash Point:93.0F,33.9C
Lower Limits:INGS 1 & 4
Upper Limits:ING 1 & 4
Extinguishing Media:AS NEEDED FOR SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:AMPOULES MAY RUPTURE AND EMIT TOXIC FUMES
UNDER FIRE CONDITIONS. ACETIC ACID:COMBUST LIQ (SORBED ON INERT
SOLID). ETHYLENEDIAMINE:FLAMM LIQ (SORBED ON (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:IF CONTENTS OF TUBE ARE RELEASED, AVOID SKIN
CONT W/SPILLED MATL. LEAVE IMMED AREA IF SMOKE IS GENERATED UNTIL
SMOKE SUBSIDES. FILL BUCKET 3/4 FULL OF WATER. PUT ON RUBB GLOVES &
SPLASHPROOF GOGGS. SW EEP UP SPILLED MATL & PLACE SWEEPINGS IN
(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY LOCATION PROTECTED
FROM CRUSHING & IMPACT FORCES. PROD IS FOR USE IN DETERMINATION OF
DIRECTION & VELOCITY OF VENT AIR CURRENTS.
Other Precautions:AVOID BRTHG EMISSIONS FROM TUBE. AVOID BRTHG TUBE
EFFLUENT. TUBE EFFUENT CNTNS ETHYLENEDIAMINE ACETATE SMOKE & MAY
CNTN RESIDUAL VAPS OF ACETIC ACID & ETHYLENEDIAMINE. NOTE:EACH
FLEXIBLE TUBE CNTNS 2 SEALED GLASS AMPOULES, 1 WITH (ING 14)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 17)
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WASH HANDS AFTER USING PRODUCT.
Supplemental Safety and Health
EXPLO HAZ:INERT SOLID). NOTE:COMPONENTS ARE SORBED ON INERT SOLIDS.
TOTAL AMT OF COMBUST/FLAMM MATL IS <1 GM PER TUBE. AMPOULES ARE
SEALED UNTIL TIME OF ACTUAL USE. FIRST AID PROC:IS CONSCIOUS, GIVE
2 GLASSES OF WATER TO DILUTE CHEM. GET MED ATTN IMMED. SPILL
RELEASE PROC:BUCKET. EXAMINE TUBE TO BE SURE (ING 9)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:INGS 1&4
Vapor Pres:INGS 1&4
Spec Gravity:INGS 1&4
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:SEE INGS 1 & 4
Appearance and Odor:SEE INGREDIENTS 1 & 4
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID ACIDS, BASES, OXIDIZERS.
Stability Condition to Avoid:AVOID ACIDS, BASES, OXIDIZERS.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:TAPE OVER ENDS OF EXHAUSTED TUBES AND DISPOSE IN
ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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