===================== Product Identification =====================
MSDS NAME:FERROUS SULFATE, C342K20
NIIN:00N073541
MSDS Number: CCNVS
=== Responsible Party ===
Company:MALLINCKRODT BAKER INC
Address:222 RED SCHOOL LN
City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Info Phone Num:800-582-2537
Emergency Phone Num:908-859-2151;800-424-9300(CHEMTREC)
CAGE:HO851
=== Contractor Identification ===
Company:MALLINCKRODT BAKER INC
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:HO851
Company:MALLINCKRODT BAKER, INC.
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:70829
============= Composition/Information on Ingredients =============
Name:IRON (II SULFATE (1:1); (FERROUS SULFATE) (CERCLA)
CAS:7720-78-7
RTECS #:NO8500000
Fraction by Wt: 100%
OSHA PEL:1 MG (FE)/M3
ACGIH TLV:1 MG (FE)/M3
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:RESP PROT:APPRVD AIR-PURIFYING RESPS DO NOT PROTECT WORKERS
IN OXYG-DEFICIENT ATMOSPHERES.
RTECS #:9999999ZZ
Name:VENT:GENERALLY PREFERRED BECAUSE IT CAN CONTROL EMISSIONS
OF CONTAMINANT AT ITS SOURCE, PREVENTING DISPERSION OF (ING 4)
RTECS #:9999999ZZ
Name:ING 3:IT INTO GENERAL WORK AREA. PLEASE REFER TO ACGIH
DOCUMENT, "INDUST VENT, A MANUAL OF REC PRACTICES", MOST (ING 5)
RTECS #:9999999ZZ
Name:ING 4:RECENT EDITION, FOR DETAILS.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,MOUSE) 1520 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHALATION:EXCESSIVE INHALATION
OF DUST MAY BE IRRITATING TO RESPIRATORY TRACT. INGESTION:LOW
TOXICITY IN SMALL QUANTITIES BUT LARGER DOSAGES MAY CAUSE NAUSEA,
VOMITING, DIARRHEA, & BLACK STOOL. PINK URINE DISCOLORATION IS
STRONG INDICATOR OF IRON POISONING. LIVER DAMAGE, COMA, & DEATH
FROM (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:IRON POISONING HAS BEEN RECORDED.
SMALLER DOSES ARE MUCH MORE TOX TO CHILDREN. SKIN:MAY CAUSE MILD
IRRITATION. EYE:CONT MAY CAUSE IRRITATION, REDNESS, & PAIN.
CHRONIC:SEVERE/CHRONIC FERROUS S ULFATE POISONINGS MAY DAMAGE BLOOD
VESSELS. LARGE CHRONIC DOSE CAUSE RICKETTS IN INFANTS.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS OR EYE PROBLEMS, OR IMPAIRED LIVER, KIDNEY OR RESPIRATORY
FUNCTION MAY BE MORE SUSECEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR. GET MED ATTN FOR ANY BRTHG DFCLTY.
INGEST:INDUCE VOMIT IMMED AS DIRECTED BY MED PERSONNEL. NEVER GIVE
ANYTHING BY MOUTH TO UNCON PERSON. SKIN:WASH EXPOSED AREA W/SOAP &
WATE R. GET MED ADVICE IF IRRIT DEVELOPS. EYE:IMMED FLUSH W/PLENTY
OF WATER FOR @ LST 15 MINS. CALL PHYS.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING
SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE A FIRE OR EXPLOSION
HAZARD.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA OF LEAK/SPILL. WEAR APPROP
PERSONAL PROT EQUIP AS SPECIFIED IN CONTROL & PROT MEASURES
SECTION. PICK UP & PLACE IN SUITABLE CNTNR FOR RECLAMATION/DISP,
USING METH THAT DOES NOT GENERATE DUST. WHATEVER CANNOT BE SAVED
FOR (SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP IN TIGHTLY CLSD CNTNR, STORED IN
COOL, DRY, VENTILATED AREA. PROJECT AGAINST PHYSICAL DMG. ISOLATE
FROM INCOMPAT SUBSTANCES.
Other Precautions:CNTNRS OF THIS MATL MAY BE HAZ WHEN EMPTY SINCE THEY
RETAIN PROD RESIDUES (DUST, SOLIDS); OBSERVE ALL WARNINGS & PRECS
LISTED FOR PROD. WARNING!MAY BE HARMFUL IF SWALLOWED. MAY CAUSE EYE
IRRIT. AVOID CONT W/EYES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOS LIM IS EXCEEDED, NIOSH APPRVD DUST/MIST
RESP MAY BE WORN FOR UP TO 10 TIMES EXPOS LIM. FOR EMER OR
INSTANCES WHERE EXPOS LEVS ARE NOT KNOWN, USE NIOSH APPRVD
POSITIVE-PRESS, AIR-SUPPLIED RESP . WARNING:NIOSH (ING 2)
Ventilation:SYS OF LOC &/OR GEN EXHAUST IS REC TO KEEP EMPLOYEE EXPOS
BELOW AIRBORNE EXPOS LIMS. LOC EXHAUST VENT IS (ING 3)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:CLEAN BODY-COVERING CLOTHING. ANSI APPRVD
EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
BP:DECOMPOSES AT >572F,>300C. MP:LOSES WATER @ 65C(149F). SOL IN
H*2O:48.6 G/100 G WATER @ 50C (122F). SPILL RELEASE
PROC:RECOVERY/RECYCLING SHOULD BE MANAGED IN APPROP & APPRVD WASTE
DISP FACILITY. P ROCESSING, USE/CONTAM OF PROD MAY CHANGE WASTE
MANAGEMENT OPTIONS, STATE & LOC DISP REGS MAY DIFFER FROM FED DISP
REGS.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:SUPDAT
Melt/Freeze Pt:M.P/F.P Text:SUPDAT
Spec Gravity:1.00
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:SUPP DATA
Appearance and Odor:BLUE-GREEN FINE CRYSTALS, ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALIES, SOLUBLE CARBONATES, & OXIDIZING MATLS. REACTS IN MOIST AIR TO
FORM FERRIC SULFATE.
Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE
AND STORAGE.
Hazardous Decomposition Products:WHEN HEATED TO DECOMPOSITION IT EMITS
TOXIC FUMES OF SULFUR OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE CONTAINER AND UNUSED CONTENTS IN
ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REQUIREMENTS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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