===================== Product Identification =====================
MSDS NAME:GLYCOL ETHER EB;ETHYLENE GLYCOL MONOBUTYL ETHER;BUTYL GLYCOL
NIIN:00-281-2001
MSDS Number: CDMKC
=== Responsible Party ===
Company:OCCIDENTAL CHEMICAL CORPORATION
Address:CUSTOMER SERVICE, OCCIDENTAL TOWER
Box:809050
City:DALLAS
State:TX
ZIP:75380
Country:US
Info Phone Num:800-752-5151/MSDS:716-286-3400
Emergency Phone Num:800-733-3665/716-278-7021
CAGE:0AH54
=== Contractor Identification ===
Company:OCCIDENTAL CHEMICAL CORPORATION
Address:5005 LYNDON B JOHNSON FWY
Box:City:DALLAS
State:TX
ZIP:75244-6198
Country:US
Phone:800-752-5151/972-404-3800
CAGE:0AH54
Company:UNI-KEM INTERNATIONAL
Address:1001 HARIMAW COURT EAST
Box:City:METAIRIE
State:LA
ZIP:70001
Country:US
Phone:504-835-7600/FAX:504-835-7608
CAGE:4S446
============= Composition/Information on Ingredients =============
Name:2-BUTOXYETHANOL
CAS:111-76-2
RTECS #:KJ8575000
Fraction by Wt: 99-99.9%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:S, 50 PPM
ACGIH TLV:S, 25 PPM; 9596
Name:ETHYLENE GLYCOL (SARA 313) (CERCLA)
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: 0-0.90%
Other REC Limits:NONE RECOMMENDED
ACGIH TLV:C STEL39PPM,A4,VAP96
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:N-BUTYL ALCOHOL (SARA 313) (CERCLA)
CAS:71-36-3
RTECS #:EO1400000
Fraction by Wt: 0-0.02%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM
ACGIH TLV:S, C 50 PPM; 9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:EGBE:ORAL,RAT,LD50:2.4G/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:EXPO MAY CAUSE RESP TRACT
IRRIT,CNS EFFECTS(HEAD,NAU).SKIN:MAY CAUSE SLIGHT IRRIT IF LEFT IN
CONTACT W/SKIN.EYE:CAUSES NOTICEABLE PAIN,SEVERE IRRIT,TRANSIENT
CORNEAL INJURY.INGEST:MALT LOW-MODER ATELY TOXIC.MAY CAUSE
HEAD,DIZZ,GI DISTRESS,METABOLIC ACIDOSIS,LIVER/KIDNEY INJURY.
Explanation of Carcinogenicity:PER MSDS:NOT LISTED AS
CARCINOGEN-AIRC/NTP/OSHA.
Effects of Overexposure:ACUTE:MAY CAUSE MOD IRRIT W/CORNEAL INJURY TO
EYES.INGEST MAY PRODUCE SIGNS OF INTOXICATION,CAHRACTERIZED BY
DROWS,HEAD,NAU,METABOLIC ACIDOSIS.CHRONIC:PROL EXPO TO HI CONCEN IN
AIR MAY RESULT IN INHAL OF HARMFUL AMTS.ACIDOSIS & CHANGES IN
KIDNEY/LIVER MAY OCCUR.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYE:IMMED FLUSH W/DIRECTED STREAM OF WATER FOR @LEAST 15MINS
HOLDING EYELIDS APART.GET MED ATTN.SKIN:IMMED REMOVE CONTAMIN
CLOTH/SHOES.FLUSH SKIN WELL W/WATER FOR @LEAST 15MINS.WASH WELL
W/SOAP/WATER. INHAL:REMOVE TO FRESH AIR.BREATH DIFF ADMIN OXY BY
TRAIN PERSON;RESP STOP GIVE MOUTH-TO-MOUTH RESUSCITATION.GET MED
ATTN IMMED.INGEST:NEVER GIVE ANYTHING BY MOUTH IF UNCONSC.GIVE
SEVERAL GLASSES(SUPP)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:=66.1C, 151.F
Lower Limits:1.1
Upper Limits:10.6
Extinguishing Media:WATER SPRAY, ALCOHOL FOAM, DRY CHEMICAL, CARBON
DIOXIDE.
Fire Fighting Procedures:KEEP PERSONNEL REMOVED & UPWIND.WEAR FULL
PROTECTIVE CLOTHING & FULL FACEPIECE POSITIVE PRESSURE
SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID.
================== Accidental Release Measures ==================
Spill Release Procedures:REVIEW FIRE/EXPLO SEC OF MSDS.USE APPROPRIATE
PPE.DIKE TO CONTAIN.PREVENT LIQ FROM ENTERING SEWERS/WATERWAYS/LOW
AREAS.RECOVER SPILL MATL W/ABSORBANT.PLACE IN CNTNR FOR DISPO.DON'T
FLUSH TO SEWERS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL DRY WELL VENTI AREA AWAY
FROM INCOMPA MATLS.DON'T STORE IN OPN UNLABEL/MISLABEL CNTNRS.KEEP
AWAYF ROM HEAT/SPARKS/FLAMES.
Other Precautions:WHEN HDNLG USE ONLY GROUND/BOND EQPMT.AVOID OPN
HEAT/AGITATION-MAY GENERATE VAP/MISTS.KEEP CNTNR CLSD WHEN NOT IN
USE.DON'T CONSUME FOOD/DRINK/TOBACCO PRODUCTS IN AREAS WHERE MAY
BECOME CONTAM W/MATL. CNTNRS EVEN EMPTIED WILL RETAIN (SUPPLE)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESP PROTECTIVE
EQPMT-AIR PURIF W/ORG VAP CARTRIDGES,AIR SUPPL-IF OTHER PROT
MEASURES DON'T ADEQU CONTROL EXPO TO VAP &/OR MISTS.EMERG/UNK
CONCEN USE +PRESSURE SCBA.UTILIZE RES P PROT EQPMT IAW
29CFR1910.134-RESP PROT
Ventilation:LOCAL EXHAUST VENTILATION IS RECOMMENDED TO CONTROL
EMISSIONS AT THE SOURCE.
Protective Gloves:CHEM RESISTANT GLOVES SUCH AS BUTYL RUBB
Eye Protection:SAF GLASSES W/SIDE SHIELDS,CHEM SAF GOG,
Other Protective Equipment:FULL FCSHIELD-PROT AGAINST SPLASH WHEN
APPROPR(ANSIZ87.1).CHEM RESIST CLOTH,EMERG EYEWASH FOUNTAIN,SAF
SHOWR(ANSIZ358.1)
Work Hygienic Practices:WASH CONTAMIN CLOTH BEF REUSE.WASH THOROUGHLY
AFT HNDLG.
Supplemental Safety and Health
1STAID:OF WATER.INDUCE VOMIT BY TICKLE BACK OF THROAT W/FINGER.KEEP
AIRWAY CLEAR.GET MED ATTN IMMED. OTHER PRECAUT:PRODUCT
RESIDUE/VAP;SHOULD BE HNDLD AS IF FULL.MAKE ALL INFO IN MSDS
AVAILABLE TO YOU R EMPLOYEES.
================== Physical/Chemical Properties ==================
HCC:V4
Boiling Pt:=171.1C, 340.F
Melt/Freeze Pt:=-36.5C, -34.F
Decomp Temp:Decomp Text:NP
Vapor Pres:0.6MM@20C
Vapor Density:4.1
Spec Gravity:0.902
pH:ND
Evaporation Rate & Reference:0.1, BUAC=1.
Solubility in Water:MISCIBLE.
Appearance and Odor:CLEAR COLORLESS LIQUID, MILD ETHER ODOR.
Percent Volatiles by Volume:100
Corrosion Rate:NP
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS,ALKALIS,STRONG OXIDIZING AGENTS,LIME,AMMONIA,ORG
AMINES,CHLORATES,CHLORINE,SODIUM HYDROXIDE.
Stability Condition to Avoid:MAY FORM PEROXIDES IF IN CONTACT W/AIR FOR
LONG PERIODS OF TIME & THESE CAN EXPLODE SPONT OR WHEN HEATED.
Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCARDED PROD NOT RCRA HAZ WASTE.DISPO OF
RECOVERED NONUSABLE PROD/MATL USED IN SPILL CLEANUP IN MANNER
APPROVED FOR THIS MATL.CONSULT APPROPRIATE FED/STATE/LOC REG
AGENCIES TO ASCERTAIN PROPER DISPO PROCEDURES.CONTAINS CHEMS SUBJ
TO SARA/20CFR372.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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