===================== Product Identification =====================
MSDS NAME:SULFURIC ACID, A298 212
NIIN:00-227-1845
MSDS Number: CDMJZ
=== Responsible Party ===
Company:FISHER SCIENTIFIC
Address:1 REAGENT LANE
City:FAIR LAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:201-796-7100
Emergency Phone Num:800-424-9300 (CHEMTREC)
CAGE:1B464
=== Contractor Identification ===
Company:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464
============= Composition/Information on Ingredients =============
Name:SULFURIC ACID (SARA 302/313) (CERCLA) LD50 (ORAL RAT): 2140
MG/KG
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 95-98%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3/3 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:SUP DAT: CHLORINE TRIFLUORIDE, CHLOROSULFONIC ACID, CUPROUS
NITRIDE, DIISOBUTYLENE, EPICHLOROHYDRIN, ETHYLENE (ING 3)
RTECS #:9999999ZZ
Name:ING 2: CYANOHYDRIN, ETHYLENE DIAMINE, ETHYLENE GLYCOL,
ETHYLENIMINE, FULMINATES, OTHER ACIDS, IODINE (ING 4)
RTECS #:9999999ZZ
Name:ING 3: HEPTAFLUORIDE, METALS, ISOPRENE, LITHIUM SILICIDE,
MERCURIC NITRIDE, MESITYL OXIDE, P-NITROTOLUENE, (ING 5)
RTECS #:9999999ZZ
Name:ING 4: PENTASILVER TRIHYD.
RTECS #:9999999ZZ
Name:FIRST AID PROC: REMOVE FROM EXPOS TO FRESH AIR IMMED. IF
NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE (ING 7)
RTECS #:9999999ZZ
Name:ING 6: OXYGEN. NOTES TO MD: TREAT SYMPTOMATICALLY AND
SUPPORTIVELY. NONE REPORTED.
RTECS #:9999999ZZ
Name:EYE PROTECTION: AND FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENT 1.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: CAUSES SEV BURNS. MAY
CAUSE IRREVERSIBLE EYE INJURY. SKIN: CAUSES BURNS. INGEST: MAY
CAUSE SEV & PERM DMG TO DIGESTIVE TRACT. CAUSES GI TRACT BURNS.
INHAL: HARMFUL IF INHALED. MAY CAUSE S EV IRRIT OF RESP TRACT
W/SORE THROAT, COUGHING, SHORTNESS OF BRTH & DELAYED LUNG EDEMA.
MAY CAUSE MUC (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SULFURIC ACID: IARC MONO ON EVAL OF
CARCIN RISK OF CHEMICALS TO MAN, VOL 54, PG 41, 1992: GROUP 1.
ANIMAL: PULM IRRIT.
Effects of Overexposure:HLTH HAZ: MEMB BURNS. CHRONIC: PRLNG/RPTD INHAL
MAY CAUSE NOSEBLEEDS, NASAL CONGESTION, EROSION OF TEETH,
PERFORATION OF NASAL SEPTUM, CHEST PAIN & BRONCHITIS. PRLNG/RPTD
EYE CONT MAY CAUSE CONJUNCTIV ITIS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
Eyes: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN, OCCAS
LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. SKIN: GET MED AID
IMMED. FLUSH SKIN W/PLENTY OF SOAP & WATER FOR AT LEAST 15 MIN
WHILE REMOVING CONTAM CLTHG & SHOES. SPEEDY ACTION IS CRITICAL!
INGEST: DO NOT INDUCE VOMIT. IF VICTIM IS CONSCIOUS & ALERT, GIVE
2-4 CUPFULS OF MILK/WATER. GET MED AID IMMED. INHAL: GET MED AID
IMMED. (ING 6)
===================== Fire Fighting Measures =====================
Extinguishing Media:DO NOT USE WATER DIRECTLY ON FIRE. USE WATER SPRAY
TO COOL FIRE-EXPOSED CONTAINERS. USE DRY CHEMICAL TO FIGHT FIRE.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:CONTACT WITH WATER CAN CAUSE VIOLENT
LIBERATION OF HEAT AND SPLATTERING OF THE MATERIAL.
================== Accidental Release Measures ==================
Spill Release Procedures:CLEAN UP SPILLS IMMEDIATELY, OBSERVING
PRECAUTIONS IN THE PROTECTIVE EQUIPMENT SECTION. COVER WITH SAND,
DRY LIME OR SODA ASH AND PLACE IN A CLOSED CONTAINER FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. KEEP CONTAINER TIGHTLY CLOSED. DO NOT ALLOW CONTACT WITH
WATER. USE ONLY IN A CHEMICAL FUME HOOD.
Other Precautions:DO NOT STORE NEAR COMBUSTIBLE MATERIALS. KEEP
CONTAINER CLOSED WHEN NOT IN USE. STORE IN A DRY AREA. STORE IN A
COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES.
DO NOT STORE NEAR ALK ALINE SUBSTANCES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29CFR 1910.134. ALWAYS USE A NIOSH APPROVED RESPIRATOR WHEN
NECESSARY.
Ventilation:USE PROCESS ENCLOSURE, LOC EXHAUST VENT/OTHER ENGINEERING
CTLS TO CONTROL AIRBORNE LEVELS BELOW REC EXPOS LIMITS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGG (ING 8)
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER . WEAR APPROP PROT CLOTHING TO MINIMIZE CONTACT W/SKIN.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE
CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
Supplemental Safety and Health
PH: 0.3 (1N SOLN). MATLS TO AVOID: ACROLEIN, ACRYLONITRILE, ALCOHOLS +
HYDROGEN PEROXIDE, ALLYL ALCOHOL, ALLYL CHLORIDE, 2-AMINOETHANOL,
AMMONIUM HYDROXIDE, AMMONIUM TRIPERCHROMATE, ANILINE, BROMATES +
METALS, BROMINE PENTAFLUORIDE, N-BUTYRALDEHYDE, CARBIDES, CESIUM
ACETYLENE CARBIDE, CHLORATES, (ING 2)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:554F,290C
Melt/Freeze Pt:M.P/F.P Text:50.6F,10.3C
Vapor Pres:<0.00120
Vapor Density:1.2
Spec Gravity:1.841
pH:SUPDAT
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:SOLUBLE
Appearance and Odor:COLORLESS (PURE) TO BROWN (IMPURE), FUMING LIQUID,
ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACETIC ANHYDRIDE, ACETONE CYANHYDRIN, ACETONE + NITRIC ACID, ACETONE +
POTASSIUM DICHROMATE, ACETONITRILE, (SUP DAT)
Stability Condition to Avoid:INCOMPATIBLE MATLS, CONT W/WATER, METALS,
EXCESS HEAT, COMBUST MATLS, ORG MATLS, OXIDIZERS, AMINES, BASES.
Hazardous Decomposition Products:OXIDES OF SULFUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE, AND LOCAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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