ing 20: for more info about odor & other safety
ing 5: sound, if venting increases in volume or intensity,
efts of overexp: abnormal efts in their card,
ing 7: of narcosis when exposed to both butane & butylene
ing 8: following exposure to butane or butylene alone.
first aid proc: followed by oxygen. seek immed med attn.
ing 10: if subject is conscious. seek medical attention.
spill proc: transfer to disposal drums using non-sparking
other prec: or incin contr. secure contr to pvnt dmg. note:
ing 13: passified (oxidation of ethyl mercaptan may occur
ing 14: that w/odorized prod intensity of ethyl mercaptan
ing 15: presence of rust, air/moisture),
ing 16: may not be able to smell ethyl mercaptan stench.
ing 17: while ethyl mercaptan may not impart warning of
ing 18: effective in a majority of situations. familiarize
propane
propene; (propylene) (sara 313)
butane; (butanes)
ethanethiol; (ethyl mercaptan) %: 0-50 ppm
sup dat: fragmentation of contr should be antic. if flame
msds toxicity property"> ing 20: for more info about odor & other safety
ing 5: sound, if venting increases in volume or intensity,
efts of overexp: abnormal efts in their card,
ing 7: of narcosis when exposed to both butane & butylene
ing 8: following exposure to butane or butylene alone.
first aid proc: followed by oxygen. seek immed med attn.
ing 10: if subject is conscious. seek medical attention.
spill proc: transfer to disposal drums using non-sparking
other prec: or incin contr. secure contr to pvnt dmg. note:
ing 13: passified (oxidation of ethyl mercaptan may occur
ing 14: that w/odorized prod intensity of ethyl mercaptan
ing 15: presence of rust, air/moisture),
ing 16: may not be able to smell ethyl mercaptan stench.
ing 17: while ethyl mercaptan may not impart warning of
ing 18: effective in a majority of situations. familiarize
propane
propene; (propylene) (sara 313)
butane; (butanes)
ethanethiol; (ethyl mercaptan) %: 0-50 ppm
sup dat: fragmentation of contr should be antic. if flame
msds toxicity property">
Search    
MSDS  
: 
 PROPANE HD-5 GRADE, 26161
CAS  
: 
 74-98-6
115-07-1
106-97-8
75-08-1
NAME  
: 
 ing 19: facts assoc w/so-called "odor-fade phenomenon". if
ing 20: for more info about odor & other safety
ing 5: sound, if venting increases in volume or intensity,
efts of overexp: abnormal efts in their card,
ing 7: of narcosis when exposed to both butane & butylene
ing 8: following exposure to butane or butylene alone.
first aid proc: followed by oxygen. seek immed med attn.
ing 10: if subject is conscious. seek medical attention.
spill proc: transfer to disposal drums using non-sparking
other prec: or incin contr. secure contr to pvnt dmg. note:
ing 13: passified (oxidation of ethyl mercaptan may occur
ing 14: that w/odorized prod intensity of ethyl mercaptan
ing 15: presence of rust, air/moisture),
ing 16: may not be able to smell ethyl mercaptan stench.
ing 17: while ethyl mercaptan may not impart warning of
ing 18: effective in a majority of situations. familiarize
propane
propene; (propylene) (sara 313)
butane; (butanes)
ethanethiol; (ethyl mercaptan) %: 0-50 ppm
sup dat: fragmentation of contr should be antic. if flame
 
=====================  Product Identification  =====================

MSDS NAME:PROPANE HD-5 GRADE, 26161
NIIN:00N046318
MSDS Number: CFNYK
=== Responsible Party ===
Company:PHILLIPS CHEMICAL CO
Address:346 HOME SAVINGS & LOAN BLVD
City:BARTLESVILLE
State:OK
ZIP:74004
Country:US
Info Phone Num:918-661-8327; 918-661-5952
Emergency Phone Num:918-661-8818
CAGE:FO153
=== Contractor Identification ===
Company:PHILLIPS 66 COMPANY(DIVISION OF PHILLIPS PETROLEUM CO)
Address:699 ADAMS BLDG 411 KEELER ST
Box:City:BARTLESVILLE
State:OK
ZIP:74004
Country:US
Phone:918-661-8327
CAGE:6Y142
Company:PHILLIPS CHEMICAL CO/BARTLESVILLE, OK 74004
CAGE:FO153

=============  Composition/Information on Ingredients  =============

Name:ING 19: FACTS ASSOC W/SO-CALLED "ODOR-FADE PHENOMENON". IF
    YOU DO NOT ALREADY KNOW ALL FACTS, WRITE MFR & ASK (ING 21)
RTECS #:9999999ZZ

Name:ING 20: FOR MORE INFO ABOUT ODOR & OTHER SAFETY
    CONSIDERATIONS ASSOC W/HANDLING, STORAGE & USE OF PROPANE.
RTECS #:9999999ZZ

Name:ING 5: SOUND, IF VENTING INCREASES IN VOLUME OR INTENSITY,
    OR IF THERE IS DISCOLORATION OF THE TANK DUE TO FIRE.
RTECS #:9999999ZZ

Name:EFTS OF OVEREXP: ABNORMAL EFTS IN THEIR CARD,
    PULM/NEUROLOGICAL FUNCS. LAB ANIMALS HAVE EXHIBITED HIGHER DEGREE
    (ING 8)
RTECS #:9999999ZZ

Name:ING 7: OF NARCOSIS WHEN EXPOSED TO BOTH BUTANE & BUTYLENE
    (ADDITIVE EFT), THAN DEGREE OF NARCOSIS EXHIBITED (ING 9)
RTECS #:9999999ZZ

Name:ING 8: FOLLOWING EXPOSURE TO BUTANE OR BUTYLENE ALONE.
RTECS #:9999999ZZ

Name:FIRST AID PROC: FOLLOWED BY OXYGEN. SEEK IMMED MED ATTN.
    INGEST: GIVE 2 GLASSES OF WATER & INDUCE VOMIT, ONLY (ING 11)
RTECS #:9999999ZZ

Name:ING 10: IF SUBJECT IS CONSCIOUS. SEEK MEDICAL ATTENTION.
RTECS #:9999999ZZ

Name:SPILL PROC: TRANSFER TO DISPOSAL DRUMS USING NON-SPARKING
    EQUIPMENT.
RTECS #:9999999ZZ

Name:OTHER PREC: OR INCIN CONTR. SECURE CONTR TO PVNT DMG. NOTE:
    STORE IN CONTRS THAT HAVE BEEN PROPERLY PURGED & (ING 14)
RTECS #:9999999ZZ

Name:ING 13: PASSIFIED (OXIDATION OF ETHYL MERCAPTAN MAY OCCUR
    IN PRESENCE OF RUST, AIR/WATER). WARNING: BE AWARE (ING 15)
RTECS #:9999999ZZ

Name:ING 14: THAT W/ODORIZED PROD INTENSITY OF ETHYL MERCAPTAN
    STENCH (ITS ODOR) MAY FADE DUE TO CHEM OXIDATION (IN (ING 16)
RTECS #:9999999ZZ

Name:ING 15: PRESENCE OF RUST, AIR/MOISTURE),
    ADSORPTION/ABSORPTION. SOME PEOPLE HAVE NASAL PERCEPTION PROBLEMS &
    (ING 17)
RTECS #:9999999ZZ

Name:ING 16: MAY NOT BE ABLE TO SMELL ETHYL MERCAPTAN STENCH.
    OTHER ODORS MAY MASK/HIDE ETHYL MERCAPTAN STENCH. (ING 18)
RTECS #:9999999ZZ

Name:ING 17: WHILE ETHYL MERCAPTAN MAY NOT IMPART WARNING OF
    PRESENCE OF PROPANE IN EVERY INSTANCE, IT IS GENERALLY (ING 19)
RTECS #:9999999ZZ

Name:ING 18: EFFECTIVE IN A MAJORITY OF SITUATIONS. FAMILIARIZE
    YOURSELF, & YOUR CUSTOMERS, W/THIS WARNING, & OTHER (ING 20)
RTECS #:9999999ZZ

Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: >90%
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT

Name:PROPENE; (PROPYLENE) (SARA 313)
CAS:115-07-1
RTECS #:UC6740000
Fraction by Wt: <5%
OSHA PEL:N/K 
ACGIH TLV:ASPHYXIANT

Name:BUTANE; (BUTANES)
CAS:106-97-8
RTECS #:EJ4200000
Fraction by Wt: <2.5%
OSHA PEL:800 PPM (MFR)
ACGIH TLV:800 PPM (MFR)

Name:ETHANETHIOL; (ETHYL MERCAPTAN) %: 0-50 PPM
CAS:75-08-1
RTECS #:KI9625000
Fraction by Wt: <0.1%
OSHA PEL:C 10 PPM
ACGIH TLV:0.5 PPM

Name:SUP DAT: FRAGMENTATION OF CONTR SHOULD BE ANTIC. IF FLAME
    IS AGAINST CONTR, WITHDRAW IMMED ON HEARING RISING (ING 6)
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: VERY HIGH GAS CONCS MAY
    CAUSE MILD IRRIT EFTS. LIQUEFIED GAS MAY CAUSE FREEZE BURNS UPON
    DIRECT CONT. SKIN: VERY HIGH GAS CONCS MAY CAUSE MILD IRRIT TO MUC
    MEMB. LIQUEFIED GAS MAY CAUSE F REEZE BURNS UPON DIRECT CONT.
    INHAL: SIMPLE ASPHY. EXTREME OVEREXP MAY PRDCE DIZZ, HDCH, (EFFECTS
    OF OVEREXPOSURE)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: DISORIENTATION, EXCITATION, FATG,
    INABILITY TO CONCENTRATE, VOMIT, COUGHING, ANESTH, UNCON & DEATH.
    INGEST: NOT A LIKELY EXPOS RTE. LIQUEFIED GAS MAY CAUSE FREEZE
    BURNS TO MUC MEMB & POSS CN S DEPRESS. CHRONIC: HUMANS BRTHG 1000
    PPM OF PROPANE FOR 8 HRS/DAY, 5 DAYS/WK, FOR APPROX 2 WKS SHOWED NO
    (ING 7)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:NOTE: FOR FREEZE BURNS, IMMED FLUSH AFFECTED AREA W/TAP WATER
    FOR AT LEAST 15 MIN, SEEK IMMED MED ATTN. EYES: FLUSH W/RUNNING
    WATER FOR AT LEAST 15 MIN. IF IRRIT/ADVERSE SYMPS DEVELOP, SEEK MED
    ATTN.  SKIN: WASH W/SOAP & WATER FOR AT LEAST 15 MIN. IF
    IRRIT/ADVERSE SYMPS DEVELOP, SEEK MED ATTN. INHAL: IMMED REMOVE
    FROM EXPOS. IF BRTHG IS DFCLT, GIVE OXYGEN. IF BRTHG CEASES, ADMIN
    ARTF RESP (ING 10)

=====================  Fire Fighting Measures  =====================

Flash Point:-156F,-104C
Lower Limits:2.1%
Upper Limits:9.5%
Extinguishing Media:DRY CHEMICAL, FOAM OR CARBON DIOXIDE .
Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP .
    EVACUATE AREA OF ALL UNNEC PERS. SHUT OFF SOURCE, IF POSS. WATER
    FOG/SPRAY MAY BE USED TO COOL EXPOSED(SUP DAT)
Unusual Fire/Explosion Hazard:CARBON & SULFUR OXIDES FORMED WHEN
    BURNED. HIGHLY FLAM VAPS WHICH ARE HVR/AIR MAY ACCUM IN LOW AREAS
    &/SPREAD ALONG GROUND AWAY FROM HNDLG SITE. FLASH (SUP DAT)

==================  Accidental Release Measures  ==================

Spill Release Procedures:EVACUATE AREA OF ALL UNNEC PERS. WEAR PROT
    EQUIP &/GARMENTS IF EXPOS CNDTNS WARRANT. SHUT OFF SOURCE, IF POSS
    & CONTAIN SPILL. PROTECT FROM IGNIT. KEEP OUT OF WATER SOURCES &
    SEWERS. ABSORB IN DRY, IN ERT MATL (SAND, CLAY, ETC). (ING 12)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:AVOID CONT W/EYES, SKIN/CLTHG. AVOID
    BRTHG VAPS, MISTS, FUMES/DUST. WEAR PROT EQUIP &/GARMENTS IF EXPOS
    CNDTNS WARRANT. USE ONLY W/ADEQ VENT.
Other Precautions:DO NOT GET LIQUEFIED GAS INTO EYES, ON SKIN/ON CLTHG.
    MAY CAUSE FREEZE BURNS UPON DIRECT CONT. KEEP AWAY FROM HEAT, SPKS
    & FLAMES. STORE IN WELL-VENTD AREA. BOND & GROUND DURING TRANSFER.
    STORE IN TIG HTLY CLSD CONTR. DO NOT PUNCTURE(ING 13)

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:NOT GENERALLY REQUIRED. IF EXPOSURE TO OR
    CONCENTRATIONS ABOVE THE RECOMMENDED EXPOSURE LIMITS IS POSSIBLE,
    USE NIOSH APPROVED SCBA.
Ventilation:USE ADEQUATE VENTILATION TO CONTROL EXPOSURE BELOW THE
    RECOMMENDED EXPOSURE LIMITS.
Protective Gloves:RUBBER OR OTHER IMPERVIOUS GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
    ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. LAUNDER
    CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
SPEC GRAV: 0.508-0.510 (H*2O=1). VP: 108-124 PSIA @ 70F (21C). FL PT
    METH: ESTIMATED. FIRE FIGHT PROC: CONTRS & EQUIP. ALLOW FIRE TO
    BURN UNTIL GAS FLOW IS SHUT OFF, IF POSS. EXPLO HAZ: BACK ALONG VAP
     TRAIL IS POSS. HEATED CONTRS MAY RUPTURE VIOLENTLY & SUDDENLY
    W/OUT WARNING DUE TO VESSEL OVER-PRESS (BLEVE). (ING 5)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:-44F,-42C
Vapor Pres:SUP DAT
Vapor Density:1.5
Spec Gravity:SUP DAT
Evaporation Rate & Reference:>1 (ETHYL ETHER=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS LIQUIFIED PETROLEUM GAS, ODORLESS
    (REPULSIVE IF ODORANT ADDED)
Percent Volatiles by Volume:100

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
OXYGEN AND STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NOT ESTABLISHED.
Hazardous Decomposition Products:CARBON AND SULFUR OXIDES FORMED WHEN
    BURNED.

====================  Disposal Considerations  ====================

Waste Disposal Methods:INSURE CONFORMITY WITH ALL APPLICABLE DISPOSAL
    REGULATIONS. INCINERATE OR PLACE IN PERMITTED WASTE MANAGEMENT
    FACILITY. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
    REGULATIONS . RCRA	CLASSIFICATION: IGNITABLE (D001).

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.

*** END OF RECORD ***
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