===================== Product Identification =====================
MSDS NAME:SODIUM SULFIDE, HYDRATED
NIIN:00N080155
MSDS Number: CFSBV
=== Responsible Party ===
Company:CHEMICAL PRODUCTS CORP
Address:102 OLD MILL RD SE
Box:2470
City:CARTERSVILLE
State:GA
ZIP:30120-1692
Country:US
Info Phone Num:706-382-2144; 770-382-2212
Emergency Phone Num:800-424-9300(CHEMTREC)
CAGE:2R425
=== Contractor Identification ===
Company:CHEMICAL PRODUCTS CORP
Address:OLD MILL RD
Box:449
City:CARTERSVILLE
State:GA
ZIP:30120
Country:US
Phone:706-382-2144
CAGE:2R425
============= Composition/Information on Ingredients =============
Name:SODIUM SULFIDE, ANHYDROUS; (SODIUM SULFIDE)
CAS:1313-82-2
RTECS #:WE1905000
Fraction by Wt: 60-63%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 37-40%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:SUPDAT: IRREVERSIBLE DESTRUCTION OF TISSUE. INGEST:
DESTRUCTION OF LINING OF ESOPHAGUS & STOMACH. RAPID BRTHG, (ING 4)
RTECS #:9999999ZZ
Name:ING 3: CONFUSION, UNCON, PARALYSIS OF RESP MUSCLES LEADING
TO DEATH. CHRONIC: INHAL: EXTREME IRRIT TO RESP (ING 5)
RTECS #:9999999ZZ
Name:ING 4: PASSAGES. SKIN CONTACT: EXTREME IRRIT TO SKIN. EYES:
EXTREME IRRIT TO EYES CAUSED BY DUSTS; CORNEAL (ING 6)
RTECS #:9999999ZZ
Name:ING 5: OPACITY. INGEST:HEADACHE, NAUSEA, DIZZINESS,
CONFUSION & PAINFUL ALKALI BURNS TO ESOPHAGUS. TOXICOLOGICAL (ING
7)
RTECS #:9999999ZZ
Name:ING 6: INFO: EYE:CORROSIVE DUE TO PROD'S ALKALINITY.
SKIN:CORROSIVE DUE TO PROD'S ALKALINITY. MAY BE TOXIC WHEN (ING 8)
RTECS #:9999999ZZ
Name:ING 7: ABSORBED THROUGH INTACT SKIN; NO DATA AVAIL.
INGEST:TOXIC - HUMAN ORAL LDLO REPORTED TO BE 50 MG/KG FOR (ING 9)
RTECS #:9999999ZZ
Name:ING 8: ANHYDROUS SODIUM SULFIDE. INHAL:TOXIC - HYDROGEN
SULFIDE INHAL IS ASSUMED. HUMAN LCLO IS 600 PPM FOR 30 (ING 10)
RTECS #:9999999ZZ
Name:ING 9: MIN FOR HYDROGEN SULFIDE. SUB-CHRONIC:IRRIT TO
CONJUNCTIVA & CORNEA OF EYE FROM VAPS. NOT A KNOWN CARCIN.(ING 11)
RTECS #:9999999ZZ
Name:ING 10: CHRONIC ACUTE EXPOS TO DUST MAY CAUSE NEURO
DEFICITS LIKE THOSE IN SURVIVORS OF OTHER SEV ASPHYXIANT
POISONINGS.
RTECS #:9999999ZZ
Name:FIRST AID PROC: SKIN: FLUSH WITH LARGE QUANTITIES OF WATER.
WASH WITH SOAP AND WATER IF AVAILABLE.
RTECS #:9999999ZZ
Name:SPILL PROC: AS HYDROGEN PEROXIDE OR SODIUM HYPOCHLORITE TO
OXIDIZE SULFIDE & ELIM DANGER OF HYDROGEN SULFIDE EVOLUTION.
RTECS #:9999999ZZ
Name:WASTE DISP METH: SULFATE; CARE SHOULD BE TAKEN AS REACTION
MAY BE VIOLENT. WASTE WITH A PH OF 12.5 OR ABOVE IS (ING 15)
RTECS #:9999999ZZ
Name:ING 14: HAZARDOUS BECAUSE OF ITS CORROSIVITY.
RTECS #:9999999ZZ
Name:EYE PROT: & FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HUMAN EFFECTS: HIGH ALKALINITY MAKES
THIS PROD CORROSIVE TO MUC MEMBS - CHEM BURNS RSLT FROM CONTACT.
DUST CAUSES IRRIT TO CONJUNCTIVA & CORNEA OF EYES & TO RESP
PASSAGES. IN ACUTE OVEREXP, VICTIM EXP ERIENCES HEADACHE, NAUSEA,
DIZZINESS, CONFUSION & WEAKNESS OF EXTREMITIES, FOLLOWED BY
PRECIPITOUS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: LAPSE INTO UNCON. ACUTE: INHAL:
SEVERE RESP DISTRESS, CONFUSION, WEAKNESS OF EXTREMITIES, UNCON,
PULMONARY EDEMA, ASPHYXIATION & POSS CENTRAL RESP PARALYSIS LEADING
TO DEATH. SKIN CONTACT: P AINFUL CHEM BURNS. SYSTEMIC POISONING BY
SULFIDE CAUSES HEADACHE, NAUSEA, DIZZINESS, CONFUSION, WEAKNESS OF
(SUPDAT)
Medical Cond Aggravated by Exposure:NONE ARE KNOWN.
======================= First Aid Measures =======================
First Aid:INGEST: HAVE VICTIM DRINK AS MUCH MILK OR WATER AS POSSIBLE.
DO NOT INDUCE VOMITING. IF VOMITING OCCURS, GIVE MORE LIQUIDS.
NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON. GET IMMED MED
ASSISTANCE. INHA L: REMOVE FROM CONTAMD ATMOSPHERE. BEGIN ARTF RESP
IMMED IF NEC. BEGIN CPR IMMED IF NEC. ADMINISTER OXYGEN IF AVAIL.
EYES: FLUSH W/LARGE QTYS OF WATER FOR AT LST 15 MIN. ALWAYS SEEK
MED ATTN. (ING 12)
===================== Fire Fighting Measures =====================
Flash Point:NON-FLAMMABLE
Extinguishing Media:USE WATER IN FLOODING QUANTITIES. A HEAVY FOG OF
WATER MAY BE EFFECTIVE IN KNOCKING DOWN VAPORS.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIPMENT .
DO NOT USE CARBON DIOXIDE FIRE EXTINGUISHERS BECAUSE TOXIC HYDROGEN
SULFIDE GAS MAY BE LIBERATED FROM PROD.
Unusual Fire/Explosion Hazard:FINELY DIVIDED DUST FORMS COMBUST MIXS
W/AIR. DRY GRINDING OF THESE FLAKES CAN RSLT IN FIRES IN GRINDING
EQUIP. POISON, FLAM HYDROGEN SULFIDE GAS WILL (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL SPILL: KEEP DRY & AWAY FROM ACID. SCOOP
UP & STORE IN SEALED CONTAINERS. LARGE SPILLS: KEEP DRY & AWAY FROM
ACID. RECOVER AS MUCH OF THE SOLID AS POSSIBLE. IF MATERIAL IS
DISSOLVED IN WATER, MIX SOLUTION W/EXCESS OXIDIZING AGENT SUCH(ING
13)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORAGE TEMPERATURE: AS COOL AS
PRACTICAL, NEVER ABOVE 80C(176F). STORAGE PRESSURE: ATMOSPHERIC.
Other Precautions:POISON HYDROGEN SULFIDE GAS WILL BE PRESENT IF THIS
PRODUCT CONTACTS ACID. KEEP AWAY FROM ACID. DO NOT STORE IN CONTACT
WITH COPPER, ZINC OR ALUMINUM. KEEP CONTAINERS CLOSED TO AVOID SLOW
REACTION WIT H AIR (OXYGEN AND CARBON DIOXIDE).
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS OR SUPPLIED-AIR RESPIRATOR IF THE PEL FOR HYDROGEN
SULFIDE MIGHT BE EXCEEDED.
Ventilation:ADEQUATE VENTILATION IS REQUIRED TO REMOVE THE TOXIC AND
CORROSIVE DUST WHICH MAY BE PRESENT.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 16)
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
PH: HIGHLY ALKALINE. SOL IN H*2O: 25 GRAMS PER 100 ML OF WATER AT
10C(50F). EXPLO HAZ: BE EVOLVED FROM THIS PROD ON EXPOS TO ACID OR
EXCESSIVE HEAT. IF PROD BURNS, TOXIC SULFUR OXIDE GASES ARE PRODUCE
D. EFTS OF OVEREXP: EXTREMITIES & POSS UNCON. EYE CONTACT: ALKALI
BURNS TO CONJUNCTIVA & CORNEA W/POSS (ING 3)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:293F,145C
Melt/Freeze Pt:M.P/F.P Text:196F,91C
Spec Gravity:1.69
pH:SUPDAT
Solubility in Water:SUPDAT
Appearance and Odor:YELLOW OR ORANGE WAXY-LOOKING SOLID; "ROTTEN EGG"
ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS AND STRONG OXIDIZERS.
Stability Condition to Avoid:CONTACT W/ACIDS LIBERATES POISONOUS,
FLAMMABLE HYDROGEN SULFIDE. MIXING W/STRONG OXIDIZERS CAUSES A
VIOLENT REACTION.
Hazardous Decomposition Products:VERY HIGH TEMPERATURES WILL DECOMPOSE
THIS PRODUCT TO FORM POISONOUS HYDROGEN SULFIDE GAS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE & FED REGS. WASTE
CONTAINING SULFIDE MAY BE HAZARDOUS & MAY REQUIRE DISPOSAL IN
APPRVD HAZARDOUS WASTE LANDFILL. SULFIDE CAN BE OXIDIZED W/DILUTE
HYDROGEN PEROXIDE OR ANY OTHER OXIDIZING AGENT TO
NON-HAZARDOUS(ING 14)
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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