===================== Product Identification =====================
MSDS NAME:WHITE WATERBASE PWC-1952
NIIN:00N080146
MSDS Number: CFSBK
=== Responsible Party ===
Company:MORTON INTERNATIONAL
Address:1021 N MISSION RD
City:LOS ANGELES
State:CA
ZIP:90033
Country:US
Info Phone Num:213-225-4154
Emergency Phone Num:800-424-9300 (CHEMTREC)
CAGE:7D283
=== Contractor Identification ===
Company:MORTON INTERNATIONAL
Address:1021 N MISSION RD
Box:City:LOS ANGELES
State:CA
ZIP:90033
Country:US
Phone:213-225-4154
CAGE:7D283
============= Composition/Information on Ingredients =============
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 5%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:1,2-PROPANEDIOL; (PROPYLENE GLYCOL)
CAS:57-55-6
RTECS #:TY2000000
OSHA PEL:N/K
ACGIH TLV:N/K
Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Name:SILICA, AMORPHOUS FUMED
CAS:112945-52-5
RTECS #:VV7310000
OSHA PEL:6 MG/M3
ACGIH TLV:10 MG/M3
Name:SILICA, CRYSTALLINE - CRISTOBALITE
CAS:14464-46-1
RTECS #:VV7325000
OSHA PEL:SEE TABLE Z-3
ACGIH TLV:0.05 MG/M3 RDUST
Name:CALCIUM CARBONATE (MARBLE) (LIMESTONE)
CAS:1317-65-3
RTECS #:EV9580000
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Name:SILICA, CRYSTALLINE - QUARTZ
CAS:14808-60-7
RTECS #:VV7330000
OSHA PEL:SEE TABLE Z-3
ACGIH TLV:0.1 MG/M3 RDUST
Name:METHANOL (SARA 313) (CERCLA)
CAS:67-56-1
RTECS #:PC1400000
OSHA PEL:S, 200 PPM
ACGIH TLV:S, 200 PPM/250 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:VOLATILE ORGANIC COMPOUND: 1.41 LB/GAL
RTECS #:9999999VO
OSHA PEL:N/K
ACGIH TLV:N/K
Name:SUPDAT:RSLTS @ MASSIVE 250 MG/M3 LEVEL ARE NOT RELEVANT TO
WORKPLACE. AMORPHOUS SILICA-MILD SKIN IRRITANT & A (ING 11)
RTECS #:9999999ZZ
Name:ING 10:MILD EYE IRRITANT IN ANIMALS, ADDNL EXPOS LIMITS: 80
MG/M3 DIVIDED BY PERCENT AMORPHOUS SILICA. SILICA, (ING 12)
RTECS #:9999999ZZ
Name:ING 11:CRYSTOBALITE-MAY CAUSE IRRIT TO MUC MEMB.
RPTD/PRLNGD EXPOS/OVERWHELMING INHAL OF DUST MAY AFFECT LUNGS. (ING
13)
RTECS #:9999999ZZ
Name:ING 12:ACGIH 50 UG/M3 RESPIRABLE DUST. OSHA 50 UG/M3
RESPIRABLE DUST. SILICON DIOXIDE-MAY BE IRRITATING TO EYES,(ING 14)
RTECS #:9999999ZZ
Name:ING 13:SKIN & MUC MEMB DUE TO MECH ACTION. CHRONIC EXPOS
MAY AFFECT LUNGS. METHANOL-EXCESS HUMAN EXPOS MAY LEAD(ING 15)
RTECS #:9999999ZZ
Name:ING 14:TO:FATG, HDCH, ANESTH, NEURALOGIC EFTS, & VISUAL
DFCLTYS INCL BLNDNESS/DEATH. RECURRENT OVEREXP MAY RSLT (ING 16)
RTECS #:9999999ZZ
Name:ING 15:IN LIVER & KIDNEY INJURY.
RTECS #:9999999ZZ
Name:FIRST AID PROC:PERSISTS/OCCURS LATER, CONSULT PHYS. NOTE TO
PHYS:TREATMENT SHOULD BE DIRECTED @ PVNTG ABSORP, (ING 18)
RTECS #:9999999ZZ
Name:ING 17:ADMINISTERING TO SYMPS AS THEY OCCUR, & PROVIDING
SUPPORTIVE THERAPY.
RTECS #:9999999ZZ
Name:SPILL PROC:IN SUITABLE CNTNR FOR DISP, APPROP SFTY MEASURES
& PROT EQUIP SHOULD BE USED. DO NOT FLUSH TO SEWER,(ING 20)
RTECS #:9999999ZZ
Name:ING 19:STREAM/OTHER BODIES OF WATER. COMPLY W/ALL APPLIC
GOVT REGS ON SPILL REPORTING.
RTECS #:9999999ZZ
Name:WASTE DISP METH:AT AN AUTHORIZED FACILITY, OR (3) TREAT AS
ACCEPTABLE WASTE TREATMENT FACILITY.
RTECS #:9999999ZZ
Name:RESP PROT:3M 9900/EQUIV FOR PROT AGAINST PNEUMONCONIOSIS
PRODUCTIVE DUST.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INGEST: GI DISTRESS. SKIN:
RPTD/PRLNGD LIQ CONT MAY CAUSE IRRIT W/DISCOMFORT & DERM. MAY ALSO
CAUSE ALLERGIC SKIN RXNS. CAN BE ABSORBED THRU SKIN IN HARMFUL
AMTS. EYES: MAY CAUSE IRRIT W/DISCOM FORT, TEARING/BLURRED VISION.
INHAL: MAY CAUSE NOSE & THROAT IRRIT, MAY CAUSE NERV SYS DEPRESS
CHARACT (EFTS OF OVEREXP)
Explanation of Carcinogenicity:CRYSTALLINE SILICA-QUARTZ & SILICA,
CRYSTALLINE-CRISTOBALITE: IARC MONO, VOL 68, 1997: GROUP 1. NTP 7TH
ANNUAL (SUPDAT)
Effects of Overexposure:HLTH HAZ: BY FOLLOWING PROGRESSIVE STEPS: HDCH,
DIZZ, NAUS, STAGG GAIT, CONFUSN, UNCON. RPTS HAVE ASSOC RPTD &
PRLNGD OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG. PROPYLENE
GLYCOL: IS CNS DEPRESSANT & MAY BE IRRITATING TO SKIN. REPROD EFTS
DATA FOUND IN RTECS LITERATURE. TITANIUM DIOXIDE - NO KNOWN HAZARD
(SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST:GI DISTRESS. CALL PHYS IMMED & HAVE NAMES OF INGREDS
AVAIL. SKIN:HIGHLY TOX BY ABSORP-CALL PHYS, IN CASE OF CONT, IMMED
FLUSH W/PLENTY OF WATER FOR @ LST 15 MINS WHILE REMOVING CONTAMD
CLTHG & SHOES. EYE:IMMED FLUSH W/PLENTY OF WATER FOR @ LST 15
MINS, CALL PHYS. IF IRRIT OCCURS, CONT PHYS. INHAL:REMOVE TO FRESH
AIR. IF NOT BRTHG GIVE ARTF RESP, PREF MOUTH TO MOUTH. IF BRTHG
DFCLTY(ING 17)
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:105F,41C
Extinguishing Media:USE CHEMICAL FOAM, DRY CHEMICAL, OR CARBON DIOXIDE,
'ALCOHOL' FOAM FOR POLAR SOLVENTS.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . WATER FROM FOG NOZZ MAY BE USED TO COOL CLSD CONTAINERS
TO PREVENT PRESSURE BUILD UP.
Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE FLASHPOINT, EMITS FLAMM
VAPS WHICH, WHEN MIXED W/AIR, CAN BURN/BE EXPLOSIVE, FINE
MIST/SPRAYS MAY BE FLAMM AT TEMPS BELOW FLASH POINT.
================== Accidental Release Measures ==================
Spill Release Procedures:STOP DISCHARGE, IF CAN BE PERFORMED SAFELY, &
CONTAIN MATL. IF SUBSTANTIAL QTY IS SPILLED, RECOVER W/PUMP/VACUUM
TRUCK. EXPLOSION PROOF EQUIP SHOULD BE USED IF THIS PROD IS
FLAMM/COMBUST. OTHERWISE, U SE SYNTHETIC ABSORB. PLACE CONTAMD
MATL(ING 19)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED
AREA. DOL STOR CATEGORY:REFERENCE OSHA 1910.106. DO NOT CUT, GRIND,
WELD/DRILL NEAR THIS CONTAINERS.
Other Precautions:THIS CNTNR CAN BE HAZ WHEN EMPTY, BECAUSE IT CAN
RETAIN PROD RESIDUE, THEREFORE, DO NOT REUSE CNTNR FOR FOOD,
CLTHG/PRODS FOR HUMAN/ANIMAL CONSUMPTION/WHERE SKIN CONT MAY OCCUR.
ALWAYS OBEY HAZ WARNIN GS & HNDL CNTNRS AS IF THEY WERE FULL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHEN ESTABLISHED AIRBORNE EXPOS LIMITS ARE
SURPASSED, WEAR NIOSH APPRVD EQUIP. DETERM APPROP TYPE EQUIP FOR
SPECIFIC APPLIC BY CONSULTING RESP MFR, OBSERVE RESP USE
LIMITATIONS SPECIFIED BY NIOSH/MFR. USE NIOSH APPRVD RESP SUCH AS
(ING 22)
Ventilation:LOC EXHAUST TO MAINTAIN VAPOR CONC BELOW THRESHOLD LIMIT
VALUE.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:REMOVE & WASH CONTAMD CLTHG BEFORE REUSE.
DISCARD SHOES IF SATURATED.
Supplemental Safety and Health
EXPLAN OF CARCIN:RPT ON CARCIN, 1994: ANTIC TO BE CARCIN. EFTS OF
OVEREXP:W/NORM INDUST USE, IN LIFE-TIME INHAL TEST, LUNG CANCERS
WERE FOUND IN SOME RATS EXPOSED TO 250 MG/M3 RESPIRABLE TITANIUM
DUS T. ANALYSIS OF TITANIUM DIOXIDE CONC INRAT'S LUNGS SHOWED THAT
LUNG CLEARANCE MECHANISM WAS OVERWHELMED & THAT (ING 10)
================== Physical/Chemical Properties ==================
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NOT KNOWN
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:49.68
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, HYDROFLUORIC ACID. AVOID CHROMIC ANHYDRIDE,
LEAD PERCHLORATE, OR PERCHLORIC ACID.
Stability Condition to Avoid:HEAT, SPARKS, AND OPEN FLAME.
Hazardous Decomposition Products:MAY LIBERTE CARBON MONOXIDE, CARBON
DIOXIDE, AND UNIDENTIFIED ORGANIC COMPOUNDS IN BLACK SMOKE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF WASTE I/A/W LOC, STATE, & FED REGS.
OF METHS OF DISP CURRENTLY AVAIL, IT IS REC THAT ALTERNATIVE BE
SELECTED ACCORDING TO FOLLOWING ORDER OF PREFERENCE BASED UPON
ENVIR ACCEPTABILITY: (1) R ECYCLE/REWORK IF @ ALL FEASIBLE, (2)
INCIN(ING 21)
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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