===================== Product Identification =====================
MSDS NAME:F93NC21 POLANE, ORDNANCE COATING, BROWN (SUPDAT)
NIIN:00N080822
MSDS Number: CFWGM
=== Responsible Party ===
Company:SHERWIN-WILLIAMS CO
Address:101 PROSPECT AVE NW
City:CLEVELAND
State:OH
ZIP:44115
Country:US
Info Phone Num:216-566-2902
Emergency Phone Num:216-566-2917
CAGE:54636
=== Contractor Identification ===
Company:SHERWIN-WILLIAMS CO THE
Address:101 PROSPECT AVE NW
Box:City:CLEVELAND
State:OH
ZIP:44115-1042
Country:US
Phone:800-251-2486/216-566-2242
CAGE:54636
============= Composition/Information on Ingredients =============
Name:TOLUENE (SARA 313) (CERCLA). VP: 22.00
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 6%
OSHA PEL:200 PPM; Z-2
ACGIH TLV:S, 50 PPM; 9495
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:SOLVENT NAPHTHA; (MEDIUM AROMATIC HYDROCARBONS). VP: 0.12
CAS:64742-94-5
RTECS #:WF3100000
Fraction by Wt: 2%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA 313)
(CERCLA). VP: 2.00
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 10%
OSHA PEL:200 PPM
ACGIH TLV:200 PPM/300STEL;9495
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:CYCLOHEXANONE (CERCLA). VP: 2.00
CAS:108-94-1
RTECS #:GW1050000
Fraction by Wt: 8%
OSHA PEL:S, 50 PPM
ACGIH TLV:S, 25 PPM; 9495
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE) (CERCLA). VP:
10.00
CAS:123-86-4
RTECS #:AF7350000
Fraction by Wt: 15%
OSHA PEL:150 PPM
ACGIH TLV:150 PPM/200STEL;9495
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (1-METHOXY
2-PROPANOL ACETATE). VP: 1.80
CAS:108-65-6
RTECS #:AI8925000
Fraction by Wt: 1%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:SILICA, CRYSTALLINE - CRISTOBALITE
CAS:14464-46-1
RTECS #:VV7325000
Fraction by Wt: 10%
OSHA PEL:SEE TABLE Z-3
ACGIH TLV:0.05 MG/M3 RDUST9495
Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (TALC
(CONTAINING NO ASBESTOS))
CAS:14807-96-6
RTECS #:WW2710000
Fraction by Wt: 10%
OSHA PEL:20 MPPCF Z-3
ACGIH TLV:2 MG/M3 RDUST; 9495
Name:CARBON BLACK
CAS:1333-86-4
RTECS #:FF5800000
Fraction by Wt: 0.6%
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3; 9495
Name:CHROMIUM(III) OXIDE (2:3) CR2O3
CAS:1308-38-9
RTECS #:GB4750000
Fraction by Wt: 8%
OSHA PEL:0.5 MG/M3 (MFR)
ACGIH TLV:0.5 MG/M3 TWA AS CR
Name:CHROMIUM; (CHROMIUM III (AS CR)) (SARA 313) (CERCLA)
CAS:7440-47-3
RTECS #:GB4200000
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3; 9495
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:EFTS OF OVEREXP:ITCHING/BURNING SENSATION MAY INDICATE
EYE/EXCESSIVE SKIN EXPOS. CHRONIC:CRYSTALLINE SILICA (ING 14)
RTECS #:9999999ZZ
Name:ING 13:(QUARTZ, CRISTOBALITE) IS LISTED BY IARC AND NTP.
LONG TERM EXPOS TO HIGH LEVELLS OF SILICA DUST, WHICH (ING 15)
RTECS #:9999999ZZ
Name:ING 14:CAN OCCUR ONLY WHEN SANDING/ABRADING THE DRY FILM,
MAY CAUSE LUNG DAMAGE (SILICOSIS) & POSSIBLY CANCER. (ING 16)
RTECS #:9999999ZZ
Name:ING 15:METHYL ETHYL KETONE MAY INCR THE NERVOUS SYS EFTS OF
OTHER SOLV. PRLNG OVEREXP TO SOLV INGRED IN (ING 17)
RTECS #:9999999ZZ
Name:ING 16:SECTION 2 MAY CAUSE ADVERSE EFTS TO THE LIVER,
URINARY, BLOOD FORMING, CARDIOVASCULAR & REPROD SYS. (ING 18)
RTECS #:9999999ZZ
Name:ING 17:PERS SENSITIVE TO ISOCYANATES WILL EXPER INCRD
ALLERGIC RXN ON RPTD EXPOS. RPTS HAVE ASSOCD RPTD & (ING 19)
RTECS #:9999999ZZ
Name:ING 18:PRLNG OVEREXP TO SOLVS W/PERM BRAIN & NERVOUS SYS
DMG. CHROMIUM III IS CONSIDERED THE ACTIVE SPECIES (ING 20)
RTECS #:9999999ZZ
Name:ING 19:IN CANCER INDUCTION, BUT CHROMIUM III CMPDS DO NOT
CROSS THE CELL WALL. HOWEVER, THERE IS SOME AVIDENCE (ING 21)
RTECS #:9999999ZZ
Name:ING 20:THAT CHROMIUM III COMPOUNDS OF RESPIRABLE PARTICLE
SIZE MAY BE TAKEN UP BY THE CELLS IN THE LUNGS.
RTECS #:9999999ZZ
Name:WASTE DISP METH:IN ACCORDANCE WITH FEDERAL, STATE, AND
LOCAL REGULATIONS REGARDING POLLUTION.
RTECS #:9999999ZZ
Name:OTHER PREC:GROUNDING PROCEDURES. KEEP CONTAINER CLOSED WHEN
NOT IN USE. FOR MORE SPECIFIC INFO CONTACT NEHC .
RTECS #:9999999ZZ
Name:RESP PROT:FOLLOW RESP MFR'S DIRECTION FOR USE. FOR MORE
SPECIFIC INFORMATION CONTACT NEHC .
RTECS #:9999999ZZ
Name:EXPLAN OF CARCIN:1997 GROUP 1. NTP 7TH ANNUAL REPORT ON
CARCIN, 1994:ATICIPATED TO BE CARCINOGEN.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:TOLUENE APPEARS ON THE NAVY LISTING OF
OCCUP CHEM REPRO HAZ. SEEK CONSULTATION FROM APPROP HLTH
PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS
INFO . EXPOS MAY BE BY INHAL &/ SKIN/EYE CNTCT, DEPENDING ON CNDTNS
OF USE. TO MINIMIZE EXPOS, FOLLOW RECOMMENDATION FOR PROPER (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:CARBON BLACK:IARC MONO, VOL 65, PG
24-27, 1995:GROUP 2B. SILICA, CRYSTALLINE-CRISTOBALITE:IARC MONO,
VOL 68, (ING 25)
Effects of Overexposure:HLTH HAZ:USE, VENT, & PERS PROT EQUIP.
ACUTE:IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE NERVOUS SYS
DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCONSCIOUSNESS & POSSIBLY
DEATH. SIGNS & SYMPS OF OVEREXP:HDCH, DIZZ, NAUS, & LOSS OF
COORDINATION AREINDICATIONS OF EXCESSIVE EXPOS TO VAPS/SPRAY MISTS.
REDNESS & (ING 13)
Medical Cond Aggravated by Exposure:MAY CAUSE ALLERGIC RESPIRATORY
AND/OR SKIN REACTION IN SUSCEPTIBLE PERSONS OR SENSITIZATION. THIS
EFFECT MAY BE DELAYED SEVERAL HOURS AFTER EXPOSURE.
======================= First Aid Measures =======================
First Aid:INHAL: IF ANY BREATHING PROBLEMS OCCUR DURING USE, LEAVE THE
AREA AND GET FRESH AIR. IF PROBLEMS REMAIN OR OCCUR LATER,
IMMEDIATELY GET MEDICAL ATTENTION. SKIN: WASH AFFECTED AREA
THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
LAUNDER BEFORE RE-USE. EYES: FLUSH EYES WITH LARGE AMOUNTS OF WATER
FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGEST: GET MEDICAL
ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:48.0F,8.9C
Lower Limits:0.8%
Upper Limits:13.1%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . IF
H*2O IS USED, FOG NOZZLES ARE PREF. H*2O MAY BE USED TO COOL CLSD
CNTNRS TO PVNT PRESS BUILD-UP & (SUPDAT)
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATED FROM
HEAT, ELEC EQUIP, SPARKS, & OPEN FLAME. CLSD CNTNRS MAY EXPLODE
WHEN EXPOSED TO EXTREME HEAT. APPLICATION (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:DOL STORAGE CATEGORY: 1B. CONTENTS ARE
FLAMMABLE. KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME.
Other Precautions:DURING USE & UNTIL ALL VAPS ARE GONE:KEEP AREA
VENT-DO NOT SMOKE-EXTING ALL FLAMES, PILOT LIGHTS, & HEATERS-TURN
OFF STOVES, ELECTRIC TOOLS & APPLICANCES, & ANY OTHER SOURCES OF
IGNITION. CONSULT NFPA CODE. USE APPRVD BONDING & (ING 23)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHERE OVERSPRAY IS PRESENT, A POS PRESS AIR
SUPPLIED RESP (TC19C NIOSH APPRVD) SHOULD BE WORN. IF UNAVAILABLE,
A PROPERLY FITTED ORG VAP/PARTICULATE RESP APPRVD BY NIOSH FOR PROT
AGAINST MATLS IN SECI ON 2 MAY BE EFFECTIVE. (ING 24)
Ventilation:LOC EXHST PREF. FOR MORE SPECIFIC INFORMATION CONTACT NEHC
.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA. . USE BARRIER CREAM ON EXPOSED SKIN.
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
MFR'S TRADE NAME/PART #:383 CAMOUFLAGE. FIRE FIGHT PROC:POSS
AUTOIGNITION/EXPLOSION WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ:TO
HOT SURFACES REQUIRES SPECIAL PRECAUTIONS. DURING EMERGENCY
CONDITIONS OV EREXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE HEALTH
HAZ. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. OBTAIN MED ATTN.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>174F,>79C
Vapor Pres:SEE INGRED
Vapor Density:HVR/AIR
Spec Gravity:1.32
VOC Pounds/Gallon:577
VOC Grams/Liter:4.82
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:66
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE:CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METALS IN SECTION 2.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER
THE RCRA 40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY &
EXTRACTABILITY TO DETERM THE APPLIC EPA HAZ WASTE NUMBERS. INCIN IN
APPRVD FACILITY. DO NO T INCIN CLSD CNTNR. DISPOSE OF (ING 22)
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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