===================== Product Identification =====================
MSDS NAME:MS-472N URETHANE CONFORMAL COATING
NIIN:00N062299
MSDS Number: CFWDW
=== Responsible Party ===
Company:MILLER-STEPHENSON CHEMICAL
Address:GEORGE WASHINGTON HWY
City:DANBURY
State:CT
ZIP:06810
Country:US
Info Phone Num:203-743-4447
Emergency Phone Num:203-797-2212;800-424-9300(CHEMTREC)
Preparer's Name:JOANNA SAFFO
CAGE:18598
=== Contractor Identification ===
Company:MILLER-STEPHENSON CHEMICAL CO INC
Address:55 BACKUS AVE/GEORGE WASHINGTON HWY
Box:950
City:DANBURY
State:CT
ZIP:06810
Country:US
Phone:203-743-4447
CAGE:18598
============= Composition/Information on Ingredients =============
Name:ETHANE, 1,1-DICHLORO-1-FLUORO-;
(1,1-DICHLORO-1-FLUOROETHANE) (SARA 313)
CAS:1717-00-6
RTECS #:KI0997000
Fraction by Wt: 22%
OSHA PEL:N/K
ACGIH TLV:N/K
Ozone Depleting Chemical:2
Name:METHANE, DICHLORO-; (METHYLENE CHLORIDE) (SARA 313)
(CERCLA)
CAS:75-09-2
RTECS #:PA8050000
Fraction by Wt: 57%
OSHA PEL:500 PPM
ACGIH TLV:50 PPM, A2
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:TOLUENE (SARA 313) (CERCLA)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 7%
OSHA PEL:200 PPM
ACGIH TLV:50 PPM, S
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:XYLENE (SARA 313) (CERCLA)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 2.75%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM/150 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:BENZENE, 2,4-DIISOCYANATO-1-METHYL-;
(TOLUENE-2,4-DIISOCYANATE) (TDI) (SARA 302/313) (CERCLA)
CAS:584-84-9
RTECS #:CZ6300000
Fraction by Wt: <0.20%
OSHA PEL:C 0.02 PPM
ACGIH TLV:0.005 PPM/0.02 STEL
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:EFTS OF OVEREXP: METHYLENE CHLORIDE IS CLASSIFIED AS
IRRITANT. SKIN PERMEATION OF METHYLENE CHLORIDE CAN OCCUR (ING 7)
RTECS #:9999999ZZ
Name:ING 6: IN AMTS CAPABLE OF PRODUCING EFTS OF SYSTEMIC
TOXICITY. CHLOROCARBON/CHLOROFLUOROCARBON MATLS HAVE PRDCED (ING 8)
RTECS #:9999999ZZ
Name:ING 7: SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS &
COULD HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS (ING 9)
RTECS #:9999999ZZ
Name:ING 8: (E.G., EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT
FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY/CHRONICALLY (ING 10)
RTECS #:9999999ZZ
Name:ING 9: EXPOSED TO CHLOROCARBONS/CHLOROFLUOROCARBONS .
TOLUENE APPEARS ON THE NAVY OCCUP CHEM REPRO HAZ (ING 11)
RTECS #:9999999ZZ
Name:ING 10: LIST. CONSULT APPROP HLTH PROFESSIONALS CONCERNING
LATEST HAZ LIST & SAFE HNDLG & EXPOS INFO .
RTECS #:9999999ZZ
Name:FIRST AID PROC: TRACT. GIVE 2 GLASSES OF WATER/ACTIVATED
CHARCOAL SLURRY (50 G ACTIVATED CHARCOAL IN 400 ML (ING 13)
RTECS #:9999999ZZ
Name:ING 12: H*2O). NEVER GIVE ANYTHING BY MOUTH TO AN UNCON
PERS. NOTE TO MD: BECAUSE OF POSS INCRD RISK OF (ING 14)
RTECS #:9999999ZZ
Name:ING 13: ELICITING CARD DYSRRHYTHMIAS, CATECHOLAMINE DRUGS,
SUCH AS EPINEPHRINE, SHOULD BE CONSIDERED ONLY AS A (ING 15)
RTECS #:9999999ZZ
Name:ING 14: LAST RESORT IN LIFE THREATENING EMERGENCIES.
RTECS #:9999999ZZ
Name:OTHER PREC: HEAT AND/OR UV RADIATION MAY CAUSE THE
FORMATION OF CHLORIDES, FLUORIDES, AND/OR PHOSGENE .
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: VAP IS HVR/AIR & CAN
CAUSE SUFFOCATION BY REDUCING OXYGEN AVAIL FOR BRTHG. BRTHG HIGH
CONCS OF VAP MAY CAUSE LT-HEAD, GIDD, SHORTNESS OF BREATH & MAY
LEAD TO NARCOSIS, CARD IRREGULARITIE S, UNCON/DEATH. METHYLENE
CHLORIDE IS METABOLIZED TO CARBON DIOXIDE, RAISING CARBOXY
HEMOGLOBIN CONC (EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE: IARC MONO, SUPP, VOL
7, PG 194, 1987: GROUP 2B. NTP 7TH ANNUAL RPT ON CARCINS, 1994:
ANTIC (SUP DAT)
Effects of Overexposure:HLTH HAZ: IN BLOOD W/RESULTING SYMPS OF CARBON
MONOXIDE POISONING. INGEST: ALTHOUGH ORAL TOXICITY IS LOW, INGEST
IS TO BE AVOIDED. MIN AMTS ASPIRATED INTO LUNGS DURING INGEST MAY
CAUSE SEV PULM INJURY /DEATH. EYES: CONT WILL CAUSE EXTREME IRRIT.
SKIN: CONT WILL CAUSE DRYNESS & MAY CAUSE SLIGHT IRRIT/DERM. (ING
6)
Medical Cond Aggravated by Exposure:PERSONS WITH PREEXISTING SKIN
DISORDERS MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS COATING.
======================= First Aid Measures =======================
First Aid:INHAL: MOVE TO FRESH AIR. IF NEC, GIVE ARTF RESP/OXYGEN. DO
NOT GIVE EPINEPHRINE/SIMILAR DRUGS AS SUCH DRUGS MAY INDUCE
VENTRICULAR ARRHY. EYES: FLUSH W/WATER FOR AT LEAST 15 MIN. CALL MD
IF IRRIT RSL TS. SKIN: WASH W/SOAP & WATER. GET MED ATTN IF IRRIT
IS PRESENT. INGEST: CALL MD. DO NOT INDUCE VOMIT AS HAZ OF ASPIR
INTO LUNGS IS A GREATER HAZ THAN ALLOWING IT TO PROGRESS THRU
INTESTINAL (ING 12)
===================== Fire Fighting Measures =====================
Extinguishing Media:FOAM, WATER FOG, DRY CHEMICAL, CARBON DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH APPROVED PRESSURE DEMAND SCBA AND
FULL PROTECTIVE EQUIPMENT . WATER MAY BE USED TO COOL CONTAINERS TO
REDUCE PRESSURE.
Unusual Fire/Explosion Hazard:CONTRS MAY RUPTURE UNDER FIRE. INTENSE
HEAT MAY CAUSE DECOMP W/EMISSION OF HALOGEN ACIDS. THERMAL DECOMP
PRODS MAY INCL FLUORIDES, CHLORIDES, PHOSGENE .
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ANY IGNITION SOURCES. VENTILATE AREA.
WIPE UP SPILL USING APPROPRIATE EYE, SKIN AND NIOSH APPROVED
RESPIRATORY PROTECTION. WASH HANDS WITH SOAP AND WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID CONT W/SKIN & EYES. AVOID BRTHG
VAPS & PRLNG SKIN EXPOS. USE ONLY IN WELL-VENTILATED AREA. DO NOT
PUNCTURE/INCIN AEROSOL CANS.
Other Precautions:DO NOT STORE NEAR SOURCES OF HEAT, IN DIRECT
SUNLIGHT/WHERE TEMPS EXCEED 49C (120F). ROTATE STOCK TO SHELF LIFE
OF 6 MONTHS. NO SMOKING IN AREA OF USE. DO NOT USE IN THE GEN VICIN
OF ARC WELDING, OPEN FLAMES/HOT SURFACES. (ING 16)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:UNDER NORMAL MANUFACTURING CONDITIONS NO
RESPIRATORY PROTECTION IS REQUIRED WHEN USING THIS PRODUCT. NIOSH
APPROVED SCBA IS REQUIRED IF A LARGE SPILL OCCURS.
Ventilation:NORM VENT FOR STANDARD MFG PROC GEN ADEQ. USE LOC EXHAUST
WHEN LARGE AMOUNTS ARE RELEASED. USE MECH VENT IN LOW PLACES.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLAN OF CARCIN: TO BE CARCIN. ANIMAL: LUNG. TOLUENE DIISOCYANATE:
IARC MONO, SUPP, VOL 7, PG 56, 1987: GROUP 2B. NTP 7TH ANNUAL RPT
ON CARCINS, 1994: ANTIC TO BE CARCIN. HAZ DECOMP PROD: ACIDS, & CA
RBONYL HALIDES SUCH AS PHOSGENE.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:96.8F,36.0C
pH:NEUT
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS LIQUID; ETHER-LIKE ODOR
Percent Volatiles by Volume:91.0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS, STRONG ACIDS AND OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID OPEN FLAMES OR RED HOT COILS.
Hazardous Decomposition Products:CAN BE DECOMPOSED BY HIGH TEMPS (OPEN
FLAMES, GLOWING METAL SURF, ETC) FORMING HYDROCHLORIC &
HYDROFLUORIC (SUP DAT)
==================== Disposal Considerations ====================
Waste Disposal Methods:COMPLY WITH FEDERAL, STATE AND LOCAL
REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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