Search   
MSDS  
:
 METHYL ETHYL KETONE
CAS  
:
 78-93-3
NAME  
:
 2-butanone; (methyl ethyl ketone) (sara 313) (cercla)
supdat:& let fire burn. withdraw immediately if hearing
ing 2:discoloration due to fire. do not release runoff from
matls to avoid:2-propanol (forms explo peroxides),
ing 4:copper, isocyanates, pyridines, & strong oxidizers.
efts of overexp:cause defat & derm, apparently w/out irrit.
first aid proc:& support brthg as needed. ingest:never give
ing 7:pois ctl ctr. unless otherwise advised, have
ing 8:do not induce vomit because of poss aspir into lungs.
ing 9:urine. there is good correlation between urinary mek
spill proc:dike far ahead of lg spill for reclamation/disp.
ing 11:booms to limit spill travel. pvnt entry into dewers,
ing 12:(29 cfr 1910.120).
waste disp meth:recs. follow applic federal, state, & local
resp prot:chem cartridge resp w/full facepiece & ovcs. for
ing 15:facepiece resp (gas mask) w/chin-style, fron-or-back
ing 16:operations (cleaning spills, reactor vess/stor
ing 17:air purifying resps do not protect workers in
ing 18:niosh apprvd resp prot program that incl @ lst: med
ing 19:monitoring, maintenance, inspection, cleaning, &
vent:because it pvnts contaminant dispersion into work area
prot gloves:& teflon w/breakthrough times (bt) of >8 hr &
ing 22:are suitable ppe materials.
hygiene pract:eat, drink/smoke in work areas. practice good
ing 24:eating, drinking, smoking, using toilet/applying
Catalog of Chemical Suppliers, Buyers, Custom Synthesis Companies And Equipment Manufacturers
[ METHYL ETHYL KETONE 78-93-3 ]
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Not Available
Buyers:  
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=====================  Product Identification  =====================

MSDS NAME:METHYL ETHYL KETONE
NIIN:00N082158
MSDS Number: CGCJN
=== Responsible Party ===
Company:GENIUM PUBLISHING CORP
Address:ONE GENIUM PLAZA
City:SCHENECTADY
State:NY
ZIP:12304-4690
Country:US
Info Phone Num:518-377-8854
Emergency Phone Num:518-377-8854
CAGE:5Z768
=== Contractor Identification ===
Company:GENIUM PUBLISHING CORPORATION
Address:1145 CATALYN ST
Box:City:SCHENECTADY
State:NY
ZIP:12303-1836
Country:US
Phone:518-377-8854
CAGE:5Z768

=============  Composition/Information on Ingredients  =============

Name:2-BUTANONE; (METHYL ETHYL KETONE) (SARA 313) (CERCLA)
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 100%
OSHA PEL:200 PPM
ACGIH TLV:200 PPM/300 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Name:SUPDAT:& LET FIRE BURN. WITHDRAW IMMEDIATELY IF HEARING
    RISING SOUND FROM VENTING SFTY DEVICE/NOTICE ANY TANK (ING 3)
RTECS #:9999999ZZ

Name:ING 2:DISCOLORATION DUE TO FIRE. DO NOT RELEASE RUNOFF FROM
    FIRE CONTROL METH TO SEWERS/WATERWAYS; DIKE FOR PROPER DISP.
RTECS #:9999999ZZ

Name:MATLS TO AVOID:2-PROPANOL (FORMS EXPLO PEROXIDES),
    CHLOROFORM + ALKALI, AMINES, AMMONIA, INORG ACIDS, CAUSTICS, (ING
    5)
RTECS #:9999999ZZ

Name:ING 4:COPPER, ISOCYANATES, PYRIDINES, & STRONG OXIDIZERS.
    MEK WILL SOFTEN/DISSOLVE SOME PLASTICS.
RTECS #:9999999ZZ

Name:EFTS OF OVEREXP:CAUSE DEFAT & DERM, APPARENTLY W/OUT IRRIT.
    TARGET ORGANS: RESP TRACT, CNS, SKIN & EYES.
RTECS #:9999999ZZ

Name:FIRST AID PROC:& SUPPORT BRTHG AS NEEDED. INGEST:NEVER GIVE
    ANYTHING BY MOUTH TO UNCON/CONVULSING PERSON. CONT (ING 8)
RTECS #:9999999ZZ

Name:ING 7:POIS CTL CTR. UNLESS OTHERWISE ADVISED, HAVE
    CONSCIOUS & ALERT PERSON DRINK 1-2 GLASSES OF WATER TO DILUTE.(ING
    9)
RTECS #:9999999ZZ

Name:ING 8:DO NOT INDUCE VOMIT BECAUSE OF POSS ASPIR INTO LUNGS.
    NOTE TO PHYS: MEK IS DETECTABLE IN EXPIRED AIR & (ING 10)
RTECS #:9999999ZZ

Name:ING 9:URINE. THERE IS GOOD CORRELATION BETWEEN URINARY MEK
    AND WORKPLACE AIR CONCENTRATION.
RTECS #:9999999ZZ

Name:SPILL PROC:DIKE FAR AHEAD OF LG SPILL FOR RECLAMATION/DISP.
    FOR SPILLS IN WATER, USE NATL BARRIERS/SPILL CTL (ING 12)
RTECS #:9999999ZZ

Name:ING 11:BOOMS TO LIMIT SPILL TRAVEL. PVNT ENTRY INTO DEWERS,
    DRAINS, & WATERWAYS. FOLLOW APPLIC OSHA REGS (ING 13)
RTECS #:9999999ZZ

Name:ING 12:(29 CFR 1910.120).
RTECS #:9999999ZZ

Name:WASTE DISP METH:RECS. FOLLOW APPLIC FEDERAL, STATE, & LOCAL
    REGS. LISTED AS RCRA HAZ WASTE (40CFR261.33):U159.
RTECS #:9999999ZZ

Name:RESP PROT:CHEM CARTRIDGE RESP W/FULL FACEPIECE & OVCS. FOR
    <3000 PPM, USE ANY NIOSH APPRVD AIR PURIFYING, FULL (ING 16)
RTECS #:9999999ZZ

Name:ING 15:FACEPIECE RESP (GAS MASK) W/CHIN-STYLE, FRON-OR-BACK
    MOUNTED ORGANIC VAP CANISTER. FOR EMER/NONROUTINE (ING 17)
RTECS #:9999999ZZ

Name:ING 16:OPERATIONS (CLEANING SPILLS, REACTOR VESS/STOR
    TANKS), WEAR NIOSH APPRVD SCBA. WARNING! NIOSH APPRVD (ING 18)
RTECS #:9999999ZZ

Name:ING 17:AIR PURIFYING RESPS DO NOT PROTECT WORKERS IN
    OXYG-DEFICIENT ATM. IF RESPS ARE USED, OSHA REQS WRITTEN (ING 19)
RTECS #:9999999ZZ

Name:ING 18:NIOSH APPRVD RESP PROT PROGRAM THAT INCL @ LST: MED
    CERTIFICATION, TRAINING, FIT-TESTING, PERIODIC ENVIR(ING 20)
RTECS #:9999999ZZ

Name:ING 19:MONITORING, MAINTENANCE, INSPECTION, CLEANING, &
    CONVENIENT, SANITARY STORAGE AREAS.
RTECS #:9999999ZZ

Name:VENT:BECAUSE IT PVNTS CONTAMINANT DISPERSION INTO WORK AREA
    BY CONTROLLING IT AT ITS SOURCE.(103)
RTECS #:9999999ZZ

Name:PROT GLOVES:& TEFLON W/BREAKTHROUGH TIMES (BT) OF >8 HR &
    POLYETHYLENE/ETHYLENE VINYL ALCOHOL W/BT OF >4 HRS (ING 23)
RTECS #:9999999ZZ

Name:ING 22:ARE SUITABLE PPE MATERIALS.
RTECS #:9999999ZZ

Name:HYGIENE PRACT:EAT, DRINK/SMOKE IN WORK AREAS. PRACTICE GOOD
    PERSONAL HYGIENE AFTER USING MEK, ESPECIALLY BEFORE (ING 25)
RTECS #:9999999ZZ

Name:ING 24:EATING, DRINKING, SMOKING, USING TOILET/APPLYING
    COSMETICS.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50:(ORAL,RAT) 2737 MG/KG
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL MAY CAUSE HDCH, DIZZ,
    NAUS, VOMIT, WEAK, & UNCON. HIGH CONC CAN CAUSE SMARTING IN ADDN TO
    IRRIT OF EYES & RESP TRACT. IN 1 STUDY, EXPOS TO 100 PPM CAUSED
    SLIGHT NOSE & THROAT IRRIT, 200 P PM CAUSED MILD EYE IRRIT, & 300
    PPM WAS"OBJECTIONABLE" W/HDCH & THROAT IRRIT. IN ANOTHER STUDY,
    SHORT (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: EXPOS TO 500 PPM CAUSED NAUS & VOMIT.
    ALSO, WORKERS EXPOSED TO 300-600 PPM FOR UNSPECIFIED TIME PERIOD
    EXPERIENCED NUMBNESS OF FINGERS & ARMS; 1 WORKER EXPERIENCED LEG
    NUMBNESS W/TENDENCY TO  "GIVE WAY UNDER HIM. DIRECT EYE CONT CAN
    CAUSE PAINFUL IRRIT & CORNEAL INJURY. CHRONIC:RPTD SKIN CONT CAN
    (ING 6)
Medical Cond Aggravated by Exposure:DERMATITIS.

=======================  First Aid Measures  =======================

Eyes:DO NOT ALLOW VICTIM TO RUB/KEEP EYES TIGHTLY SHUT.
    GENTLY LIFT EYELIDS & FLUSH IMMED & CONTINUOUSLY W/FLOODING AMTS OF
    WATER FOR @ LST 15 MINS & UNTIL TRANSPORTED TO EMER MED FACILITY.
    CONSULT PH YS IMMED. SKIN:QUICKLY REMOVE CONTAMD CLTHG. RINSE
    W/FLOODING AMTS OF WATER FOR @ LST 15 MINS. WASH EXPOSED AREA
    W/SOAP & WATER. INHAL:REMOVE TO FRESH AIR, ADMIN 100% HUMIDIFIED
    SUPP OXYG (ING 7)

=====================  Fire Fighting Measures  =====================

Flash Point:16.0F,-8.9C
Lower Limits:1.4%
Upper Limits:11.4%
Extinguishing Media:CLASS 1B FLAMM LIQ. FOR SM FIRES, USE DRY CHEM,
    CO*2, WATER SPARY/ALCOHOL-RESIST FOAM. FOR LG FIRES, USE WATER,
    (SUPDAT)
Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . IF POSS
    W/OUT RISK, MOVE CNTNR FROM FIRE AREA. APPLY COOLING WATER TO CNTNR
    SIDES UNTIL WELL AFTER FIRE IS (SUPDAT)
Unusual Fire/Explosion Hazard:VAPORS MAY TRAVEL TO IGNITION SOURCE &
    FLASH BACK. CNTNR MAY EXPLODE IN FIRE. BURNING RATE = 4.1 MM/MIN.

==================  Accidental Release Measures  ==================

Spill Release Procedures:NOTIFY SFTY PERS, ISOLATE & VENTILATE AREA,
    DENY ENTRY, & STAY UPWIND. SHUT OFF IGNIT SOURCES. CLEANUP PERS
    SHOULD PROTECT AGAINST EXPOS. TAKE UP SM SPILLS W/EARTH, SAND,
    VERMICULITE/OTHER ABSORB, NON COMBUST MATL & PLACE IN SUITABLE
    CNTNRS. (ING 11)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:PRVNT PHYSICAL DAMAGE TO CNTNRS. STORE
    IN COOL, DRY, WELL-VENTILATED AREA AWAY FROM HEAT, INCOMPATIBLES
    (SEC 5). PERIODICALLY CHECK CNTNRS FOR LEAKS.
Other Precautions:TO REDUCE POTNTL HLTH HAZS, USE SUFFICIENT
    DILUTION/LOC EXHAUST VENT TO CTL AIRBORNE CONTAMINANTS & TO
    MAINTAIN CONCS @ LOWEST PRACTICAL LEVEL. TO PVNT STATIC SPKS, ELEC
    GROUND & BOND ALL EQUIP USED W ITH MEK.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:SEEK PROFESSIONAL ADVICE PRIOR TO RESP SELECTION
    & USE. FOLLOW OSHA RESP REGS (29 CFR 1910.134) &, IF NEC, WEAR
    NIOSH APPRVD RESP. FOR <1000 PPM, USE ANY NIOSH APPRVD POWDERED
    AIR-PURIFYING RESP W/ORG  VAP CARTRIDGES (OVCS)/ANY NIOSH(ING 15)
Ventilation:PROVIDE GEN & LOC EXHAUST VENT SYS TO MAINTAIN AIRBORNE
    CONCS BELOW OSHA PEL (SEC 2). LOC EXHAUST VENT IS PREF (ING 21)
Protective Gloves:CHEMICALLY PROT. BUTYL RUBB (ING 22)
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER .
    BOOTS, APRONS, & GAUNTLETS TO PVNT SKIN CONTACT.
Work Hygienic Practices:SEPARATE CONTAMD CLTHG WORK & STREET CLOTHES &
    LAUNDER BEFORE REUSE. REMOVE MEK FROM SHOES & CLEAN PPE. NEVER (ING
    24)
Supplemental Safety and Health
SATURATED VAP DENS:0.085 OR 1.368. SOL IN H*20:MEK IN WATER =28%; WATER
    IN MEK = 12.5%. APPEAR/ODOR:THE ODOR THRESHOLD IS 25 PPM. EXTING
    MEDIA:FOG/ALCOHOL-RESIST FOAM. FIRE FIGHT PROC:OUT. STAY AWAY F ROM
    ENDS OF TANKS. FOR MASSIVE FIRE IN CARGO AREA, USE MONITOR
    NOZZ/UNMANNED HOSE HOLDERS; IF POSS, W/DRAW(ING 2)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:176F,80C
Melt/Freeze Pt:M.P/F.P Text:-123F,-86C
Vapor Pres:71.2 @ 20C
Vapor Density:SUPDAT
Spec Gravity:0.8045
Evaporation Rate & Reference:2.7 (ETHER =1)
Solubility in Water:SUPP DATA
Appearance and Odor:COLORLESS, VOLATILE, LIQUID WITH A SWEET MINT OR
    ACETONE-LIKE ODOR. (SUPDAT)

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
INCL CHLOROSULFONIC ACID, OLEUM (FUMING SULFURIC ACID),
    POTASSIUM-T-BUTOXIDE, HYDROGEN PEROXIDE + NITRIC ACID, (ING 4)
Stability Condition to Avoid:EXPOSURE TO HEAT, IGNITION SOURCES, AND
    INCOMPATIBLES.
Hazardous Decomposition Products:THERMAL OXIDATIVE DECOMPOSITION OF MEK
    CAN PRODUCE CARBON DIOXIDE GAS AND ACRID SMOKE.

====================  Disposal Considerations  ====================

Waste Disposal Methods:INCIN IS POSS IN PERMIT-APPRVD FACILITIES. STEAM
    STRIPPING CAN BE USED TO REMOVE MEK FROM AQUEOUS WASTE. CONCS UP TO
    SEV WT % SOLVENT IN WATER CAN BE HNDLD W/BETTER THAN 99% REMOVAL
    EXPECTED. CONT SUP PLIER/LICENSED CONTRACTOR FOR DETAILED (ING 14)

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.

*** END OF RECORD ***
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NAMECAS
SULFUR 7704-34-9
PROGESTERONE 57-83-0
BENZOCAINE 94-09-7
PODOPHYLLIN, PODOPHYLLUM 9000-55-9
CHLOROBUTANOL, C4046 57-15-8
CAFFEINE, C3130 58-08-2
BENZALKONIUM CHLORIDE SOL 50%, BAK50 8001-54-5
7732-18-5
PERUVIAN BALSAM, P3340 8007-00-9
COLCHICINE, C4570 64-86-8
ACETIC ACID, A3040 64-19-7
IODINE SOLUTION 5%, 10D05 7553-56-2
7681-11-0
7732-18-5
ACETONITRILE, HPLC, 00692 75-05-8
01-D0301-000, PROFESSIONAL LYSOL BRAND (SUPDAT) 112-34-5
75-28-5
TILE-MATE PREMIUM THIN-SET-WHITE 65997-15-1
112945-52-5
HYDROMET DRY TILE GROUT ALL COLORS 14808-60-7
65997-15-1
13463-67-7
14464-46-1
1309-37-1
1309-37-1
1333-86-4
68187-11-1
THAT'S INCREDIBLE-Q QTS, 135800 111-76-2
67-63-0
ADIOS 34590-94-8
FURNITURE POLISH 136 8052-41-3
75-28-5
74-98-6
BRASS POLISH, 130140 102-71-6
111-76-2
5989-27-5
68476-85-7
WERTH GLASS CLEANER, G547 67-63-0
TA-0610 901, COLORED WALL GROUT 1317-65-3
1332-58-7
14808-60-7
65997-15-1
TA-0335 THINSET 14808-60-7
65997-15-1
TA-0650 901 DW ACCUCOLOR SANDED GROUT 1317-65-3
14808-60-7
65997-15-1
13463-67-7
2-BUTANONE, 48877 7732-18-5
78-93-3
67-56-1
1,2-DICHLOROETHANE, 48613 107-06-2
67-56-1
METHYLENE CHLORIDE, 48600 67-56-1
75-09-2
METHYL ETHYL KETONE 78-93-3
RIM EASE 68131-40-8
102-71-6
TCP 150 CLEAN SOL 67-64-1
108-88-3
78-93-3
108-10-1
SANI-DEX SOLUTION 64-17-5
88-04-0
ANTI-STATIC SCREEN CLEANER, 70018 76-13-1
75-69-4
67-63-0
124-38-9
PHENYLEPHRINE HCL NASAL SOLUTION USP 1%
INK JETS
MK 87 MOD O DEMOLITION CHARGE 7439-92-1
78-11-5
EN-CRB-Q, 941607 100-41-4
108-65-6
108-88-3
112926-00-8
123-86-4
1330-20-7
1333-86-4
1344-28-1
13463-67-7
147-14-8
25068-38-6
25550-14-5
25551-13-7
50-00-0
64742-48-9
64742-95-6
71-36-3
112945-52-5
95-63-6
98-82-8
EN-CRB-G, 941610 100-41-4
108-65-6
108-88-3
112926-00-8
123-86-4
1330-20-7
1333-86-4
1344-28-1
13463-67-7
147-14-8
25068-38-6
25550-14-5
25551-13-7
50-00-0
64742-48-9
64742-95-6
71-36-3
112945-52-5
95-63-6
98-82-8
BIOGUARD STABILIZER 100 GRANULAR, BB1023218 108-80-5
A2B18, SWP EXT GLOSS OIL BASE PAINT- (SUPDAT) 64742-88-7
64742-88-7
1330-20-7
136-52-7
14808-60-7
1333-86-4
PURE WHITE BASE X, PROMAR 400 INT LATEX (SUPDAT) 112-34-5
107-21-1
13463-67-7
SWEEN KIND TOUCH 7732-18-5
61789-40-0
7647-14-5
120-40-1
56-81-5
111-60-4
77-92-9
LITHIUM BASE MULTI-PURPOSE HI-TEMP GREASE
DRY MOLY LUBRICANT 71-55-6
67-64-1
108-88-3
1317-33-5
74-98-6
75-28-5
REGULAR CLEAR PVC SOLVENT CEMENT, 30881 9002-86-2
78-93-3
109-99-9
108-94-1
67-64-1
SHOT SHELL PRIMERS, DPE010000 7439-89-6
15245-44-0
7440-50-8
10022-31-8
1345-40-6
CORROX EDM 101 B
LERNER 1 HEMATOXYLIN 107-21-1
10043-01-3
517-28-2
64-19-7
7681-55-2
COMBO PRIMER, WHITE, 082 64742-47-8
ADVANCED CEL POLYESTER COATING, PART A 1480-96-6
9003-53-6
100-42-5
LEAD PELLETS 7439-92-1
7440-36-0
7440-31-5
7440-38-2
7440-50-8
7440-70-2
TROPICAL COLORED ORTHO POWDER

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