===================== Product Identification =====================
MSDS NAME:DREW 6005 PH CONTROL ADDITIVE
NIIN:00N061362
MSDS Number: CGFXL
=== Responsible Party ===
Company:ASHLAND CHEMICAL INC
Address:ONE DREW PLAZA
City:BOONTON
State:NJ
ZIP:07005
Country:US
Info Phone Num:201-263-7600
Emergency Phone Num:800-274-5263
CAGE:DO048
=== Contractor Identification ===
Company:ASHLAND CHEMICAL CO., ASHLAND OIL DIV.
Address:P.O. BOX 2219
Box:2219
City:COLUMBUS
State:OH
ZIP:43216
Phone:606-324-1133
CAGE:DO048
Company:DREW CHEMICAL CORP,DIV OF ASHLAND CHEMICAL CO
Address:ONE DREW CHEMICAL PLAZA
Box:City:BOONTON
State:NJ
ZIP:07005
Country:US
Phone:606-324-1133
CAGE:52454
============= Composition/Information on Ingredients =============
Name:HYDROCHLORIC ACID; (HYDROGEN CHLORIDE) (SARA 302/313)
(CERCLA)
CAS:7647-01-0
RTECS #:MW4025000
Fraction by Wt: 31%
OSHA PEL:5 PPM, C
ACGIH TLV:5 PPM, C
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 69%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:SUPDAT: PERSON WARM & QUIET. IF PERSON IS NOT BREATHING,
BEGIN ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT (ING 4)
RTECS #:9999999ZZ
Name:ING 3: ADMINISTER OXYGEN.
RTECS #:9999999ZZ
Name:SPILL PROC: CONDUCT THIS PROCEDURE. UNTRAINED PERSONNEL
SHOULD BE REMOVED FROM SPILL AREA. LARGE SPILLS: PERSONS (ING 6)
RTECS #:9999999ZZ
Name:ING 5: NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED
FROM AREA OF SPILL UNTIL CLEAN-UP IS COMPLETED. STOP (ING 7)
RTECS #:9999999ZZ
Name:ING 6: SPILL AT SOURCE. DIKE TO PREVENT SPREADING. PUMP TO
SALVAGE TANK.
RTECS #:9999999ZZ
Name:RESP PROT: SPECIFIED CONDITIONS (SEE YOUR INDUSTRIAL
HYGIENIST). ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD (ING 9)
RTECS #:9999999ZZ
Name:ING 8: BE IMPLEMENTED TO REDUCE EXPOSURE.
RTECS #:9999999ZZ
Name:EYE PROT: & FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: EXPOSURE CAUSES SEVERE
EYE IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS,
SWELLING AND EYE DAMAGE. SKIN: EXPOSURE CAUSES SEVERE SKIN
IRRITATION. SYMPTOMS MAY INCLUDE REDNESS , BURNING AND SEVERE SKIN
DAMAGE. INHALATION: EXPOSURE TO DUST IS POSSIBLE. EXPOSURE MAY BE
HARMFUL (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: OR FATAL. SYMPTOMS MAY INCLUDE SEVERE
IRRITATION AND BURNS TO THE NOSE, THROAT AND RESPIRATORY TRACT.
INGESTION: MAY BE HARMFUL OR FATAL. SYMPTOMS MAY INCLUDE SEVERE
IRRITATION AND BURNS OF THE MOUTH, THROAT AND DIGESTIVE TRACT.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS AND
LUNG DISORDERS (EG ASTHMA-LIKE CONDITIONS) MAY BE AGGRAVATED BY
EXPOSURE TO THIS MATERIAL.
======================= First Aid Measures =======================
First Aid:SKIN: REMOVE CONTAMD CLTHG. FLUSH EXPOSED AREA W/LARGE AMTS
OF WATER. IF SKIN IS DAMAGED, SEEK IMMED MED ATTN. IF SKIN IS NOT
DAMAGED & SYMPS PERSIST, SEEK MED ATTN. LAUNDER CLTHG BEFORE REUSE.
EYES: IF SYMPS DEVELOP, IMMED MOVE AWAY FROM EXPOS & INTO FRESH
AIR. FLUSH EYES GENTLY W/WATER FOR AT LST 15 MIN WHILE HOLDING
EYELIDS APART; SEEK IMMED MED ATTN. INGEST: SEEK IMMED MED ATTN. DO
(SUPDAT)
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER FOG OR CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . REFER TO PERSONAL PROTECTIVE EQUIPMENT SECTION OF MSDS.
Unusual Fire/Explosion Hazard:ACID REACTS WITH MOST METALS TO RELEASE
HYDROGEN GAS WHICH CAN FORM EXPLOSIVE MIXTURE WITH AIR.
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL SPILL: COVER CONTAMD SURF W/SODIUM
BICARBONATE OR SODA ASH/FLAKED LIM MIXTURE (50-50). MIX & ADD WATER
IF NECESSARY TO FORM SLURRY. SCOOP UP SLURRY & WASH SITE W/SODA ASH
SOLN. PROPER MIXING PRO CS ARE ESSENTIAL. TRAINED PERS SHOULD (ING
5)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:ADDITION TO WATER RELEASES HEAT WHICH
CAN RESULT IN VIOLENT BOILING AND SPATTERING. ALWAYS ADD SLOWLY AND
IN SMALL AMOUNTS. NEVER USE HOT WATER.
Other Precautions:NEVER ADD WATER TO ACIDS. ALWAYS ADD ACIDS TO WATER.
CONTAINERS OF THIS MATL MAY BE HAZARDOUS WHEN EMPTIED. SINCE
EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR, LIQUID &/OR
SOLID) ALL HAZARD PRECA UTIONS GIVEN IN MSDS MUST BE OBSERVED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF WORKPLACE EXPOS LIM(S) OF PROD/ANY COMPONENT
IS EXCEEDED, NIOSH APPRVD AIR SUPPLIED RESPIRATOR IS ADVISED IN
ABSENCE OF PROPER ENVIRONMENTAL CONTROL. OSHA REGS ALSO PERMIT
OTHER NIOSH APPRVD RESPIR ATORS (NEG PRESS TYPE) UNDER (ING 8)
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL &/OR LOCAL EXHAUST)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLVS.
Protective Gloves:RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 10)
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . TO
PREVENT SKIN CONTACT, WEAR IMPERVIOUS CLOTHING & BOOTS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRST AID PROC: NOT INDUCE VOMITING. VOMITING WILL CAUSE FURTHER DAMAGE
TO MOUTH & THROAT. IF CONSCIOUS & ALERT, IMMED RINSE MOUTH W/WATER
& GIVE MILK OR WATER TO DRINK. IF POSS, DO NOT LEAVE INDIVIDU AL
UNATTENDED. INHAL: IF SYMPS DEVELOP,IMMED MOVE AWAY FROM EXPOS &
INTO FRESH AIR. SEEK IMMED MED ATTN; KEEP (ING 3)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:108F,42C
Vapor Pres:55 @ 68F
Vapor Density:1.27
Spec Gravity:1.160
Evaporation Rate & Reference:2.00 (N-BUTYL ACETATE=1)
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG ALKALIES, ALKALI METALS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY FORM HYDROGEN CHLORIDE, ACID
VAPORS, ETC.
==================== Disposal Considerations ====================
Waste Disposal Methods:SM SPILL: FLUSH DOWN DRAIN W/LG AMTS OF WATER
I/A/W APPLIC FED, STATE & LOC REGS. LG SPILL: COLLECT & ADD SLOWLY
TO LG VOL OF AGITATED SOLN OF SODA ASH & SLAKED LIME. ADD
NEUTRALIZED SOLN TO EXCESS RU NNING WATER I/A/W APPLIC FED, STATE &
LOC REGS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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