===================== Product Identification =====================
MSDS NAME:METCO 81NS,81VF-NS,AMDRY 305,307,DIAMALLOY 3004;METAL POWDER
NIIN:01-407-5369
MSDS Number: CGLHQ
=== Responsible Party ===
Company:SULZER METCO (US) INC
Address:1101 PROSPECT AVE
Box:1006
City:WESTBURY
State:NY
ZIP:11590-0201
Country:US
Info Phone Num:516-334-1300
Emergency Phone Num:516-334-1300,800-424-9300(CHEMTREC)
CAGE:01FK3
=== Contractor Identification ===
Company:SULZER METCO (US) INC
Address:1101 PROSPECT AVE
Box:City:WESTBURY
State:NY
ZIP:11590-2724
Country:US
Phone:516-334-1300
CAGE:01FK3
============= Composition/Information on Ingredients =============
Name:CHROMIUM (SARA 313) (CERCLA)
CAS:7440-47-3
RTECS #:GB4200000
Fraction by Wt: 70%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3; 9596
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:NICKEL (SARA 313) (CERCLA)
CAS:7440-02-0
RTECS #:QR5950000
Fraction by Wt: 20%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9596
Name:CARBON GRAPHITE, NATURAL
CAS:7782-42-5
RTECS #:MD9659600
Fraction by Wt: 10%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:15 MPPCF; Z-3
ACGIH TLV:2 MG/M3 RDUST; 9596
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYES: CONJUNCTIVAL IRRITATION,
LACRIMATION. SKIN: IRRITATION, DERMATITIS, SENSITIZATION, CHROME
LESIONS, CANCER. INHALATION: PNEUMOCONIOSIS, MUCOUS MEMBRANE
IRRITATION OR ULCERATION, CNS DEPRESSION, C ANCER OF LUNGS AND
NASAL SINUSES. INGESTION: IRRITATION TO RESPIRATORY SYSTEM AND GI
TRACT, CONFUSION, CONVULSIONS.
Explanation of Carcinogenicity:PER MSDS:CR+6,ACGIH A1;IARC GROUP 1;NTP
KNOWN CARCI.NICKEL,ACGIH A1,IARC GROUP 1,NTP REASONABLY ANTICIPATED
CARCINOGEN.
Effects of Overexposure:EYE: IRRITATION, LACRIMATION. SKIN: IRRITATION,
DERMATITIS, SENSITIZATION, CHROME LESIONS, DISCOLORATION, CANCER.
INHALATION: PNEUMOCONIOSIS, MUCOUS MEMBRANE IRRITATION
ORULCERATION, CNS DEPRESSION,CA NCER OF LUNGS AND NASAL SINUSES.
INGESTION: IRRITATION TO GI TRACT AND RESPIRATORY SYSTEM,
CONFUSION, CONVULSIONS.
Medical Cond Aggravated by Exposure:CONSULT PHYSICIAN.
======================= First Aid Measures =======================
Eyes: FLUSH WITH LARGE AMOUNTS OF WATER. IF IRRITATION
PERSISTS GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING.
WASH SKIN AREA WITH SOAP AND WATER.GET MEDICAL ATTENTION.
INHALATION: MOVE TO FRESH AIR. IF IRRITATION OR RESPIRATORY
DISTRESS PERSISTS, GET MEDICAL ATTENTION. INGESTION: GET MEDICAL
ATTENTION.
===================== Fire Fighting Measures =====================
Autoignition Temp:Autoignition Temp Text:NP
Extinguishing Media:USE CLASS D FIRE EXTINGUIGHER.
Fire Fighting Procedures:TREAT AS METALLIC FIRE.USE NIOSH/MSHA APPROVED
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING IF
INVOLVED IN FIRE.
Unusual Fire/Explosion Hazard:FINE METAL DUST FLAMM,MAY EXPLO WHEN EXPO
TO HEAT/FLAME/OXIDIZERS.CHROMIUM MAY IGNITE IF AIRBORNE IN PRESENCE
OF IGN SOURCE.DUSTS OF CARBON GRAPHITE MAY (SUPPL)
================== Accidental Release Measures ==================
Spill Release Procedures:VACUUM LOOSE POWDER ONLY WITH VACUUMS EQUIPPED
WITH HEPA FILTRATION. VACUUMS APPROPRIATE FOR USE WITH METALLIC
DUSTS SHOULD BE UTILIZED. WIPE AREA CLEAN. DO NOT USE WATER FOR
CLEAN UP OPERATIONS. DO N OT SWEEP. AVOID GENERATING AIRBORNE DUST.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLES.STORE
CONTAINERS IN WELL-VENTILATED,CLEAN,COOL,DRY AREA.STORE IN MANNER
TO MINIMIZE PUNCTURES AND BREAKAGE OF CONTAINERS
Other Precautions:AVOID INGESTION, INHALATION, EXCESSIVE SKIN CONTACT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:RESPIRATOR APPROVED BY NIOSH W/FILTER CARTRIDGES
APPROVED FOR DUST/FUMES/MISTS SHOULD BE WORN AT ALL TIMES DURING
THERMAL SPRAY PROCESS TO PROTECT FROM DUST/FUME
EXPOSURE.RESPIRATORS MAY ALSO BE WORN WHEN PRODUCT HANDLING
GENERATES DUST.
Ventilation:PRODUCT SHOULD BE USED WITH APPROPRIATE LOCAL EXHAUST
VENTILATION PROVIDED.
Protective Gloves:ALUMINIZED FOR SPRAY, RUBBER FOR OTHER.
Eye Protection:GOGGLES FOR OTHER THAN SPRAYING.SEE SUPP
Other Protective Equipment:EYE WASH STATION AND WASHING FACILITIES. EAR
PROTECTION FOR EXCESS NOISE. ALUMINIZED APRON FOR PLASMA SPRAY
PROCESS.
Work Hygienic Practices:WEAR APPROPRIATE PROTECTIVE CLOTHING AS
NECESSARY DURING PRODUCT HANDLING TO AVOID EXCESSIVE CONTACT WITH
SKIN.
Supplemental Safety and Health
WEAR DURING COMBUSTION SPRAYING SHADE #5, PLASMA SPRAYING UP TO 40 KW
SHADE #9, 40-60 KW SHADE #10 AND GREATER THAN 60KW SHADE #11.
================== Physical/Chemical Properties ==================
HCC:N1
Melt/Freeze Pt:M.P/F.P Text:2200F,1204C
Spec Gravity:2.8
Viscosity:NP
Solubility in Water:INSOLUBLE
Appearance and Odor:POWDER, NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CHROMIUM INCOMPATIBLE WITH OXIDIZERS;NICKEL
W/ACIDS,SULFUR,SELENIUM,WOOD,COMBUSTIBLES,NICKEL NITRATE;CARBON
W/OXIDIZERS.
Stability Condition to Avoid:AVOID GENERATING FINE METAL DUSTS WHICH
ARE FLAMMABLE AND MAY EXPLODE WHEN EXPOSED TO HEAT, FLAME, OR
OXIDIZERS.
Hazardous Decomposition Products:HAZARDOUS DECOMPOSITION PRODUCTS OF
CARBON GRAPHITE ARE CARBON MONOXIDE AND CARBON DIOXIDE. WELDING
FUMES.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:EMPTY PRODUCT CONTAINERS, PRODUCT WASTE AND
CLEANING MEDIA SHOULD BE STORED AND DISPOSED OF ACCORDING TO LOCAL,
STATE, AND FEDERAL REGULATORY GUIDELINES.CONTAINS CHEMICALS SUBJECT
TO REPORTING REQUIRE MENTS UNDER SEC 313
SARA/40CFR372:CHROMIUM,NICKEL.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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