===================== Product Identification =====================
MSDS NAME:186 5161 KODALITH FIXER AND REPLENISHER,TO MAKE 20GAL,PART B
NIIN:00D007169
Kit Part:Y
MSDS Number: CGLKB
=== Responsible Party ===
Company:EASTMAN KODAK COMPANY
Address:343 STATE STREET
City:ROCHESTER
State:NY
ZIP:14650
Country:US
Info Phone Num:716-477-3194 MSDS :800- 242-2424
Emergency Phone Num:716-722-5151
CAGE:19139
=== Contractor Identification ===
Company:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS
Address:343 STATE ST
Box:City:ROCHESTER
State:NY
ZIP:14650-1115
Country:US
Phone:716-722-5151/(800) 242-2424
CAGE:19139
Company:EASTMAN KODAK CO US CUSTOMER SERVICE/GOVERNMENT SALES
Address:800 LEE RD
Box:City:ROCHESTER
State:NY
ZIP:14650-3129
Country:US
Phone:800-828-6203
CAGE:5K871
============= Composition/Information on Ingredients =============
Name:SULFURIC ACID (SARA 302/313) (CERCLA)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 14%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3/3 STEL; 9596
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:ALUMINUM SULFATE
CAS:10043-01-3
RTECS #:BD1700000
Fraction by Wt: 10-15%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3; 9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 70-75%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50,RAT:3200MG/KG(M);2263MG/KG (F)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:GENERAL:CONTAINS SULFURIC ACID.IARC
HAS DETERMINED THAT OCCUPATIONAL EXPO TO STRONG INORGANIC
MISTS/VAPO CONTAINING SULFURTIC ACID IS CARCINOGENIC TO
HUMANS.PRODUCT NOT EXPECTED TO GENERATE MSIT/VAP W HEN PRODUCT
INSTRUCTIONS FOR MIX/USE ARE FOLLOWED.INHAL:EXPECTED TO BE LOW HAZ
FOR RECOMMENDED HNDLG.EYE:CAUSES(SIGN/SY)
Explanation of Carcinogenicity:PER MSDS:CARCINOGENICITY
CLASSIFICATION:ACGIH/NTP/OSHA:NONE;IARC:YES.SEE HEALTH HAZARDS
SECITION OF MSDS FOR EXPLANATION
Effects of Overexposure:HEALTH:IRRIT.SKIN:CAUSES IRRIT OR
BURNS.INGEST:MAY BE HARMFUL IF SWALLOWED.MAY CAUSE BURNS OF
GASTROINTESTINAL TRACT IF SWALLOWED.
Medical Cond Aggravated by Exposure:SOME ASTHMATICS OR HYPERSENSITIVE
OR SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT
BREATHING,WHEEZING,CHEST TIGHTNESS,STOMACH
UPSET,HIVES,FAINTNESS,WEAKNESS,DIARRHEA.
======================= First Aid Measures =======================
First Aid:INHAL:IF SYMPTOMATIC MOVE TO FRESH AIR.TREAT
SYMPTOMATICALLY.SYMPTOMS PERSIST GET MED ATTN.EYES:IMMED FLUSH
W/PLENTY OF WATER FOR @LEAST 15MINS.GET MED ATTN IMMED.SKIN:IMEMD
FLUSH W/PLENTY OF WATER FO R @LEAST 15MINS WHILE REMOVING CONTAM
CLOTH/SHOE.SYMPTOMS OCCUR GET MED ATTN.INGEST:DONT INDUCE
VOMIT.GIVE VICTIM GLASS OF WATER.NEVER GIVE ANYTHING BY MOUTH IF
UNCONSC.CALL DR/POIS CNTRL CNTR IMMED.
===================== Fire Fighting Measures =====================
Flash Point:NONE,NON-COMBUST
Autoignition Temp:Autoignition Temp Text:NP
Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:MAY REQUIRE NEUTRALIZATION IF
PH<2.0/>12.5.FLUSH TO SEWER W/LG AMTS OF WATER.OTHERWISE ABSORB
W/VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN CONTAINER FOR
CHEMICAL WASTE. CLEAN SURFACE THOROUGHL Y TO REMOVE RESIDUAL
CONTAMINATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID BREATH MIST @CONCEN >EXPO
LIMITS.AVOID EYE/SKIN/CLOTH CONTACT.USE W/ADEQU VENTI.KEEP CNTNR
TIGHTLY CLSD,AWAY FRM INCOMPAT SUBSTANCES.
Other Precautions:STRONGLY ACIDIC AQU SOLN.PROPERTIES:NO BIOCHEM OXY
DEMAND,NO POT TO CAUSE OXY DEPLETION IN AQU SYS,MOD POT TO AFFECT
SOME AQUATIC ORGANISMS,MOD POT TO AFFECT 2ND WASTE TREAT MICROBIAL
METABOLISM,LOW P OT TO AFFECT BIOCONCEN.AFT DIL (SUPPLEM)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF ENGINEERING CONTROLS DONT MAINTAIN AIRBORNE
CONCEN BELOW RECOMMENDED EXPO LIMITS,APPROV RESP MUST BE WORN.RESP
TYPE:FULL-FACE CARTRIDGE RESP ACID GAS W/DUST/MIST PREFILT.RESP
USED,INSTITUTE PROGRAM TO ASSURE COMPLIANCE W/29CFR1910.134.
Ventilation:USE GOOD GEN VENTI(TYP10 AIR CHANGES/HR).MATCH VENTI RATES
W/CONDITIONS.SUPPLEM LOC EXHAU VENTI,CLSD SYS,RESP PROT(SUPP)
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:SAFETY GLASSES W/SIDE SHIELDS, GOGGLES.
Other Protective Equipment:EYEBATH, WASHING FACILITIES, SAFETY SHOWER.
WEAR PROTECTIVE CLOTHING APPROPRIATE FOR RISK OF EXPOSURE.
Work Hygienic Practices:WASH CONTAM CLOTH BEF REUSE;DESTROY/CLEAN WELL
CONTAM SHOE.WASH WELL AFT HNDLG.
Supplemental Safety and Health
OTHER PRECAUT:W/LG AMT OF WATER/2ND WASTE TREAT MATL NOT EXPECTED TO
CAUSE ADVERSE ENVIRO EFFECTS. VENTI:MAY BE NEEDED IN SPEC
CIRCUMST(POOR VENTI SPACES,EVAPO FRM LG SURF,SPRAY,HEAT,ETC).
KEY1:HCC=C1 .
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:>212F,>100C
Melt/Freeze Pt:M.P/F.P Text:NP
Decomp Temp:Decomp Text:NP
Vapor Pres:18
Vapor Density:0.6
Spec Gravity:1.25
pH:<1.0
Viscosity:NP
Evaporation Rate & Reference:NP
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID, COLORELSS, ODORLESS
Percent Volatiles by Volume:70-75
Corrosion Rate:NP
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
BASES.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:SULFUR DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHAR/TREAT/DISPO MAY BE SUBJ TO NAT/STATE/LOC
LAWS.MAY REQUIRE NEUTRA IF PH<2.0.>12.5.FLUSH TO SEWER W/LG AMTS OF
H2O.SINCE EMPTIED CNTNR RETAINPROD RESIDUE FOLLOW LABEL WARN EVEN
AFT EMPTIED.CHEM SUBJ TO SEC 313 TITLE III/40CFR372:SUL,FURIC
ACID.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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