===================== Product Identification =====================
MSDS NAME:MINERAL SPIRITS 66
NIIN:00-285-8012
MSDS Number: BDTSD
=== Responsible Party ===
Company:ASHLAND CHEMICAL CO
Box:2219
City:COLUMBUS
State:OH
ZIP:43216
Country:US
Info Phone Num:614-790-3333
Emergency Phone Num:606-324-1133
CAGE:5A188
=== Contractor Identification ===
Company:ASHLAND CHEMICAL CO
Address:5200 PAUL BLAZEL MEMORIAL PARKWAY
Box:City:DUBLIN
State:OH
ZIP:43017
Country:US
Phone:614-889-4505
CAGE:5A188
============= Composition/Information on Ingredients =============
Name:ALIPHATIC PETROLEUM DISTILLATES.
Fraction by Wt: >95%
OSHA PEL:500 PPM
ACGIH TLV:100 PPM
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL RAT) IS NOT SPECIFIED.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CAN CAUSE SEVERE EYE IRRITATION,
REDNESS, TEARING AND BLURRED VISION. CAN CAUSE MODERATE SKIN
IRRITATION, DEFATTING & DERMATITIS, VAPORS CAN CAUSE NASAL &
RESPIRATORY IRRITATION, DIZZINESS, WEAKNESS, FATIGUE, NAUSEA,
HEADACHE, UNCONSCIOUSNESS AND EVEN ASPHYXIATION. CAN CAUSE
GASTROINTESTINAL IRRITATION & VOMITING.
Explanation of Carcinogenicity:NONE OF THE COMPONENTS IN THIS PRODUCT
EXCEEDING 0.1% BY WT IS LISTED BY IARC, NTP, OR OSHA AS A
CARCINOGEN.
Effects of Overexposure:EYE, SKIN, RESPIRATORY TRACT AND
GASTROINTESTINAL IRRITATION. CAN CAUSE TEARING, DIZZINESS,
WEAKNESS, FATIGUE, NAUSEA, HEADACHE, POSSIBLE UNCONSCIOUSNESS,
ASPHYXIATION, VOMITING, AND DIARRHEA. ASPIRAT ION OF MATERIAL INTO
THE LUNGS CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF EYE, SKIN
OR RESPIRATORY DISEASE MAY BE AT INCREASED RISK FROM EXPOSURE.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE VICTIM TO FRESH AIR. IF NOT BREATHING,
GIVE CPR. CALL A PHYSICIAN. EYES: IMMEDIATELY FLUSH WITH PLENTY OF
WATER FOR 15 MINUTES. CALL A PHYSICIAN. SKIN: WASH WITH PLENTY OF
SOAP AND WATER. REMOVE CONTAMINATED CLOTHING & SHOES. INGESTION:
DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE A PINT OF WATER TO
DRINK.GIVE NOTHING BY MOUTH IF UNCONSCIOUS. CALL A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:100F,37.8C
Lower Limits:0.7
Upper Limits:6.0
Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE GEAR. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR & MAY TRAVEL
ALONG THE GROUND OR BE MOVED BY VENTILATION AND IGNITED BY HEAT,
PILOT LIGHTS, OTHER FLAMES & IGNITION SOURCES.
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL SPILL: WIPE/SOAK UP WITH PAPER TOWEL OR
INERT ABSORBANT. PUT IN DISPOSAL CONTAINER. REMOVE RESIDUE WITH
SOLVENT. LARGE SPILL: EVACUATE AND VENTILATE AREA. IF POSSIBLE,
STOP LEAK. DIKE TO RETAIN RUN OFF. VACUUM UP FREE LIQUID. ABSORB
RESIDUE.
Neutralizing Agent:NONE
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL,DRY, WELL VENTILATED
AREA. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. PROTECT
CONTAINERS FROM PHYSICAL DAMAGE & IGNITION SOURCES.
Other Precautions:DRUMS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED.
SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPORS, LIQUID),
ALL HAZARD PRECAUTIONS GIVEN IN THE DATA SHEET MUST BE OBSERVED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION
EXPOSURES BELOW PEL(TLV), USE NIOSH/MSHA APPROVED RESPIRATORS AS
PER CURRENT 29 CFR 1910.134. INSTRUCTIONS/WARNINGS AND
NIOSH-RESPIRATOR DECISION LOGIC-PUB. #87.108.
Ventilation:PROVIDE SUFFICIENT GENERAL/LOCAL EXHAUST VENTILATION IN
PATTERN/VOLUME TO CONTROL INHALATION EXPOSURES BELOW OSHA'S PEL.
Protective Gloves:HEAVY DUTY NIRTRILE,RUBBER IS REQUIRED.
Eye Protection:SAFETY GLASSES/GOGGLES AND/OR FACESHIELD
Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER.
INDUSTRIAL-TYPE WORK CLOTHING, COVERALLS, APRONS, BOOTS &
PROTECTIVE GARMENTS AS REQD.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICE AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
DO NOT GET ON SKIN, IN EYES OR ON CLOTHING. DO NOT BREATHE VAPORS OR
MISTS. NEVER USE WELDING OR CUTTING TORCH ON OR NEAR DRUM (EVEN
EMPTY) BECAUSE PRODUCT (EVEN JUST RESIDUE) CAN IGNITE EXPLOSIVELY.
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:300F,149C
Vapor Pres:2.0
Vapor Density:4.9
Spec Gravity:0.770
Evaporation Rate & Reference:70.0%(ETHER=1)
Solubility in Water:UNK
Appearance and Odor:LIQUID,COLORLESS.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:HIGH TEMPERATURES.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, AND
OTHER TOXIC HYDROCARBON VAPORS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL
APPLICABLE FEDERAL,STATE AND LOCAL LAWS AND REGULATIONS.
INCINERATION IS RECOMMENDED.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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