===================== Product Identification =====================
MSDS NAME:LA 6660 (F)
NIIN:00N084147
MSDS Number: CGSHR
=== Responsible Party ===
Company:ASHLAND CHEMICAL INC
Box:2219
City:COLUMBUS
State:OH
ZIP:43216
Country:US
Info Phone Num:614-790-3333
Emergency Phone Num:800-274-5263
CAGE:34897
=== Contractor Identification ===
Company:ASHLAND CHEMICAL CO
Box:2219
City:COLUMBUS
State:OH
ZIP:43216-2219
Country:US
Phone:614-790-3333/800-274-5263
CAGE:34897
============= Composition/Information on Ingredients =============
Name:VM & P NAPHTHA; (ALIPHATIC PETROLEUM DISTILLATES)
CAS:64742-89-8
Fraction by Wt: 35-39%
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ACETONE (SARA 313) (CERCLA)
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 20-24%
OSHA PEL:1000 PPM
ACGIH TLV:750 PPM/1000 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:TOLUENE (SARA 313) (CERCLA)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 18%
OSHA PEL:200 PPM
ACGIH TLV:50 PPM, S
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:ACETIC ACID, ISOBUTYL ESTER; (ISOBUTYL ACETATE) (CERCLA)
CAS:110-19-0
RTECS #:AI4025000
Fraction by Wt: 8-12%
OSHA PEL:150 PPM
ACGIH TLV:150 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ISOPROPYL ALCOHOL; (ISOPROPANOL) (SARA 313)
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 6%
OSHA PEL:400 PPM
ACGIH TLV:400 PPM/500 STEL
Name:METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 4%
OSHA PEL:200 PPM, S
ACGIH TLV:200 PPM/250 STEL, S
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ETHANOL, 2-BUTOXY-; (ETHYLENE GLYCOL MONOBUTYL ETHER)
CAS:111-76-2
RTECS #:KJ8575000
Fraction by Wt: 1-5%
OSHA PEL:50 PPM, S
ACGIH TLV:25 PPM, S
Name:EFTS OF OVEREXP: IRRIT (NOSE, THROAT, RESP TRACT), CNS
DEPRESS (DIZZ, DROW, WEAK, FATG, NAUS, HDCH, UNCON), (ING 9)
RTECS #:9999999ZZ
Name:ING 8: VISUAL IMPAIRMENT (INCL BLINDNESS), & DEATH. TARGET
ORGAN EFTS: OVEREXP HAS BEEN SUGGESTED AS CAUSE OF (ING 10)
RTECS #:9999999ZZ
Name:ING 9: THE FOLLOWING EFTS IN LAB ANIMALS: BLOOD & LIVER
ABNORMS; NASAL, SPLEEN, TESTIS, NERV SYS, EYE, KIDNEY, (ING 11)
RTECS #:9999999ZZ
Name:ING 10: LUNG & BRAIN DMG. MAY CAUSE EYE DMG IN HUMANS.
TOLUENE MAY BE HARMFUL TO FETUS BASED ON LAB ANIMAL (ING 12)
RTECS #:9999999ZZ
Name:ING 11: STUDIES. INTENTIONAL MISUSE BY DELIB INHAL OF
TOLUENE HAS CAUSED LIVER, KIDNEY & BRAIN DMG IN HUMANS. (ING 13)
RTECS #:9999999ZZ
Name:ING 12: RPTD EXPOS TO TOLUENE HAS CAUSED HIGH FREQUENCY
HEARING LOSS BASED ON EVIDENCE IN LAB ANIMALS; HUMAN (ING 14)
RTECS #:9999999ZZ
Name:ING 13: HLTH CONSEQUENCES OF THIS FINDING IS UNCERTAIN.
DEVEL INFO: CAUSES HARM TO FETUS IN LAB ANIMAL STUDIES. (ING 15)
RTECS #:9999999ZZ
Name:ING 14: HARM TO FETUS OCCURS ONLY AT EXPOS LEVELS THAT HARM
PREGNANT ANIMAL. RELEVANCE OF THESE FINDINGS TO (ING 16)
RTECS #:9999999ZZ
Name:ING 15: HUMANS IS UNCERTAIN. TOLUENE APPEARS ON THE NAVY
OCCUP CHEM REPRO HAZ LIST. CONSULT APPROP HEALTH (ING 17)
RTECS #:9999999ZZ
Name:ING 16: PROFESSIONALS CONCERNING LATEST HAZ LIST INFO &
SAFE HNDLG & EXPOS INFO . ANIMAL STUDIES CLEARLY (ING 18)
RTECS #:9999999ZZ
Name:ING 17: DEMONSTRATED DOSE-RELATED ADVERSE EFTS ON CNS,
HEMATOPOIETIC TISS, BLOOD, KIDNEYS & LIVER, ASSOC W/ADMIN(ING 19)
RTECS #:9999999ZZ
Name:ING 18: OF 2-BUTOXYETHANOL (EXTRACTED FROM DHHS (NIOSH)
PUBLICATION #90-118) .
RTECS #:9999999ZZ
Name:SUP DAT: INHAL: SEEK IMMED MED ATTN. KEEP WARM & QUIET. IF
NOT BRTHG, BEGIN ARTF RESP. IF BRTHG IS DFCLT, ADMIN (ING 21)
RTECS #:9999999ZZ
Name:ING 20: OXYGEN. NOTE TO MD: CONTAINS METHANOL WHICH CAN
CAUSE INTOXICATION & CNS DEPRESS & IS METABOLIZED TO (ING 22)
RTECS #:9999999ZZ
Name:ING 21: FORMIC ACID & FORMALDEHYDE. THESE METABOLITES CAN
CAUSE METABOLIC ACIDOSIS, VISUAL DISTURBS & BLINDNESS.(ING 23)
RTECS #:9999999ZZ
Name:ING 22: SINCE METABOLISM IS REQUIRED FOR THESE TOX SYMPS,
THEIR ONSET MAY BE DELAYED 6-30 HRS FOLLOWING INGEST. (ING 24)
RTECS #:9999999ZZ
Name:ING 23: ETHANOL COMPETES FOR SAME METABOLIC PATHWAY & HAS
BEEN USED TO PVNT METHANOL METABOLISM. ETHANOL ADMIN (ING 25)
RTECS #:9999999ZZ
Name:ING 24: IS INDICATED IN SYMP PATIENTS/AT BLOOD METHANOL
CONCS >20 UG/DL. METHANOL EFFECTIVELY REMOVED BY HEMODIALYSIS.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: IRRIT, INCL STINGING,
TEARING, REDNESS, SWELL & DMG. SKIN: MAY CAUSE MILD IRRIT.
PRLNG/RPTD EXPOS MAY DRY SKIN, INCL REDNESS, BURNING, DRYING &
CRACKING, BURNS. SKIN ABSORPTION IS POSS, & MAY CONTRIBUTE TO
SYMPS OF TOXICITY FROM OTHER RTES OF EXPOS. INGEST: SINGLE DOSE
ORAL TOXICITY MOD. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: MAY BE HARMFUL. CAN CENTER LUNGS
DURING SWALLOWING/VOMIT & CAUSE LUNG INFLAMM &/OR DMG. INHAL: EXPOS
TO VAP/MIST POSS. SHORT-TERM INHAL TOXICITY IS LOW. BRTHG SML AMTS
DURING NORM HNDLG IS N OT LIKELY TO CAUSE HARMFUL EFTS; BRTHG LGE
AMTS MAY BE HARMFUL. SYMPS OF EXPOS: GI IRRIT (NAUS, VOMIT, DIARR),
(ING 8)
Medical Cond Aggravated by Exposure:PREEXISTING BLOOD AND LIVER
ABNORMALITIES. NASAL, SPLEEN, TESTIS, NERVOUS SYSTEM, EYE, KIDNEY,
LUNG, AND BRAIN DAMAGE.
======================= First Aid Measures =======================
First Aid:EYE:IMMED MOVE TO FRESH AIR. FLUSH GENTLY W/WATER FOR AT
LEAST 15 MIN, HOLDING EYELIDS APART; SEEK IMMED MED ATTN.
SKIN:REMOVE CONTAM CLTHG & LAUNDER BEFORE REUSE. WASH SKIN W/SOAP &
WATER. IF SYMPS P ERSIST, SEEK MED ATTN. INGEST:IMMED DRINK 2
GLASSES OF WATER & INDUCE VOMIT BY GIVING IPECAC SYRUP/BY PLACING
FINGER AT BACK OF THROAT. NEVER GIVE ANYTHING BY MOUTH TO UNCON
PERS. GET MED (SUP DAT)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:<-1F,<-18C
Lower Limits:1.1%
Extinguishing Media:REGULAR FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . REFER TO THE PERSONAL PROTECTIVE EQUIPMENT SECTION OF
THIS MSDS.
Unusual Fire/Explosion Hazard:HIGHLY VOLAT & READILY GIVES OFF VAPS
WHICH MAY TRAVEL ALONG GROUND/BE MOVED BY VENT & IGNITED BY PILOT
LIGHTS, OTHER FLAMES, SPKS, HEATERS, SMKNG, (SUP DAT)
================== Accidental Release Measures ==================
Spill Release Procedures:SML SPILL:ABSORB ON VERMICULITE, FLOOR
ABSORB/OTHER ABSORB MATL. LGE SPILL:ELIM ALL IGNIT SOURCES (FLARES,
FLAMES INCL PILOT LIGHTS, ELEC SPKS). WEAR PROT EQUIP. STOP SPILL
AT SOURCE. PVNT FROM ENTERI NG DRAINS, SEWERS. CONT NEHC FOR MORE
INFO .
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:CONTRS MAY BE HAZ WHEN EMPTIED. SINCE
EMPTIED CONTRS RETAIN PROD RESIDUE (VAP, LIQ &/OR SOLID), ALL HAZ
PREC GIVEN IN MSDS MUST BE OBSERVED.
Other Precautions:ALL 5 GAL PAILS & LARGER METAL CONTRS INCL TANK CARS
& TANK TRUCKS SHOULD BE GROUNDED &/OR BONDED WHEN TRANSFERRED. USE
IN ELEVATED TEMP PROCESSES SHOULD BE THORO EVALUATED TO ESTABLISH &
MAINT SAFE C NDTNS. CONT NEHC FOR MORE INFO .
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOS LIM IS EXCEEDED, NIOSH APPRVD AIR SUPP
RESP IS ADVISED IN ABSENCE OF PROPER ENVIRON CTL. OSHA REGS ALSO
PERMIT OTHER NIOSH APPRVD RESPS (NEG PRESS TYPE) UNDER SPECIFIED
CNDTNS. IMPLEMENT ENGI NEERING/ADMIN CONTROLS TO REDUCE EXPOS.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA . WEAR IMPERVIOUS CLOTHING AND BOOTS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ:ELEC MOTORS, STATIC DISCHARGE/OTHER IGNIT SOURCES AT
LOCATIONS DISTANT FROM MATL HNDLG POINT. NEVER USE WELDING/CUTTING
TORCH ON/NEAR DRUM (EVEN EMPTY) BECAUSE PROD (EVEN JUST RESIDUE)
CAN I GNITE EXPLO. FIRST AID PROC:ATTN IMMED.(ASPIR INTO LUNGS CAN
CAUSE CHEM PNEUM). INHAL:IMMED MOVE TO FRESH AIR. (ING 20)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:133F,56C
Vapor Pres:181.7@68F
Spec Gravity:0.790 @ 77F
Evaporation Rate & Reference:SLOWER THAN ETHYL ETHER
Appearance and Odor:LIQUID (HOMOGENOUS SOLUTION)
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY FORM CARBON DIOXIDE AND CARBON
MONOXIDE, VARIOUS HYDROCARBONS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
LOCAL, STATE AND FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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