===================== Product Identification =====================
MSDS NAME:LEADED GASOLINE, REGULAR GRADE, LR
NIIN:00N087829
MSDS Number: CHKDS
=== Responsible Party ===
Company:HAWAIIAN INDEPENDENT REFINERY INC
Address:91-315 KOMOHANA ST
City:EWA BEACH
State:HI
ZIP:96707
Country:US
Info Phone Num:808-547-3900
Emergency Phone Num:800-424-9300 (CHEMTREC)
CAGE:8P840
=== Contractor Identification ===
Company:HAWAIIAN CEMENT
Address:91-055 KAOMI LOOP
Box:City:EVA BEACH
State:HI
ZIP:96707
Country:US
Phone:808-673-4200
CAGE:HAWAX
Company:HAWAIIAN INDEPENDENT REFINERY, INC.
Address:733 BISHOP STREET
Box:3379
City:HONOLULU
State:HI
ZIP:96842
Country:US
Phone:808-547-3111 OR 800-424-9300
CAGE:8P840
============= Composition/Information on Ingredients =============
Name:BENZENE (SARA 313) (CERCLA)
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: 4%
OSHA PEL:SEE 1910.1028
ACGIH TLV:10 PPM; A2
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:CYCLOHEXANE (SARA 313) (CERCLA)
CAS:110-82-7
RTECS #:GU6300000
Fraction by Wt: 1%
OSHA PEL:300 PPM
ACGIH TLV:300 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:ETHYL BENZENE (SARA 313)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: 10%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM/125 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:METHYL TERT-BUTYL ETHER (MTBE) (SARA 313) (CERCLA)
CAS:1634-04-4
RTECS #:KN5250000
Fraction by Wt: 11%
OSHA PEL:N/K
ACGIH TLV:N/K
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:TETRAETHYL LEAD (SARA 302/313) (CERCLA)
CAS:78-00-2
RTECS #:TP4550000
Fraction by Wt: 0.1%
OSHA PEL:0.075 MG (PB)/M3, S
ACGIH TLV:0.1 MG(PB)/M3, S
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:TOLUENE (SARA 313) (CERCLA)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 15%
OSHA PEL:200 PPM
ACGIH TLV:50 PPM, S
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:XYLENE (SARA 313) (CERCLA)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 25%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM/150 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: PROLONGED/REPEATED CONTACT MAY
CAUSE DRYNESS OF SKIN WHICH CAN RESULT IN DERMATITIS/MORE SERIOUS
SKIN DISORDERS. VAPORS/MISTS MAY CAUSE PULMONARY IRRITATION,
DIZZINESS, NAUSEA/UNCONSCIOUSNESS, PARTICULARLY IN CONFINED
SPACES. CENTRAL NERVOUS SYSTEM DEPRESSANT. API STUDIES SHOW (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:BENZENE: IARC MONO, SUPP, VOL 7, PG 120,
1987: GRP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994: KNOWN TO BE
CARCIN. (SUP DAT)
Effects of Overexposure:HLTH HAZ: INCREASES IN RAT & MICE KIDNEY TUMORS
AFTER LENGTHY EXPOSURE, HUMAN CORRELATION IF UNCERTAIN. LEAD &
TOLUENE APPEAR ON THE HAVY OCCUPATIONAL CHEMICAL REPRODUCTIVE
HAZARDS LIST. CONSULT APPRO PRIATE HEALTH PROFESSIONALS CONCERNING
LATEST HAZARD LIST INFORMATION & SAFE HANDLING & EXPOSURE
INFORMATION .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:SKIN: REMOVE AFFECTED CLTHG & FLUSH AREA W/LGE AMTS OF WATER
FOR 15 MIN; SOAP MAY BE USED TO AID IN REMOVAL. SEEK MED ATTN
DEPENDING UPON SEVERITY OF CONT. INHAL: MOVE TO FRESH AIR. ADMIN
ARTF RESP & OXYGEN IF NEC. SEEK MED ATTN. EYES: IMMED FLUSH
W/RUNNING WATER FOR 20 MIN, LIFTING EYELIDS PERIODICALLY TO ASSURE
COMPLETE FLUSHING. SEEK IMMED MED ATTN. INGEST: DO NOT INDUCE
VOMIT. (SUP DAT)
===================== Fire Fighting Measures =====================
Flash Point:-50F,-46C
Lower Limits:1.4%
Upper Limits:7.6%
Extinguishing Media:FOAM, DRY CHEM, CO*2. WATER FOG/WATER SPRAY ARE OF
VALUE FOR COOLING, BUT MAY NOT ACHIEVE EXTING DUE TO LOW FL PT.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . COOL TANKS AND CONTAINERS EXPOSED TO FIRE WITH WATER.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND MAY
TRAVEL TO IGNITION SOURCES AND FLASHBACK.
================== Accidental Release Measures ==================
Spill Release Procedures:STOP FLOW OF MATERIAL. REMOVE ALL SOURCES OF
IGNITION. WEAR FULL PROTECTIVE CLOTHING. CONTAIN SPILL USING SAND
OR ABOSRBENT MATERIAL. RUNOFF MAY CREATE AN EXPLOSION HAZARD,
PREVENT FROM ENTERING SEWER S AND WATERWAYS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:SMOKING SHOULD BE PROHIBITED WHEN
TRANSFERRING PRODUCT. DO NOT SIPHON GASOLINE BY MOUTH.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE FOR MOST USES. NIOSH APPROVED ORGANIC VAPOR
RESPIRATOR OR SCBA FOR SPILL EMERGENCIES.
Ventilation:MAINTAIN VAPOR CONCENTRATION BELOW TLV. EQUIPMENT SHOULD BE
SPARK-PROOF.
Protective Gloves:IMPERVIOUS (NEOPRENE, NITRILE RUBBER).
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER . WEAR IMPERVIOUS (NEOPRENE, NITRILE RUBBER) CLOTHING.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
VP: <11.5 PSI @ 100F. EXPLAN OF CARCIN: OSHA REGULATED: CFR 29
1910.1028. HUMAN: BLOOD. FIRST AID PROC: RINSE MOUTH THORO W/WATER.
CONT MD/LOC POIS CTL CTR FOR MED ATTN.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>85F,>29C
Vapor Pres:SUP DAT
Vapor Density:3.5-5.0
Spec Gravity:0.75
Evaporation Rate & Reference:>1.0 (ETHYL ETHER=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:RED LIQUID WITH MILD AROMATIC ODOR.
Percent Volatiles by Volume:>95
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS SUCH AS LIQUID CHLORINE AND OXYGEN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:USE ABSORBENT MATERIAL SUCH AS CLAY OR
DIATOMACEOUS EARTH TO CLEAN UP SPILL. DISPOSE OF MATERIAL AND ANY
CONTAMINATED SOIL IN AN APPROVED DISPOSAL SITE. COMPLY WITH ALL
APPLICABLE FEDERAL, STATE AND L OCAL WASTE DISPOSAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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