===================== Product Identification =====================
MSDS NAME:04-400-WB POLYURETHANE ENAMEL WB
NIIN:00F031523
MSDS Number: CHMMR
=== Responsible Party ===
Company:COLUMBIA PAINT CO
Address:N 112 HAVEN ST
Box:4569
City:SPOKANE
State:WA
ZIP:99202-3822
Country:US
Info Phone Num:509-535-9741
Emergency Phone Num:509-535-9741
Preparer's Name:BILL HEIBER
CAGE:1DY82
=== Contractor Identification ===
Company:COLUMBIA PAINT COMPANY
Address:NORTH 112 HAVEN STREET
Box:City:SPOKANE
State:WA
ZIP:99202-3822
Phone:(509) 535-9741
CAGE:1DY82
============= Composition/Information on Ingredients =============
Name:STODDARD SOLVENT (PETROLEUM DISTILLATE), MINERAL SPIRITS
*98-2*
CAS:8052-41-3
RTECS #:WJ8925000
Fraction by Wt: 38.38%
Other REC Limits:525 MG/CUM
OSHA PEL:500 PPM
ACGIH TLV:100 PPM
Name:TITANIUM DIOXIDE, TITANIUM OXIDE (SUSPECTED ANIMAL
CARCINOGEN, IARC GROUP 3) *98-2*
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 25.06%
OSHA PEL:15 MG/CUM
ACGIH TLV:10 MG/CUM (DUST)
Name:COBALT (II) 2-ETHYLHEXANOATE, COBALT OCTOATE *98-2*
CAS:136-52-7
Fraction by Wt: 0.14%
Name:VOLATILE ORGANIC CONTENT: 3.82 LBS/GAL; 457 G/L
RTECS #:9999999VO
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: MAY CAUSE RESPIRATORY
IRRITATION, CNS DEPRESSION. DELIBERATELY CONCENTRATING SOLVENT
VAPOR MAY RESULT IN PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE/DEATH.
SKIN: IRRITATION, DERMATITIS. EYES: SEVERE IRRITANT. INGESTION:
HARMFUL/FATAL. GI IRRITANT. MAY AFFECT THE CNS/BLOOD/LIVER/KIDNEY &
HEARING. (SEE SUPP)
Explanation of Carcinogenicity:NONE
Effects of Overexposure:HEADACHES, DIZZINESS, LOSS OF COORDINATION,
UNCONSCIOUSNESS, IRRITATION, DRY/DEFATTING OF SKIN, REDNESS,
TEARING, BLURRED VISION, ITCHING, RASH, HIVES, SWELLING, NAUSEA,
VOMITING, DIARRHEA, GI DISTURB ANCES, COUGHING, ABDOMINAL PAIN
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN/LUNG
DISEASES/ALLERGIES.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE FROM EXPOSURE. START RESUSCITATION/GIVE
OXYGEN. INGESTION: DON'T INDUCE VOMITING. EYES: FLUSH W/CLEAR WATER
FOR 15 MINS. SKIN: WASH W/SOAP & WARM WATER. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:106F
Lower Limits:2.1
Upper Limits:14.4
Extinguishing Media:FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:EVACUATE UNPROTECTED PERSONNEL. WATERSPRAY MAY
BE INEFFECTIVE, BUT MAY BE USED TO COOL CLOSED CONTAINERS. USE FULL
PROTECTIVE EQUIPMENT W/SCBA.
Unusual Fire/Explosion Hazard:ISOLATE FROM IGNITION SOURCES. VAPORS
FORM EXPLOSIVE CONCENTRATIONS W/AIR, TRAVEL LONG
DISTANCES/FLASHBACK. IN CLOSED CONTAINERS PRESSURE BUILDUP MAY
OCCUR.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE
AREA. CONTAIN & REMOVE W/INERT ABSORBENT & NON-SPARKING TOOLS.
====================== Handling and Storage ======================
Handling and Storage Precautions:DON'T STORE NEAR HEAT, SPARKS/FLAME.
NO SMOKING/OPEN LIGHTS. USE W/ADEQUATE VENTILATION. STORE IN SEALED
CONTAINERS AWAY FROM SPACE HEATING EQUIPMENT.
Other Precautions:AVOID CONTACT W/EYES. AVOID PROLONGED/REPEATED
CONTACT W/SKIN & BREATHING OF VAPORS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR A PROPERLY FITTED VAPOR/PARTICULATE
RESPIRATOR APPROVED BY NIOSH/MSHA DURING APPLICATION UNTIL ALL
VAPORS & SPRAY MISTS ARE EXHAUSTED. CONFINED AREA: USE A NIOSH/MSHA
APPROVED POSITIVE-PRESSURE, AIR SUPPLIED RESPIRATOR/USE HOODS.
Ventilation:ADEQUATE TO PREVENT THE TLV'S OF HAZARDOUS INGREDIENTS
BEING EXCEEDED.
Protective Gloves:CHEMICAL RESISTANT NITRILE/NEOPRENE
Eye Protection:SAFETY EYEWEAR W/SPLASHGUARDS/SIDESHIELD
Other Protective Equipment:RUBBER GLOVES, PROTECTIVE APRON/CLOTHING
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH HANDS BEFORE EATING/USING WASHROOM. SMOKE IN SMOKING
AREA ONLY.
Supplemental Safety and Health
INGESTION CONT'D: COBALT COMPOUNDS MAY CAUSE NERVE DEAFNESS.
REPEATED/PROLONGED EXPOSURE MAY CAUSE CARDIOMYOPATHY, HEART
ENLARGEMENT & ECG ABNORMALITIES.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:300F
Vapor Density:>1
Spec Gravity:1.13
Evaporation Rate & Reference:SLOWER THAN N-BU ACETATE
Appearance and Odor:WHITE LIQUID W/SOLVENT ODOR
Percent Volatiles by Volume:57.46
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXYGEN, STRONG OXIDANTS, STRONG ACIDS, STRONG BASES, AMINES, SOME
PLASTICS & RUBBER
Stability Condition to Avoid:HEAT, SPARKS, ELECTRICAL EQUIPMENT, OPEN
FLAME, HIGH TEMPERATURES, DIRECT HEATING & OTHER IGNITION SOURCES.
Hazardous Decomposition Products:CO2, CO, OXIDES OF NITROGEN, AROLEIN
==================== Disposal Considerations ====================
Waste Disposal Methods:DON'T INCINERATE CLOSED CONTAINER. DISPOSE OF IN
ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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