===================== Product Identification =====================
MSDS NAME:S00339 RED OXIDE
NIIN:00F039473
MSDS Number: CHMNS
=== Responsible Party ===
Company:SHERWIN WILLIAMS CO THE SPECIALTY DIV
Address:31500 SOLON ROAD
City:SOLON
State:OH
ZIP:44139-5000
Country:US
Info Phone Num:800-777-2966/800-247-3266
Emergency Phone Num:800-777-2966/216-292-7400
CAGE:54626
=== Contractor Identification ===
Company:SHERWIN WILLIAMS COMPANY
Address:101 PROSPECT AVE NW
City:CLEVELAND
State:OH
ZIP:44115
Country:US
Phone:216-566-2902
CAGE:54626
Company:SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC.
Address:26300 FARGO AVENUE
Box:City:BEDFORD HEIGHTS
State:OH
ZIP:44146
Country:US
Phone:216-292-7400 OR 216-595-8634
CAGE:09800
============= Composition/Information on Ingredients =============
Name:PROPANE (DIMETHYLMETHANE) *98-2*
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 14%
Other REC Limits:1800 MG/CUM
OSHA PEL:1000 PPM
ACGIH TLV:SIMPLE ASPHYXIANT
Name:BUTANE, N-BUTANE *98-2*
CAS:106-97-8
RTECS #:EJ4200000
Fraction by Wt: 13%
Other REC Limits:800 PPM
OSHA PEL:800 PPM
ACGIH TLV:1900 MG/CUM
Name:ETHYL BENZENE *98-2*
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: 4%
Other REC Limits:100 PPM
OSHA PEL:435 MG/CUM
ACGIH TLV:434 MG/CUM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:XYLENE, DIMETHYLBENZENE, XYLOL (IARC - GROUP 3) *98-2*
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 23%
Other REC Limits:100 PPM
OSHA PEL:100 PPM
ACGIH TLV:100 PPM, SKIN
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:ACETONE; DIMETHYL KETONE; 2-PROPANONE *98-2*
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 22%
OSHA PEL:2400 MG/CUM
ACGIH TLV:750 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:TALC (POWDER), (ASBESTOS FREE), TALCUM; HYDROUS MAGNESIUM
SILICATE (IARC - GROUP 3) *98-2*
CAS:14807-96-6
RTECS #:WW2710000
Fraction by Wt: 5.9%
OSHA PEL:2 MG/CUM (RESP DUST)
ACGIH TLV:2 MG/CUM (RESP DUST)
Name:ZINC COMPOUND
Fraction by Wt: 4%
Name:VOLATILE ORGANIC CONTENT: 55.2%/WT; COMPOUNDS 3.71 LBS/GAL
RTECS #:9999999VO
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:IRRITATION OF EYES, SKIN & RESPIRATORY
SYSTEM. MAY CAUSE NERVOUS SYSTEM DEPRESSION & POSSIBLE DEATH.
PROLONGED OVEREXPOSURE TO SOLVENT MAY CAUSE ADVERSE EFFECTS TO THE
LIVER/URINARY/BLOOD FORMING/CARD IOVASCULAR & REPRODUCTIVE SYSTEM.
HEXANMAY CAUSE DAMAGE TO NERVE TISSUE OF THE ARMS & LEGS(PERIPHERAL
NEUROPATHY).(SUPP
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, UNCONSCIOUSNESS, HEADACHE,
DIZZINESS, NAUSEA, LOSS OF COORDINATION, REDNESS, ITCHING, BURNING
SENSATION.
Medical Cond Aggravated by Exposure:NONE
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. KEEP WARM
& QUIET. SKIN: WASH THOROUGHLY W/SOAP & WATER. EYES: FLUSH W/LARGE
AMOUNTS OF WATER FOR 15 MINS. INGESTION: NEVER GIVE ANYTHING BY
MOUTH T O AN UNCONSCIUOS PERSON. DON'T INDUCE VOMITING. GIVE
SEVERAL GLASSES OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:<0F
Lower Limits:0.7
Upper Limits:12.8
Extinguishing Media:CO2, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE FULL PROTECTIVE EQUIPMENT & SCBA. WATER
SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE
PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE DUE TO
EXTREME HEAT. APPLICATION TO HOT SURFACES NEEDS SPECIAL PRECAUTION.
OVEREXPOSURE TO DECOMPOSITION MAY CAUSE A HEALTH HAZARD
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE SOURCES OF IGNITION. VENTILATE AREA &
REMOVE W/INERT ABSORBENT.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM HEAT/SPARKS/OPEN FLAME.
KEEP AREA VENTILATED. USE APPROVED BONDING/GROUNDING PROCEDURES.
DON'T PUNCTURE/INCINERATE TO TEMPS >120F.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. DON'T TAKE INTERNALLY.
DON'T SMOKE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING &
INHALING THE CONTENTS CAN BE HARMFUL/FATAL. VAPORS WILL ACCUMULATE
READILY & MAY I GNITE EXPLOSIVELY. (SEE SUPP)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERSONAL EXPOSURE CAN'T BE CONTROLLED BELOW
APPLICABLE LIMITS, WEAR A PROPERLY FITTED ORGANIC VAPOR/PARTICULATE
RESPIRATOR APPROVED BY NIOSH/MSHA. WHEN SANDING/ABRADING THE DRIED
FILM, WEAR A DUST/ MIST RESPIRATOR APPROVED BY NIOSH/MSHA.
Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE TO
MAINTAIN BELOW APPLICABLE EXPOSURE LIMITS.
Protective Gloves:RECOMMENDED
Eye Protection:SAFETY GLASSES W/UNPERFORATED SIDESHIELD
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH HANDS AFTER USING.
Supplemental Safety and Health
HLTH HZRD CONT'D: METHYL ETHYL KETONE MAY INCREASE THE NERVOUS SYSTEM
EFFECTS OF OTHER SOLVENTS. OVEREXPOSURE TO SOLVENTS MAY CAUSE
PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. PREC CONT'D: CONTENTS
EXTRE MELY FLAMMABLE & UNDER PRESSURE. AVOID BREATHING VAPOR/SPRAY
MIST. AVOID CONTACT W/SKIN & EYES.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:<0F-395F
Vapor Density:>1
Evaporation Rate & Reference:FASTER THAN ETHER
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:HEAT, SPARKS & OPEN FLAME, HOT SURFACES.
Hazardous Decomposition Products:BY FIRE: CO2, CO.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS. WASTE MAY BE HAZARDOUS UNDER THE RCRA & MUST BE TESTED
FOR IGNITABILITY TO DETERMINE THE APPLICABLE EPA HAZARDOUS WASTE
NUMBERS. WASTE FROM METHYL ET HYL KETONE MAY REQUIRE TESTING FOR
EXTRACTABILITY.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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