===================== Product Identification =====================
MSDS NAME:SODIUM HYDROXIDE, PURUM PELLETS, S31810
Status Code:A
MSDS Number: CJFZN
=== Responsible Party ===
Company:FISHER SCIENTIFIC
Address:1 REAGENT LANE
City:FAIRLAWN
State:NJ
ZIP:07410
Country:US
Emergency Phone Num:201-796-7100
Chemtrec Ind/Phone:(800)424-9300
CAGE:1B464
=== Contractor Identification ===
Company:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464
============= Composition/Information on Ingredients =============
Name:LIMESTONE
CAS:1317-65-3
RTECS #:EV9580000
Minumum % Wt:5.
Maxumum % Wt:10.
OSHA PEL:15 MG/M3
ACGIH TLV:10 MG/M3
Name:QUARTZ
CAS:14808-60-7
RTECS #:VV7330000
Minumum % Wt:10.
Maxumum % Wt:20.
OSHA PEL:see Table Z-3
ACGIH TLV:0.1 MG/M3
Name:PROPANOIC ACID, 2-METHYL-, MONOESTER WITH
2,2,4-TRIMETHYL-1,3-PENTANEDIOL LD50: (ORAL, RAT) 6.86 ML/KG
CAS:25265-77-4
RTECS #:UF6000000
Minumum % Wt:1.
Maxumum % Wt:5.
Name:ACRYLIC COPOLYMER (CAS #, SUPPLIER CONFIDENTIAL)
Minumum % Wt:20.
Maxumum % Wt:30.
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:50.
Maxumum % Wt:60.
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENT 3
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: IRRITATION OF RESPIRATORY
TRACT. PROLONGED INHALATION MAY LEAD TO SNEEZING, PNEUMOCONIOSIS.
SKIN CONTACT: IRRITATION OF SKIN. EYE CONTACT: IRRITATION OF EYES.
INGESTION: INGESTION MAY CAUS E GASTRO-INTESTINAL DISTURBANCES.
SUPPLEMENTAL HEALTH INFO: CONTAINS CRYSTALLINE SILICA WHICH IS
CONSIDERED A HAZARD BY INHALATION. IARC HAS CLASSIFIED CRYSTALLINE
SILICA AS PROBABLY CARCINOGENIC FOR HUMANS (21). THIS
CLASSIFICATION IS BASED ON THE FINDINGS OF LAB ANIMAL STUDIES THAT
WERE CONSIDERED SUFFICIENT AND DATA FROM EPIDEMIOLOGICAL STUDIES
THAT WERE CONSIDERED LIMITED FOR CARCINOGENICITY. (EFTS OF
OVEREXPOSURE)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE QUARTZ: IARC
MONOGRAPHS, VOL 68, 1997:GROUP 1. NTP 8TH ANNUAL REPORT ON
CARCINOGENS, 1998:REASONABLY ANTICIPATED TO BE HUMAN CARCINOGEN.
Effects of Overexposure:HLTH HAZS: CRYSTALLINE SILICA IS ALSO A KNOWN
CAUSE OF SILICOSIS, A NONCANCEROUS LUNG DISEASE. NTP HAS CLASSIFIED
CRYSTALLINE SILIA A REASONABLY ANTICIPATED HUMAN CARCINOGEN.
Medical Cond Aggravated by Exposure:EYE, SKIN, RESPIRATORY DISORDERS.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE AND SUPPORT
CONTINUED BREATHING. GET EMERGENCY MEDICAL ATTENTION. HAVE TRAINED
PERSON GIVE OXYGEN IF NECESSARY. GET MEDICAL HELP FOR ANY BREATHING
DIFFICULTY. SKIN: FLUSH FROM SKIN WITH WATER. THEN WASH THOROUGHLY
WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. EYES: FLUSH
IMMEDIATELY WITH LARGE AMOUNTS OF WATER, ESPECIALLY UNDER LIDS FOR
AT LEAST 15 MIN UTES. IF IRRITATION OR OTHER EFFECTS PERSIST,
OBTAIN MEDICAL TREATMENT. INGESTION: IF SWALLOWED, OBTAIN MEDICAL
TREATMENT IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:NOT AVAILABLE.
Autoignition Temp:Autoignition Temp Text:NOT AV
Lower Limits:NOT AVAIL
Upper Limits:NOT AVAIL.
Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE,
WATER SPRAY OR ALCOHOL-RESISTENT FOAM.
Fire Fighting Procedures:WEAR APPROPRIATE PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND EYES. WEAR A SELF-CONTAINED BREATHING
APPARATUS (SCBA) (NIOSH APPROVED - ) TO PREVENT CONTACT WITH
THERMAL DECOMPOSITION PRODU CTS. USE WATER WITH CAUTION AND IN
FLOODING AMOUNTS. CONTACT WITH MOISTURE OR WATER (UNUSUAL FIRE AND
EXPLOSION HAZARD)
Unusual Fire/Explosion Hazard:N/P. FIRE FIGHTING PROCEDURE (CONT):
MAY GENERATE SUFFICIENT HEAT TO IGNITE NEARBY COMBUSTIBLE
MATERIALS.
================== Accidental Release Measures ==================
Spill Release Procedures:COMPLY WITH ALL APPLICABLE HEALTH AND
ENVIRONMENTAL REGULATIONS. ELIMINATE ALL SOURCES OF IGNITION.
VENTILATE AREA. EVACUATE ALL UNNECESSARY PERSONNEL. SMALL SPILLS -
USE ABSORBENT TO PICK UP RESIDUE AND DISPOSE OF PROPERLY.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE BELOW 100F. KEEP FROM FREEZING.
Other Precautions:USE ONLY W/ADEQ VENT. DO NOT TAKE INTERNALLY. KEEP
OUT OF REACH OF CHILDREN. AVOID CONTACT W/SKIN & EYES, & BRTHG OF
VAPORS. WASH HANDS THOROUGHLY AFTER HNDLG, ESPECIALLY BEFORE EATING
OR SMOKING. KEE P CNTNRS TIGHTLY CLSD & UPRIGHT WHEN NOT IN USE.
AVOID CNDTNS WHICH RSLT IN FORMATION OF INHALABLE ( SUPDAT)
============= Exposure Controls/Personal Protection =============
Supplemental Safety and Health
OTHER PRECS: PARTICLES SUCH AS SPRAYING OR ABRADING (SANDING) PAINTED
SURFACES. IF SUCH CNDTNS CANNOT BE AVOIDED, USE APPROP NIOSH APPRVD
RESP PROT AS DIRECTED UNDER SPECIAL PROTECTION INFO.
================== Physical/Chemical Properties ==================
Boiling Pt:=1390.C, 2534.F
B.P. Text:@ 760.00 MM HG.
Melt/Freeze Pt:=318.C, 604.4F
Decomp Temp:Decomp Text:NOT AVAILABLE.
Vapor Pres:100 MM HG.
Vapor Density:NOT AVAIL.
Spec Gravity:2.1300 G/CM3.
pH:NOT AVAILABLE.
Viscosity:NOT AVAILABLE.
Evaporation Rate & Reference:NOT AVAILABLE.
Solubility in Water:1 G / 0.9 ML WATER.
Appearance and Odor:WHITE SOLID. ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
GENERATES LARGE AMOUNTS OF HEAT WHEN IN CONTACT WITH WATER AND MAY
STEAM AND SPLATTER. REACTS WITH MINERAL ACIDS TO FORM CORRESPONDING
SALTS; REACTS WITH WEAK ACID GASES LIKE HYDROGEN SULFIDE, SULFUR
DIOXIDE, AND CARBON DIO
Stability Condition to Avoid:INCOMPATIBLE MATERIALS, MOISTURE, CONTACT
WITH WATER, ACIDS.
Hazardous Decomposition Products:TOXIC FUMES OF SODIUM OXIDE, SODIUM
PEROXIDE FUMES.
Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED.
=================== Toxicological Information ===================
Toxicological Information:LD50/LC50: NOT AVAILABLE. CARCINOGENICITY:
NOT LISTED BY ACGIH, IARC, NIOSH, NTP, OR OSHA. EPIDEMIOLOGY: NO
INFORMATION REPORTED. TERATOGENICITY: NO INFORMATION REPORTED.
REPRODUCTIVE EFFECTS: NO INFO RMATION REPORTED. NEUROTOXICITY: NO
INFORMATION REPORTED. MUTAGENICITY: MUTATION DATA REPORTED. OTHER
STUDIES: NO INFORMATION REPORTED. OTHER INFO (CONT): CANADA'S
INGREDIENT DISCLOSURE LIST. EXP OSURE LIMITS: CAS # 1310-73-2: OEL
- AUSTRALIA: TWA 2 MG/M3. OEL - BELGIUM: STEL 2 MG/M3. OEL DENMARK:
TWA 2 MG/M3. OEL - FINLAND: TWA 2 MG/M3. OEL - FRANCE: TWA 2 MG/M3.
OEL - GERMANY: TWA 2 MG/M3. O EL - JAPAN: STEL (ECOLOGICAL INFO)
===================== Ecological Information =====================
Ecological:ECOTOXICITY: TLM, MOSQUITO FISH, 125 PPM/96HR. (FRESH
WATER); TLM, BLUEGILL, 99 MG/48HR. (TAP WATER). ENVIRONMENTAL
FATE: THIS CHEMICAL IS NOT MOBILE IN SOLID FORM, ALTHOUGH IT
ABSORBS MOISTURE VERY EASILY. ONCE LIQUID, SODIUM HYDROXIDE
LEACHES RAPIDLY INTO THE SOIL, POSSIBLY CONTAMINATING WATER
SOURCES. PHYSICAL/CHEMICAL: NO INFORMATION FOUND. OTHER: NO
INFORMATION FOUND. TOX INFO (CONT): 2 MG/M3. OEL - THE
NETHERLANDS: TWA 2 MG/M3. OEL - THE PHILLIPINES: TWA 2 MG/M3. OEL -
SWEDEN: TWA 2 MG/M3. OEL - SWITZERLAND: TWA 2 MG/M3, STEL 4 MG/M3.
OEL - THAILAND: TWA 2 MG/M3. OEL - TURKEY: TWA 2 MG/M3. OEL -
UNITED (TRANSPORT INFO)
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS.
=================== MSDS Transport Information ===================
Transport Information:US DOT: SHIPPING NAME: SODIUM HYDROXIDE, SOLID.
HAZARD CLASS: 8. UN NUMBER: UN1823. PACKING GROUP: II. IMO:
SHIPPING NAME: SODIUM HYDROXIDE, SOLID. HAZARD CLASS: 8. UN NUMBER:
1823. PACKING GROUP: 2 . IATA: SHIPPING NAME: SODIUM HYDROXIDE,
SOLID. HAZARD CLASS: 8. UN NUMBER: 1823. PACKING CLASS: 2.
RID/ADR: SHIPPING NAME: SODIUM HYDROXIDE, SOLID. DANGEROUS GOODS
CODE: 8 (41B). UN NUMBER: 1823. CANADIAN TDG: SHIPPING NAME:
SODIUM HYDROXIDE. HAZARD CLASS: 8 (9.2). UN NUMBER: UN1823.
ECOLOGICAL INFO (CONT): KINGDOM: TWA 2 MG/M3; STEL 2 MG/M3. OEL IN
BULGARIA, COLOMBIA CHECK ACGIH TLV. C ONTACT NEHC FOR ADDITIONAL
INFO
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302 (RQ): CAS # 1310-73-2: FINAL RQ=
1000 POUNDS (454 KG). SECTION 302 (TPQ): NONE OF THE CHEMICALS IN
THIS PRODUCT HAVE A TPQ. SARA CODES: CAS # 1310-73-2: ACUTE,
REACTIVE. SECTION 313: NO CHEMICALS ARE REPORTABLE UNDER
SECTION313. FEDERAL REGULATORY (CONT): CAS # 1310-73-2 IS
LISTED AS A HAZARDOUS SUBSTANCE UNDER THE CWA. NONE OF THE
CHEMICALS IN THIS PRODUCT ARE LISTED AS PRIORI TY POLLUTANTS UNDER
THE CWA. NONE OF THE CHEMICALS IN THIS PRODUCT ARE LISTED AS TOXIC
POLLUTANTS UNDER THE CWA. OSHA: NONE OF THE CHEMICALS IN THIS
PRODUCT ARE CONSIDERED HIGHLY HAZARDOUS BY OSHA.
Federal Regulatory Information:TSCA: CAS# 1310-73-2 IS LISTED ON THE
TSCA INVENTORY. HEALTH AND SAFETY REPORTING LIST: NONE OF THE
CHEMICALS ARE ON THE HEALTH & SAFETY REPORTING LIST. CHEMICAL TEST
RULES: NONE OF THE CHEMICALS IN THIS PRODUCT ARE UNDER A CHEMICAL
TEST RULE. SECTION 12B: NONE OF THE CHEMICALS ARE LISTED UNDER
TSCA SECTION 12B. TSCA SIGNIFICANT NEW USE RULE: NONE OF THE
CHEMICALS IN THIS MATERIAL HAVE A SNUR UNDER TSCA. CLEAN AIR ACT:
THIS MATERIAL DOES NOT CONTAIN ANY HAZARDOUS AIR POLLUTANTS. THIS
MATERI AL DOES NOT CONTAIN ANY CLASS 1 OZONE DEPLETORS. THIS
MATERIAL DOES NOT CONTAIN ANY CLASS 2 OZONE DEPLETORS. CLEAN WATER
ACT: (SARA III)
State Regulatory Information:SODIUM HYDROXIDE CAN BE FOUND ON THE
FOLLOWING STATE RIGHT TO KNOW LISTS: CALIFORNIA, NEW JERSEY,
FLORIDA, PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. CALIFORNIA NO
SIGNIFICANT RISK LEVEL: NONE OF THE CHE MICALS IN THIS PRODUCT ARE
LISTED. EUROPEAN / INTERNATIONAL REGULATIONS: EUROPEAN LABELING
IN ACCORDANCE WITH EC DIRECTIVES: HAZARD SYMBOLS: C. RISK PHRASES:
R 35 CAUSES SEVERE BURNS. SAFETY PHRASE S: S 26 IN CASE OF CONTACT
WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL
ADVICE ; S 37/39 WEAR SUITABLE GLOVES AND EYE / FACE PROTECTION; S
45 IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE
(OTHER INFO)
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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