===================== Product Identification =====================
MSDS NAME:1001122 ACE WHT STRIPING PAINT, W2553520
NIIN:00N091782
Status Code:A
MSDS Number: CJPQC
=== Responsible Party ===
Company:SHERWIN-WILLIAMS
Address:31500 SOLON ROAD
City:SOLON
State:OH
ZIP:44139
Country:US
Info Phone Num:800-247-3270
Emergency Phone Num:216-292-7400
CAGE:09800
=== Contractor Identification ===
Company:SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC.
Address:26300 FARGO AVENUE
Box:City:BEDFORD HEIGHTS
State:OH
ZIP:44146
Country:US
Phone:216-292-7400 OR 216-595-8634
CAGE:09800
============= Composition/Information on Ingredients =============
Name:PROPANE. VP: 760.
CAS:74-98-6
RTECS #:TX2275000
= Wt:9.
OSHA PEL:1800 MG/M3;1000 PPM
Name:2-METHYLPROPANE. VP: 760.
CAS:75-28-5
RTECS #:TI4300000
= Wt:11.
Name:HYDROTREATED HEAVY NAPHTHA (PETROLEUM); (VM&P NAPHTHA)
VP:12.
CAS:8032-32-4
= Wt:3.
OSHA PEL:300 PPM
OSHA STEL:400 PPM
ACGIH TLV:1370 MG/M3;300 PPM
Name:XYLENE. VP:5.9.
CAS:1330-20-7
RTECS #:ZE2100000
= Wt:15.
OSHA PEL:100 PPM
OSHA STEL:150 PPM
ACGIH TLV:434 MG/M3;100 PPM
ACGIH STEL:651 MG/M3;150 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:METHANOL. VP:92..
CAS:67-56-1
RTECS #:PC1400000
= Wt:2.
OSHA PEL:260 MG/M3;200 PPM
OSHA STEL:250 PPM, S
ACGIH TLV:262 MG/M3;200 PPM
ACGIH STEL:328 MG/M3;250 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ACETONE. VP: 180.
CAS:67-64-1
RTECS #:AL3150000
= Wt:16.
Other REC Limits:OSHA PEL:750 PPM(M).
OSHA PEL:2400 MG/M3;1000 PPM
OSHA STEL:1000 PPM
ACGIH TLV:1780 MG/M3;750 PPM
ACGIH STEL:2380 MG/M3;1000 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:CALCIUM CARBONATE
CAS:471-34-1
RTECS #:FF9335000
= Wt:5.
Other REC Limits:PEL:5 MG/M3 RDUST(M)
OSHA PEL:15 MG/M3 (TDUST)
ACGIH TLV:10 MG/M3
Name:BARIUM SULFATE. OSHA PEL: 10 MG/M3 (TDUST); 5 MG/M3 (RDUST)
(M).
CAS:7727-43-7
RTECS #:CR0600000
= Wt:3.
OSHA PEL:15 MG/M3
ACGIH TLV:10 MG/M3
Name:TITANIUM DIOXIDE. OSHA PEL: 10 MG/M3 (TDUST); 5 MG/M3
(RDUST) (M).
CAS:13463-67-7
RTECS #:XR2275000
= Wt:17.
OSHA PEL:15 MG/M3
ACGIH TLV:10 MG/M3
Name:BARIUM
CAS:7440-39-3
RTECS #:CQ8370000
= Wt:1.
ACGIH TLV:0.5 MG/M3
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EXPOSURE MAY BE BY INHALATION AND/OR
SKIN OR EYE CONTACT, DEPENDING ON CONDITIONS OF USE. TO MINIMIZE
EXPOSURE, FOLLOW RECOMMENDATIONS FOR PROPER USE, VENTILATION AND
PERSONAL PROTECTIVE EQUIPMENT. AC UTE: IRRITATION OF EYES, SKIN AND
RESPIRATORY SYSTEM. MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME
OVEREXPOSURE MAY RESULT IN UNCONSCIOUSNESS AND POSSIBLY DEATH.
HEADACHE, DIZZINESS, NAUSEA AND LOSS O F COORDINATION ARE
INDICATIONS OF EXCESSIVE EXPOSURE TO VAPORS OR SPRAY MISTS. REDNESS
AND ITCHING OR BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN
EXPOSURE. CHRONIC: PROLONGED OVEREXPOSURE (EF TS OF OVEREXP)
Explanation of Carcinogenicity:NO INGREDIENT IN THIS PRODUCT IS AN
IARC, NTP OR OSHA LISTED CARCINOGEN.
Effects of Overexposure:HLTH HAZ: TO SOLVENT INGREDIENTS MAY CAUSE
ADVERSE EFFECTS TO THE LIVER, URINARY AND REPRODUCTIVE SYSTEMS.
RATS EXPOSED TO TITANIUM DIOXIDE DUST AT 250 MG/M3 DEVELOPED LUNG
CANCER, HOWEVER, SUCH EXPOS URE LEVELS ARE NOT ATTAINABLE IN THE
WORKPLACE. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED
OVEREXPOSURE TO SOLVENT WITH PERMANENT BRAIN AND NERVOUS SYSTEM
DAMAGE. INTENTIONAL MISUSE BY DELIBERATEL Y CONCENTRATING AND
INHALING CONTENTS CAN BE HARMFUL OR FATAL.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP
WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND
WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE.
EYES: FLUSH W ITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
GET MEDICAL ATTENTION. INGESTION: NEVER GIVE ANYTHING BY MOUTH TO
AN UNCONSCIOUS PERSON. DO NOT INDUCE VOMITING. GIVE SEVERAL GLASSES
OF WATER. SEEK MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:<-17.8C, 0.F
PROPELLANT
Lower Limits:0.9%
Upper Limits:36.5%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG
NOZZLES ARE PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS
TO PREVENT PRESS URE BUILD-UP & POSSIBLE AUTOIGNITION OR EXPLOSION
WHEN EXPOSED TO EXTREME HEAT.
Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT, ELEC EQUIP, SPKS &
OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT.
APPLICATION TO HOT SURFS REQS SPECIAL PRECS. DURING EMER CNDTNS
OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED
APPARENT. OBTAIN MED ATTN. HMIS CODES: HLTH - 3; FLAMMABILITY - 4;
REACTIVITY - 0.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
====================== Handling and Storage ======================
Handling and Storage Precautions:DOL STORAGE CATEGORY: 1A. USE ONLY
W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST. AVOID CONT W/SKIN &
EYES. CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING PROCS.
CONTENTS UNDER PRESS. DO NOT PUNCTURE, INCIN/EXPOSE TO TEMP >120F.
DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:KEEP AWAY FROM HEAT, SPKS & OPEN FLAME. VAPS WILL
ACCUM READILY & MAY IGNITE EXPLOSIVELY. DURING USE & UNTIL ALL VAPS
ARE GONE: KEEP AREA VENTED; DO NOT SMOKE; EXTING ALL FLAMES, PILOT
LIGHTS & HEATER S; TURN OFF STOVES, ELEC TOOLS & APPLIANCES & ANY
OTHER SOURCES OF IGNIT. HEAT FROM SUNLIGHT, RADIAT ORS,
STOVES,(SUPDAT)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENTILATION, WEAR A PROPERLY FITTED NIOSH
APPROVED ORGANIC VAPOR/PARTICULATE RESPIRATOR FOR PROTECTION
AGAINST INGREDIENTS. WHEN SA NDING OR ABRADING DRIED FILM, WEAR A
NIOSH APPROVED DUST/MIST RESPIRATOR FOR DUST WHICH MAY BE GENERATED
FROM THIS PRODUCT, UNDERLYING PAINT, OR THE ABRASIVE.
Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF
EXPOS TO INGS IS MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA
STD 1910.94, 1910.107, 1910.108.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
OTHER PREC:HOT WATER & OTHER HEAT SOURCES COULD CAUSE CNTNR TO BURST.
ADDN OF REDUCERS/OTHER ADDITIVES TO THIS PROD MAY SUBSTANTIALLY
ALTER COMPOSITION & HAZS OF PROD. THIS COATING MAY CONTAIN MATLS C
LASSIFIED AS NUISANCE PARTICULATES WHICH MAY BE PRESENT AT HAZ
LEVELS ONLY DURING SANDING/ABRADING OF (OTHER INFO)
================== Physical/Chemical Properties ==================
Boiling Pt:<162.8C, 325.F
B.P. Text:<0-325F
Vapor Pres:SEE INGREDIENTS
Vapor Density:HVR/AIR
Spec Gravity:0.95
Evaporation Rate & Reference:FASTER THAN ETHER
Percent Volatiles by Volume:77
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:SKIN IRRITATION: NO INFORMATION IS AVAILABLE.
EYE IRRITATION: NO INFORMATION IS AVAILABLE. ACUTE TOXICITY (LD50):
LD50: (ORAL, RAT) 6.8 G/KG (ACETONE: DECOMPOSED PRODUCT). ACUTE
TOXICITY (LC50): LC50: (INHALATION/RAT) 50.1 G/M3/8HR (ACETONE:
DECOMPOSED PRODUCT). CHRONIC TOXICITY: NO INFORMATION IS AVAILABLE.
CARCINOGENICITY: NTP: NOT LISTED. IARC: NOT LISTED. OSHA REGULATED:
NOT LISTED. OTHER INFO RMATION: NONE.
===================== Ecological Information =====================
Ecological:BIODEGRADATION: NOT APPLICABLE. BIOACCUMULATION: NO
INFORMATION IS AVAILABLE. AQUATIC TOXICITY: NO INFORMATION IS
AVAILABLE. OTHER INFORMATION: NONE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS
DEFINED UNDER THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) 40
CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE
APPLICABLE EPA HAZARDOUS WAST E NUMBERS. DO NOT INCINERATE.
DEPRESSURIZE CONTAINER. DISPOSE OF I/A/W FEDERAL, STATE & LOCAL
REGULA TIONS REGARDING POLLUTION.
=================== MSDS Transport Information ===================
Transport Information:UN NO: NONE. (THIS PRODUCT MAY TAKE FIRE BY
LITTLE EVOLVED FLAMMABLE VAPOR WHEN THE CONTAINER IS OPENED AND THE
IGNITION SOURCES ARE BROUGHT CLOSE TO THIS PRODUCT. BUT IT DOES NOT
CONTINUE BURNING AND CONTRIBUTE TO FIRE.) IMO CLASSIFICATION AND
CLASS: NONE. PACKAGING GROUP: NONE. PROPER SHIPPING NAME: NONE.
TECHNICAL SHIPPING NAME: NONE. MARINE POLLUTANT: NONE. HAZARD
SUBSTANCE(S) NAME/CAS NO, CON TENTS AND RQ: NOT APPLICABLE.
===================== Regulatory Information =====================
SARA Title III Information:SARA 313 (40 CFR 372.65C) SUPPLIER
NOTIFICATION: CAS NO: 1330-20-7, CHEMICAL/COMPOUND: XYLENE, % BY
WT: 15; CAS NO: 67-56-1, CHEMICAL/COMPOUND: METHANOL, % BY WT: 2;
CAS NO: 67-64-1, CHEMICAL/COMPOUND : ACETONE, % BY WT: 15;
CHEMICAL/COMPOUND: BARIUM, % ELEMENT: 1.
State Regulatory Information:
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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