===================== Product Identification =====================
MSDS NAME:CITRACONIC ANHYDRIDE, 27430
NIIN:00N092038
Status Code:A
MSDS Number: CJQFG
=== Responsible Party ===
Company:FLUKA CHEMICAL CORP
Address:1001 W ST PAUL
City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Info Phone Num:414-273-3850
Emergency Phone Num:414-273-3850
CAGE:63181
=== Contractor Identification ===
Company:FLUKA CHEMICAL CORP
Address:1001 WEST ST PAUL
Box:City:MILWAUKEE
State:WI
ZIP:53233
Country:US
Phone:414-273-3850
CAGE:63181
============= Composition/Information on Ingredients =============
Name:CITRACONIC ANHYDRIDE
CAS:616-02-4
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE TOXICOLOGICAL INFORMATION.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TOXIC. ACUTE: HARMFUL IF SWALLOWED,
INHALED, OR ABSORBED THROUGH SKIN. VAPOR OR MIST IS IRRITATING TO
THE EYES, MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. IRRITATING
TO SKIN. SYMPTOMS OF EXPOSURE M AY INCLUDE BURNING SENSATION,
COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE,
NAUSEA AND VOMITING.
Effects of Overexposure:SEE HEALTH HAZARDS.
======================= First Aid Measures =======================
Eyes: RINSE IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES. SEEK MEDICAL ADVICE. ASSURE ADEQUATE FLUSHING OF THE EYES
BY SEPARATING THE EYELIDS WITH FINGERS. SKIN: IMMEDIATELY WASH SKIN
WITH SOAP AND COPIOUS AMOUNTS OF WATER. INHALATION: REMOVE TO
FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. INGESTION: IF SWALLOWED, WASH
OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A
PHYSICIAN. WASH CONTAMINATED CLOTHING BEFORE REUSE. IN CASE OF
ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIATELY
(SHOW THE LABEL WHERE POSSIBL E).
===================== Fire Fighting Measures =====================
Flash Point:=101.C, 213.8F
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE
FOAM. WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR NIOSH APPROVED RESPIRATOR, CHEMICAL
SAFETY GOGGLES, RUBBER BOOTS AND HEAVY RUBBER GLOVES. COVER WITH
DRY LIME OR SODA ASH, PICK UP, KEEP IN A CLOSED CONTAINER AND HOLD
FOR WASTE DISPOSAL. VENTILA TE AREA AND WASH SPILL SITE AFTER
MATERIAL PICKUP IS COMPLETE.
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID INHALATION. DO NOT GET IN EYES,
ON SKIN, ON CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. READILY
ABSORBED THROUGH SKIN. IRRITANT. TOXIC. KEEP TIGHTLY CLOSED.
MOISTURE-SENSITIVE. STORE IN A CO OL DRY PLACE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . WEAR SUITABLE PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:>6.C, 42.8F
M.P/F.P Text:6C - 9C
Vapor Density:4
Spec Gravity:1.245
Appearance and Odor:COLORLESS TO FAINT YELLOW LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
BASES, OXIDIZING AGENTS, REDUCING AGENTS.
Hazardous Decomposition Products:TOXIC FUMES OF CARBON MONOXIDE, CARBON
DIOXIDE.
=================== Toxicological Information ===================
Toxicological Information:RTECS #: GE6825000, CITRACONIC ANHYDRIDE.
IRRITATION DATA: SKIN-RABBIT 10 MG/24H OPEN - JIHTAB 26, 269, 1944.
TOXICITY DATA: ORAL-RAT LD50: 2600 MG/KG - JIHTAB 26, 269, 1944.
SKIN-RABBIT LD50: 218 MG/ KG - SHELL. SKIN-GUINEA PIG LD50: 1 ML/KG
- JIHTAB 26, 269, 1944. ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF
CHEMICAL SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL
ENTRY IN RTECS FOR COMPLETE INFORMATION.
===================== Ecological Information =====================
Ecological:DATA NOT YET AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:CONTACT FLUKE CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.
===================== Regulatory Information =====================
Federal Regulatory Information:EUROPEAN INFORMATION: TOXIC. R 36/37/38
- IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN. R 23/24/25 -
TOXIC BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED. S 26 -
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE. S 36/37/39 - WEAR SUITABLE
PROTECTIVE CLOTHING, GLOVES AND EYE/FACE PROTECTION. S 45 - IN CASE
OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE IMMEDIATELY
(SHOW THE LABEL WHERE POSSIBLE).
State Regulatory Information:
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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