===================== Product Identification =====================
MSDS NAME:NICKEL (II) OXIDE GREEN OR BLACK, N69 500
NIIN:00N092932
Status Code:A
MSDS Number: CJVWX
=== Responsible Party ===
Company:FISHER SCIENTIFIC
Address:ONE REAGENT LANE
City:FAIRLAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:201-796-7100
Emergency Phone Num:201-796-7100
Resp. Party Other MSDS Num.:ACC 16380
Chemtrec Ind/Phone:(800)424-9300
CAGE:1B464
=== Contractor Identification ===
Company:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464
============= Composition/Information on Ingredients =============
Name:NICKEL(II) OXIDE EINECS/ELINCS: 215-215-7.
CAS:1313-99-1
RTECS #:QR8400000
= Wt:100.
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: CAUSES EYE IRRITATION. SKIN:
CAUSES SKIN IRRITATION. MAY CAUSE SEVERE IRRITATION AND POSSIBLE
BURNS. MAY CAUSE DERMATITIS. INGESTION: CAUSES GASTROINTESTINAL
IRRIATION WITH NAUSEA, VOMITING AND D IARRHEA. INHALATION: CAUSES
RESPIRATORY TRACT IRRITATION. MAY CAUSE ALLERGIC RESPIRATORY
REACTION. CHRONIC: REPEATED INHALATION IS ASSOCIATED WITH NASAL AND
NASOPHARYNGEAL CANCER.
Explanation of Carcinogenicity:NICKEL OXIDE: NTP 8TH ANNUAL REPORT ON
CARCINOGENS, 1998: REASONABLY ANTICIPATED TO BE HUMAN CARCINOGEN.
Effects of Overexposure:SEE HEALTH HAZARDS.
======================= First Aid Measures =======================
Eyes: FLUSH EYES W/PLENTY OF WATER FOR AT LEAST 15 MIN,
OCCASNLY LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. SKIN:GET
MED AID. FLUSH SKIN W/PLENTY OF SOAP & WATER FOR AT LEAST 15 MIN
WHILE REMOVING CONTAM CLTHG & SHOES. WASH CLTHG BEFORE REUSE.
INGEST: IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF
MILK/WATER. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON. GET MED
AID IMMED. INHAL: GET MED AID IMMED. REMOVE FROM EXPOS TO FRESH
AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG DFCLT, GIVE
OXYGEN. NOTES TO MD: TREAT SYMPTOMATICALLY & SUPPORTIVELY.
ANTIDOTE: USE OF METAL CHELATOR SHOULD BE DETERMINED ONLY BY
QUALIFIED MED PERS.
===================== Fire Fighting Measures =====================
Flash Point:NOT AVAILABLE
Lower Limits:NOT AVAIL
Upper Limits:NOT AVAIL
Extinguishing Media:SUBSTANCE IS NONCOMBUSTIBLE; USE AGENT MOST
APPROPRIATE TO EXTINGUISH SURROUNDING FIRE. IN CASE OF FIRE USE
WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE OR APPROPRIATE FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:DURING A FIRE, IRRITATING AND HIGHLY
TOXIC GASES MAY BE GENERATED BY THERMAL DECOMPOSITION OR
COMBUSTION.
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS
INDICATED IN SECTION 8, EXPOSURE CONTROLS, PERSONAL PROTECTION.
CLEAN UP SPILLS IMMEDIATELY, OBSERVING PRECAUTIONS IN THE
PROTECTIVE EQUIPMENT SECTION. SWEE P UP, THEN PLACE INTO A SUITABLE
CONTAINER FOR DISPOSAL. AVOID GENERATING DUSTY CONDITIONS. PROVIDE
VENTILATION.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A TIGHTLY CLOSED CONTAINER.
STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE
SUBSTANCES.
Other Precautions:WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE
EATING. USE WITH ADEQUATE VENTILATION. MINIMIZE DUST GENERATION AND
ACCUMULATION. AVOID CONTACT WITH SKIN AND EYES. AVOID INGESTION AND
INHALATION. WA SH CLOTHING BEFORE REUSE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR A NIOSH OR EUROPEAN STANDARD EN 149
APPROVED FULL-FACEPIECE AIRLINE RESPIRATOR IN THE POSITIVE PRESSURE
MODE WITH EMERGENCY ESCAPE PROVISION. FOLLOW THE OSHA RESPIRATOR
REGULATIONS FOUND IN 29 CF R 1910.134 OR EUROPEAN STANDARD EN 149.
ALWAYS USE A NIOSH OR EUROPEAN STANDARD EN 194 APPROVED RESPIRATOR
WHEN NECESSARY.
Ventilation:USE PROCESS ENCLOSURE, LOCAL EXHAUST VENTILATION OR OTHER
ENGINEERING CONTROLS TO CONTROL AIRBORNE LEVELS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING TO MINIMIZE
CONTACT WITH SKIN.
Supplemental Safety and Health
EXPOSURE LIMITS: NICKEL (II) OXIDE: ACGIH:NONE LISTED. NIOSH: NONE
LISTED. OSHA - FINAL PELS: NONE LISTED. OSHA VACATED PELS: NICKEL
(II) OXIDE: NO OSHA VACATED PELS ARE LISTED FOR THIS CHEMICAL. PHYS
ICAL DATA: MOLECULAR FORMULA: NIO.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:NOT AVAILABLE
Melt/Freeze Pt:=1684.C, ######F
Decomp Temp:Decomp Text:NOT AVAILABLE
Vapor Density:NOT AVAIL
Spec Gravity:4.8-6.8
pH:NOT AVAILABLE
Solubility in Water:INSOLUBLE
Appearance and Odor:GRAY TO GREEN BLACK SOLID; ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
FLUORINE, HYDROGEN SULFIDE, BARIUM OXIDE AND AIR.
Stability Condition to Avoid:INCOMPATIBLE MATERIALS, DUST GENERATION.
STABLE UNDER NORMAL TEMPERATURES AND PRESSURES.
Hazardous Decomposition Products:IRRITATING AND TOXIC GASES, NICKEL
OXIDE, NICKEL, METALLIC OXIDES.
=================== Toxicological Information ===================
Toxicological Information:LD50/LC50: NOT AVAILABLE. CARCINOGENICITY:
CAS #1313-99-1: CALIFORNIA: CARCINOGEN - INITIAL DATE 10/1/89
(LISTED AS NICKEL). NIOSH: OCCUPATIONAL CARCINOGEN (LISTED AS
NICKEL). NTP: SUSPECT CARCINOGEN. OSHA: POSSIBLE SELECT
CARCINOGEN. IARC: GROUP 2B CARCINOGEN (LISTED AS NICKEL).
EPIDEMIOLOGY: NO INFO AVAILABLE. TERATOGENICITY: NO INFO AVAILABLE.
REPRODUCTIVE EFFECTS: NO INFO AVAILABLE. NEUROTOXIC ITY: NO INFO
AVAILABLE. MUTAGENICITY: NO INFO AVAILABLE. OTHER STUDIES: NONE.
===================== Ecological Information =====================
Ecological:ECOTOXICITY: NO INFO AVAILABLE. ENVIRONMENTAL FATE: NO INFO
REPORTED. PHYSICAL/CHEMICAL: NO INFO AVAILABLE. OTHER: NONE.
--OTHER INFO: S 45 IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK
MED ADVICE I MMED (SHOW LABEL WHERE POSS). S 53 AVOID EXPOS-OBTAIN
SPEC INSTRUCTIONS BEFORE USE. WGK (WATER DANGER/PROTECTION) CAS
#1313-99-1: 3. CANADA - CAS #1313-99-1 IS LSITED ON CANADA'S
DSL/DNSL LIST. THIS P ROD HAS WHMIS CLASSIFICATION OF D2A. CAD
#1313-99-1 IS NOT LISTED ON CANADA'S INGRED DISCLOSURE LIST. EXPOS
LIMITS: CAS #1313-99-1: OEL-ARAB REPUBLIC OF EGYPT: TWA 0.1
MG(NI)/M3. OEL-AUSTRALIA: TWA 1 MG(NI)/M3. (TRANSPORT INFO)
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE AND LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONCENTRATION OF
CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOXICITY REFERENCE
LEVELS: NONE LIS TED. RCRA F-SERIES: NONE LISTED. RCRA P-SERIES:
NONE LISTED. RCRA U-SERIES: NONE LISTED.
=================== MSDS Transport Information ===================
Transport Information:US DOT, IATA, RID/ADR, IMO, CANADA TDG: NO INFO
AVAIL. --ECOLOGICAL INFO: OEL-BELGIUM: TWA 1 MG(NI)/M3 (INSOL
CMPDS). OEL-BELGIUM: TWA 1 MG(NI)/M3. OEL-CZECHOSLOVAKIA: TWA 0.05
MG(NI)/M3; STEL 0.25 MG (NI)/ME. OEL-DENMARK: TWA 0.05
MG(NI)/M3;CARCIN. OEL-DENMARK: TWA 1 MG(NI)/M3 (INSOL CMPDS).
OEL-FINLAND: TWA 0.1 MG(NI)/M3; CARCIN. OEL-FINLAND: TWA 0.1
MG(NI)/M3; SKIN, CAR (INSOL CMPDS). OEL-FRANCE : TWA 1 MG(NI)/M3.
OEL-GERMANY; CARCIN. OEL-HUNGARY: STEL 0.005 MG(NI)/M3; CAR (INSOL
CMPDS). OEL-HUNGARY: STEL 0.005 MG(NI)/M3; CARCIN. OEL-JAPAN: TWA 1
MG(NI)/M3; CARCIN. OEL-THE NETHERLANDS: TWA 0. 1 MG(NI)/M3. OEL-THE
(SARA REG INFO)
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302 (RQ): NONE OF THE CHEM IN THIS
MATL HAVE AN RQ. SECTION 302 (TPQ): NONE OF THE CHEMS IN THIS PROD
HAVE A TPQ. SARA CODES: CAS #1313-99-1: ACUTE, CHRONIC. SECTION
313: THIS MATL CONTAINS NI CKEL (II) OXIDE (LISTED AS NICKEL),
100%, (CAS #1313-99-1) WHICH IS SUBJECT TO THE REPORTING REQS OF
SECTION 313 OF SARA TITLE III & 40 CFR PART 373. --TRANSPORT INFO:
NETHERLANDS: TWA 1 MG(NI)/M3 (IN SOL CMPDS). OEL-THE PHILIPPINES:
TWA 1 MG(NI)/M3. OEL-RUSSIA: STEL 0.05 MG(NI)/M3. OEL-SWEDEN: TWA
0.1 MG/M3; CARCIN. OEL-SWEDEN: TWA 0.5 MG(NI)/M3. OEL-SWITZERLAND:
TWA 0.5 MG(NI)/M3 (INSOL CMPDS). O EL-SWITZERLAND: (STATE REG INFO)
Federal Regulatory Information:CAS #1313-99-1 IS LISTED ON TSCA
INVENTORY. NONE OF CHEMS ARE ON HLTH & SFTY REPORTING LIST. NONE OF
CHEMS IN PROD ARE UNDER CHEM TEST RULE. NONE OF CHEMS ARE LISTED
UNDER TSCA SECTION 12B. NONE OF CH EMS IN THIS MATL HAVE SNUR UNDER
TSCA. CLEAN AIR ACT:THIS MATL DOES NOT CNTN ANY HAZ AIR POLLUTANTS.
THIS MATL DOES NOT CNTN ANY CLASS 1 OZONE DEPLETORS. THIS MATL DOES
NOT CNTN ANY CLASS 2 OZONE DEPL ETORS. CLEAN WATER ACT: NONE OF
CHEMS IN THIS PROD ARE LISTED AS HAZ SUBSTANCES UNDER CWA. NONE OF
C HEMS IN PROD ARE LISTED AS PRIORITY POLLUTANTS UNDER CWA. NONE OF
CHEMS IN PROD ARE LISTED (OTHER INFO)
State Regulatory Information:CAS #1313-99-1 CAN BE FOUND ON FOLLOWING
STATE RIGHT TO KNOW LISTS: NEW JERSEY, FLORIDA, PENNSYLVANIA,
MASSACHUSETTS. CALIFORNIA NO SIGNIFICANT RISK LEVEL: NONE OF CHEMS
IN THIS PROD ARE LISTED. --SAR A REG INFO: TWA 0.5 MG(NI)/M3;
CARCIN JAN9. OEL-SWITZERLAND: TWA 0.5 MG/M3; CARCIN. OEL-THAILAND:
TWA 1 MG(NI)/M3. OEL-UNITED KINGDOM: TWA 0.5 MG(NI)/M3 (INSOL
CMPDS). OEL-UNITED KINGDOM: TWA 1 MG(NI) /M3. OEL IN BULGARIA,
COLOMBIA, JORDAN, KOREA CHECK ACGIH TLV.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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