===================== Product Identification =====================
MSDS NAME:D-(+)-GLUCOSE ANHYDROUS ACS REAGENT, G5767
NIIN:00N093195
Status Code:A
MSDS Number: CJXBK
=== Responsible Party ===
Company:SIGMA CHEMICAL CO
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Info Phone Num:314-771-5765
Emergency Phone Num:314-771-5765
CAGE:21076
=== Contractor Identification ===
Company:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:21076
============= Composition/Information on Ingredients =============
Name:D(+)-GLUCOSE
CAS:50-99-7
RTECS #:LZ6600000
= Wt:100.
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50: (ORAL,RAT) 25800 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE EFFECTS: MAY BE HARMFUL BY
INHALATION, INGESTION, OR SKIN ABSORPTION. MAY CAUSE IRRITATION.
Effects of Overexposure:SEE HEALTH HAZARDS.
======================= First Aid Measures =======================
First Aid:IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. IN CASE OF CONTACT,
IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS AMOUNTS OF WATER. IF
INHALED, REMOVE T O FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF SWALLOWED,
WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL A
PHYSICIAN. WASH CONTAMIN ATED CLOTHING BEFORE REUSE.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR
APPROPRIATE FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:CHEMICAL SAFETY GOGGLES. USE PROTECTIVE
CLOTHING, GLOVES AND MASK. SWEEP UP, PLACE IN A BAG AND HOLD FOR
WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA AND WASH SPILL
SITE AFTER MATERIAL PICKUP IS COMPLETE.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT BREATHE DUST. DO NOT GET IN
EYES, ON SKIN, ON CLOTHING. KEEP TIGHTLY CLOSED. STORE IN A COOL
DRY PLACE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH -APPROVED RESPIRATOR IN NONVENTILATED
AREAS AND/OR FOR EXPOSURE ABOVE THE ACGIH TLV.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Protective Gloves:COMPATIBLE CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
WASTE DISP METH: DOUBT ABOUT SUITABILITY OF METHOD USE LICENSED WASTE
DISP COMPANY. OBSERVE ALL FEDERAL, STATE & LOCAL ENVIRONMENTAL
REGS. TOX INFO: SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE ACTU
AL ENTRY IN RTECS FOR COMPLETE INFORMATION.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:>153.C, 307.4F
M.P/F.P Text:153 C TO 156 C
Appearance and Odor:WHITE POWDER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:TOXIC FUMES OF: CARBON MONOXIDE,
CARBON DIOXIDE.
=================== Toxicological Information ===================
Toxicological Information:SEE HEALTH HAZS. RTECS #: LZ6600000.
D-GLUCOSE. TOX DATA: ORL-RAT LD50:25800 MG/KG 85AIAL -,39,1973.
IPR-MUS LD50:18 GM/KG PSEBAA 35,98,1936. IVMUS LD50:9 GM/KG ARZNAD
18,666,1968. TARGET ORGAN DATA: MATERNAL EFTS (OTHER EFT ON
FEMALE). EFTS OF FERTILITY (POST-IMPLANTATION MORTALITY) EFTS ON
EMBRYO/FETUS (OTHER EFTS TO EMBYRO/FETUS). SPECIFIC DEVELOPMENTAL
ABNORMALITIES (CRANIOFACIAL), (HEPATOBILI ARY SYS), (UROGENITAL
SYS), (OTHER DEVELOPMENTAL ABNORMALITIES). EFTS ON NEWBORN
(BIOCHEMICAL & METABOLIC), (BEHAVIORAL). ONLY SELECTED REGISTRY OF
TOXIC EFTS OF CHEM (SUPDAT)
===================== Ecological Information =====================
Ecological:DATA NOT YET AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSOLVE IN WATER & DILUTE TO 5% SOLN. CHECK PH
& ADJUST IT TO 7 IF NECESSARY. POUR SOLN DOWN DRAIN W/RUNNING WATER
& CONTINUE TO FLUSH DRAIN SYS FOR 10 MINS, PROVIDED RULES AT PLACE
OF EMPLOYMENT/LOC AL, STATE & FEDERAL GUIDELINES ALLOW YOU TO DO
SO. IF YOU ARE UNABLE TO FLUSH SOLN DOWN DRAIN OR IN (SUPDAT)
=================== MSDS Transport Information ===================
Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.
===================== Regulatory Information =====================
Federal Regulatory Information:REVIEWS, STANDARDS, AND REVIEWS.
OEL=MAK. NOHS 1974: HZD 81836; NIS 117; TNF 16738; NOS 90; TNE
136870. NOES 1983: HAZD 81836; NIS 86; TNF 11017; NOS 102; TNE
363666; TFE 186490. EPA GENETOX PROGRAM 1 988, NEGATIVE: SPERM
MORPHOLOGY-MOUSE. EPA GENETOX PROGRAM 1988, INCONSLUSIVE: MAMMALIAN
MICRONUCLEUS. EPA TSCA SECTION 8(B) CHEMICAL INVENTORY. EPA TSCA
SECTION 8 (D) UNPLUBHISED HEATH/SAFETY STUDIES . EPA TSCA TEST
SUBMISSION (TSCATS) DATA BASE, JUNE 1998.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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