===================== Product Identification =====================
MSDS NAME:SIGMAGUARD BT AQUA GREEN BASE, 5411-S674A
NIIN:00N093323
Status Code:A
MSDS Number: CJXSX
=== Responsible Party ===
Company:SIGMA COATINGS USA BV
Address:1401 DESTREHAN AVE
City:HARVEY
State:LA
ZIP:70058-2436
Country:US
Info Phone Num:504-347-4321
Emergency Phone Num:(800)424-9300
Preparer's Name:JAY FOLSE
Chemtrec Ind/Phone:(800)424-9300
CAGE:1K005
=== Contractor Identification ===
Company:SIGMA COATINGS USA BV
Address:1401 DESTREHAN AVE
Box:City:HARVEY
State:LA
ZIP:70058-2436
Country:US
Phone:504-347-4321
CAGE:1K005
============= Composition/Information on Ingredients =============
Name:NONYLPHENOL LD50: (ORAL, RAT) 1.62 G/KG. LC50: OVER 2
MG/LITER
CAS:25154-52-3
RTECS #:SM5600000
Minumum % Wt:1.
Maxumum % Wt:10.
Name:TITANIUM DIOXIDE LD50: (SKIN, RABBITS) OVER 10,000 MG/KG
CAS:13463-67-7
RTECS #:XR2275000
Minumum % Wt:10.
Maxumum % Wt:25.
OSHA PEL:15 MG/M3
ACGIH TLV:10 MG/M3
Name:SILICA, CRYSTALLINE-QUARTZ; (CRYSTALLINE SILICA)
CAS:14808-60-7
RTECS #:VV7330000
= Wt:.35
OSHA PEL:SEE TABLE Z-3
ACGIH TLV:0.1 MG/M3
Name:CALCIUM CARBONATE
CAS:1317-65-3
RTECS #:EV9580000
Minumum % Wt:10.
Maxumum % Wt:25.
OSHA PEL:15 MG/M3
ACGIH TLV:10 MG/M3
Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (MAGNESIUM
SILICATE)
CAS:14807-96-6
RTECS #:WW2710000
Minumum % Wt:1.
Maxumum % Wt:10.
OSHA PEL:SEE TABLE Z-3
ACGIH TLV:2 MG/M3
Name:DIBUTYL PHTHALATE LD50: (ORAL, RAT) 8 G/KG
CAS:84-74-2
RTECS #:TI0875000
= Wt:10.33
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:BISPHENOL A-EPICHLOROHYDRIN EPOXY RESIN; (BPA/EPH EPOXY
RESIN) LD50: (ORAL, RAT) 5,000 MG/KG. LD50: (DERMAL, RAT) 20
ML/KG.
CAS:25068-38-6
RTECS #:CE6880000
Minumum % Wt:25.
Maxumum % Wt:50.
Name:GLYCIDYL NEODECANOATE
CAS:26761-45-5
RTECS #:QO7800000
Minumum % Wt:1.
Maxumum % Wt:10.
Name:METHYL ISOBUTYL KETONE LD50: (ORAL, RAT) 2.08 G/KG. LC50:
4,000 PPM - 4 HOURS/RAT. LEL: 1.40%
CAS:108-10-1
RTECS #:SA9275000
= Wt:1.34
OSHA PEL:410 MG/M3;100 PPM
ACGIH TLV:205 MG/M3;50 PPM
ACGIH STEL:307 MG/M3;75 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:PROD CONTAINS CRYSTALLINE SILICA (CS)
WHICH IS CONSIDERED HAZ BY INHAL. INHAL OF CS MAY CAUSE SILICOSIS,
A FIBROTIC LUNG DISEASE WHICH CAN BE PROGRESSIVE, DISABLING & WHICH
MAY LEAD TO DEATH. CS MAY C AUSE SCLERODERMA & KIDNEY DISEASE. CS
CONTAINED IN PAINTS IS TYPICALLY BELIEVED TO BE ENCAPSULATED IN
RESIN BINDER, UNLIKELY IN NORM BRUSH & SPRAY APPLICATNS TO BE AVAIL
FOR INHAL AS DUST. SANDING & B LASTING OF PAINTS CONTAINING CS MAY
CAUSE ENCAPSULATED CS TO BECOME AVAIL FOR INHAL. PRODS CONTAINING
CS SHOULD BE USED ONLY IN CONNECTION W/SAFETY PROGRAM DESIGNED TO
PROPERLY PROTECT PERS. PROD MAY CAUSE SKIN IRRIT (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ: IARC
MONOGRAPHS, VOL 68, PG 41, 1997:GROUP 1. NTP 8TH ANNUAL REPORT ON
CARCINOGENS, 1998:REASONABLY ANTICIPATED TO BE HUMAN CARCINOGEN.
Effects of Overexposure:HLTH HAZS: & DRYING/DEFATTING OR CRACKING &
DERM ON RPTD/PRLNGD EXPOS TO SKIN. PROD MAY CAUSE IRRIT TO UPPER
RESP TRACT. BASED ON PRESENCE OF METHYL ISOBUTYL KETONE, PROD MAY
BE MOD IRRIT TO EYES. EXP OS CAN CAUSE CORNEAL INJURY. EXCESS INHAL
OF VAPS CAN CAUSE NASAL & RESP IRRIT, DIZZ, WEAK, FATG, NAUS, HDCH,
POSS UNCON & EVEN ASPHY. BASED ON PRESENCE OF NONYLPHENOL, PROD IS
CORR TO EYE, SKIN, NOSE & THROAT. IN TWO YR STUDY IN RATS, INCR IN
BENIGN & MALIGNANT LUNG TUMORS OBSERVED AT 250 MG/CUBIC METER
RESPIRABLE DUST LEVEL. THIS IS 50 TIMES CURRENT OCCUP LEVEL & IS
NOT EXPECTED TO CORRELATE TO HUMANS. ALSO, SEE TOXICOLOGICAL INFO.
Medical Cond Aggravated by Exposure:SKIN DISORDERS AND ALLERGIES.
======================= First Aid Measures =======================
First Aid:EYE CONTACT: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SEEK
PHYSICIAN IMMEDIATELY. SKIN CONTACT: FLUSH WASH WITH COPIOUS
AMOUNTS OF WATER. REMOVE CONTAMINATED CLOTHING PROMPTLY. CONTACT A
PHYSICIAN IM MEDIATELY. INHALATION: REMOVE EXPOSED INDIVIDUAL TO
FRESH AIR. RESTORE BREATHING IF REQUIRED. CONTACT A PHYSICIAN
IMMEDIATELY. INGESTION: RINSE MOUTH IMMEDIATELY. GIVE EXPOSED
INDIVIDUAL 6 TO 8 OUNCES OF LIQUID. (NEVER GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS PERSON.) DO NOT INDUCE VOMITING UNLESS ADVISED BY
A PHYSICIAN. CONTACT A PHYSICIAN IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:=65.C, 149.F
Lower Limits:SEE INGREDS
Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL, FOAM, ALCOHOL
FOAM OR WATER FOG. .
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFTIVE. WATER MAY BE USED TO COOL CLSD CNTNRS
TO PVNT PRESS BUILDUP & POSS AUTOIGNIT OR EXPLO WHEN EXPOSED TO
EXTREME HEAT. IF WATE R IS USED, FOG NOZZS ARE PREF. BASED ON
PRESENCE OF METHYL ISOBUTYL KETONE THIS LIQ & VAP IS DANGEROUS
(SUPDAT)
Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE
FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS & OPEN FLAME. CLOSED
CONTAINER MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. USE SPECIAL
PRECAUTIONS TO APPLY TO HOT SURFACE S. DO NOT USE WELDING OR
CUTTING TORCH ON OR NEAR CONTAINER (EVEN EMPTY) BECAUSE LIQUID
PRODUCT MAY IGNITE EXPLOSIVELY.
================== Accidental Release Measures ==================
Spill Release Procedures:STAY UPWIND & AWAY FROM SPILL UNLESS WEARING
APPROP PROT EQUIP. STOP &/OR CONTAIN DISCHARGE IF IT MAY BE DONE
SAFELY. KEEP ALL SOURCES OF IGNIT AWAY. VENT AREA OF SPILL. USE
NON-SPARKING TOOLS FOR CLE ANUP. COVER W/INERT MATL TO REDUCE
FUMES. KEEP OUT OF DRAINS, SEWERS OR WATERWAYS. CONTACT FIRE
AUTHORITIES. NOTIFY LOCAL HEALTH & POLLUTION CONTROL AGENCIES. CALL
SPILL RESPONSE TEAMS IF LARGE SPILL.
====================== Handling and Storage ======================
Handling and Storage Precautions:PERSONNEL SHOULD AVOID INHAL OF VAPS.
PERSONAL CNTCT W/PROD SHOULD BE AVOIDED. SHOULD CNTCT BE MADE,
REMOVE SATURATED CLTHG & FLUSH AFFECTED SKIN AREAS W/WATER. CNTNRS
OF MATL MAY BE HAZARDOUS WHEN EM PTIED. SINCE EMPTIED CNTNRS RETAIN
PROD RESIDUES (VAP, LIQ &/OR SOLID), ALL HAZ PRECS (SUPDAT)
Other Precautions:NOTICE: REPORTS HAVE ASSOCIATED REPEATED AND
PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT
BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY
CONCENTRATING AND INHALI NG THE CONTENTS MAY BE HARMFUL OR FATAL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IN OUTDOOR OR OPEN AREAS USE NIOSH APPRVD
MECHANICAL FILTER RESP TO REMOVE SOLID AIRBORNE PARTICLES OF
OVERSPRAY DURING SPRAY APPLICATN. IN RESTRICTED VENT AREAS USE
NIOSH APPRVD CHEMICAL-MECHANICAL F ILTERS DESIGNED TO REMOVE
COMBINATION OF PARTICULATE & GAS & VAP. IN CONFINED AREAS USE NIOSH
APPRVD AIR LINE TYPE RESPS OR HOODS. RESP (SUPDAT)
Ventilation:USE VENT AS REQD TO CONTROL VAPOR CONCS. AVOID PRLNGD/RPTD
BRTHG OF VAPORS. IF EXPOSURE EXCEEDS TLV, USE NIOSH APPRVD RESP TO
PREVENT OVEREXPOSURE.
Protective Gloves:RESISTANT GLOVES SUCH AS NATURAL RUBBER, NEOPRENE,
BUNA N OR NITRILE.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES AND FULL LENGTH
FACESHIELD .
Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . AN APRON SHOULD BE WORN TO AVOID SKIN CONTACT.
Work Hygienic Practices:WASH HANDS THOROUGHLY BEFORE EATING AND USING
WASHROOM. AVOID CONTACT WITH EYES.
Supplemental Safety and Health
HNDLG/STOR PRECS: GIVEN IN THIS SHEET MUST BE OBSERVED. FIRE FIGHT
PROC: FIRE HAZ & MOD EXPLO HAZ WHEN EXPOS TO HEAT/FLAME. HVR/AIR
VAPS CAN FLOW ALONG SURFS TO DISTANT IGNIT SOURCES & FLASH BACK.
RES P PROT: PROT MAY ALSO BE NEC IN ANY LATER MFG OPERATIONS IN
WHICH PROD MAY BECOME AIRBORNE IN FORM OF VAP/DUST.
================== Physical/Chemical Properties ==================
Boiling Pt:>116.7C, 242.F
B.P. Text:242-237
Vapor Pres:16
Vapor Density:9.6
Spec Gravity:1.3900
Evaporation Rate & Reference:1.6400 (ETHER=1)
Appearance and Odor:THICK LIQUID; SLIGHT/NOT IRRITATING ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
THIS PRODUCT CAN REACT WITH OXIDIZING AGENTS, STRONG LEWIS ACIDS,
MINERAL ACIDS, ORGANIC BASES AND PRIMARY AND SECONDARY AMINES.
Stability Condition to Avoid:THIS PRODUCT IS STABLE BUT MAY DECOMPOSE
AT TEMPERATURES OVER 500F YIELDING CARBON MONOXIDE, ALDEHYDES,
ACIDS AND OTHER ORGANIC SUBSTANCES.
=================== Toxicological Information ===================
Toxicological Information:IARC HAS CLASSIFIED CRYSTALLINE SILICA (CS)
AS CARCINOGENIC TO HUMANS (GROUP 1). THIS CLASSIFICATION IS USED
ONLY WHEN IARC FINDS THERE IS SUFFICIENT EVIDENCE OF
CARCINOGENICITY IN HUMANS. THE NATIONA L TOXICOLOGY PROGRAM (NTP)
OF US DEPARTMENT OF HEATLH & HUMAN SERVICES LISTS CS AS "REASONABLY
ANTICIPATED " TO BE CARCINOGENIC. ALSO, SEE HEALTH HAZARDS.
===================== Ecological Information =====================
Ecological:N/P.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF PRODUCT IN ACCORDANCE WITH APPLICABLE
LOCAL, COUNTY, STATE AND FEDERAL REGULATIONS.
===================== Regulatory Information =====================
SARA Title III Information:SARA 313 INFORMATION: THIS PRODUCT CONTAINS
THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING REQUIREMENTS OF
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND
REAUTHORIZATION ACT OF 1986 AND 4 0 CFR PART 372: DIBUTYL
PHTHALATE, CAS #84-74-2, % BY WT: 10.3280. METHYL ISOBUTYL KETONE,
CAS # 108-10-1, % BY WT: 1.3390.
Federal Regulatory Information:BASED ON THE PRESENCE OF METHYL ISOBUTYL
KETONE, YOU MAY BE REQUIRED UNDER THE COMPREHENSIVE ENVIRONMENTAL
RESPONSE, COMPENSATION AND LIABILITY ACT OF 1980 (CERCLA) TO NOTIFY
THE NATIONAL RESPONSE CEN TER OF RELEASES OF QUANTITIES OF THESE
CHEMICALS EQUAL TO OR GREATER THAN THE REPORTABLE QUANTITIES (RQ)
LISTED IN 40 CFR 302.4. REFER TO 40 CFR 302.4 FOR DETAILS ON
REPORTING REQUIREMENTS.
State Regulatory Information:CALIFORNIA PROPOSITION 65 REQUIRES
MANUFACTURERS TO WARN USERS OF THE PRESENCE OF CHEMICALS WHICH MAY
CAUSE A "SIGNIFICANT RISK." BASED UPON THE POSSIBILITY OF THE
PRESENCE OF MINUTE AMOUNTS OF CONTAM INANTS IN ANY PAINT, SIGMA
COATINGS GIVES THE FOLLOWING WARNINGS: WARNING: THIS PRODUCT
CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER. WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE
STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE
HARM.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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