===================== Product Identification =====================
MSDS NAME:LENIUM ES
NIIN:00N093354
Status Code:A
MSDS Number: CJXXC
=== Responsible Party ===
Company:TECH SPRAY INC
Address:88 HUGHES STREET
Box:949
City:AMARILLO
State:TX
ZIP:79105-0949
Country:US
Info Phone Num:806-372-8523
Emergency Phone Num:(800)424-9300
Chemtrec Ind/Phone:(800)424-9300
CAGE:54700
=== Contractor Identification ===
Company:TECH SPRAY INC
Address:1001 NW 1ST
Box:949
City:AMARILLO
State:TX
ZIP:79105-0949
Country:US
Phone:806-372-8523
CAGE:54700
============= Composition/Information on Ingredients =============
Name:1-BROMOPROPANE LD50: (ORAL, RAT) 4,260 MG/KG
CAS:106-94-5
RTECS #:TX4110000
Code:F
> Wt:93.
Name:1,2-EPOXYBUTANE LD50: (ORAL, RAT) 500 MG/KG
CAS:106-88-7
RTECS #:EK3675000
< Wt:1.
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:2-METHYL-2-PROPANOL LD50: (ORAL, RAT) 3,500 MG/KG
CAS:75-65-0
RTECS #:EO1925000
< Wt:2.
OSHA PEL:300 MG/M3;100 PPM
ACGIH TLV:303 MG/M3;100 PPM
Name:DIMETHOXYMETHANE
CAS:109-87-5
RTECS #:PA8750000
= Wt:2.
OSHA PEL:3100 MG/M3;1000 PPM
ACGIH TLV:3110 MG/M3;1000 PPM
Name:2-PROPANOL
CAS:67-63-0
RTECS #:NT8050000
Minumum % Wt:5.
Maxumum % Wt:10.
OSHA PEL:980 MG/M3;400 PPM
ACGIH TLV:983 MG/M3;400 PPM
ACGIH STEL:1230 MG/M3;500 PPM
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:POTENTIAL HEALTH EFFECTS: INHALATION:
MAJOR ROUTE OF EXPOSURE. VAPOR IS HEAVIER THAN AIR AND CAN CAUSE
SUFFOCATION BY REDUCING THE AVAILABLE OXYGEN FOR BREATHING.
BREATHING HIGH CONCENTRATIONS OF VAPO R MAY CUASE LIGHT-HEADEDNESS,
GIDDINESS, SHORTNESS OF BREATH, CONFUSION AND MAY LEAD TO NARCOSIS,
CARDIAC IRREGULARITIES, OR UNCONSCIOUSNESS. INHALATION OF HIGH
CONCENTRATIONS IN A CLOSELY CONFINED AR EA MAY BE FATAL. MAY HAVE
ADVERSE EFFECTS ON LIVER, LUNG AND KIDNEY IN HIGH DOSES. EYES:
LIQUID CONTACT WILL IRRITATE EYES. SKIN: EXPECTED TO BE AN
IRRITANT, NOT CORROSIVE. REPEATED OR PROLONGED EXPOS URE (EFFECTS
OF OVEREXPOSURE)
Effects of Overexposure:HEALTH HAZARDS: CAUSES DEFATTING OF SKIN.
INGESTION: SINGLE DOSE TOXICITY IS LOW TO MODERATE. IF VOMITING
OCCURS THE LIQUID CAN BE ASPIRATED INTO LUNGS, WHICH CAN CAUSE
CHEMICAL PNEUMONIA AND SYSTEMIC EFFECTS. HUMAN PSYCHOTROPIC,
GASTROINTESTINAL AND CENTRAL NERVOUS SYSTEM EFFECTS POSSIBLE.
CHRONIC EFFECTS: NONE KNOWN.
======================= First Aid Measures =======================
First Aid:INHAL: MOVE TO FRESH AIR IN CASE OF ACCIDENTAL INHALATION OF
VAPORS. IF VICTIM HAS STOPPED BREATHING, GIVE ARTIFICIAL
RESPIRATION. CALL FOR PROMPT MEDICAL ATTN. EYE CONTACT: FLUSH EYES
WITH LARGE AMOU NTS OF WATER FOR AT LEAST 15 MINUTES OR UNTIL
IRRITATION SUBSIDES. GET MEDICAL ATTN. SKIN CONTACT: REMOVE
CONTAMINATED CLOTHING (INCLUDING SHOES) AND WASH BEFORE REUSE.
FLUSH WITH LARGE AMOUNTS OF WAT ER. USE SOAP IF AVAILABLE. IF
IRRITATION PERSISTS, SEEK MEDICAL ATTN. INGESTION: DO NOT INDUCE
VOMITING UNLESS DIRECTED BY A PHYSICIAN. IF CONSCIOUS AND ALERT,
GIVE TWO GLASSES OF WATER. SEEK MEDICAL ATTN IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:NON-FLAMMABLE
Autoignition Temp:Autoignition Temp Text:NE
Lower Limits:3%
Upper Limits:8%
Extinguishing Media:FOAM, DRY CHEMICAL, CARBON DIOXIDE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . AVOID CONTACT WITH FUMES WHICH COULD CONTAIN
HYDOBROMIDE AND HYDROBROMIDE ACID.
Unusual Fire/Explosion Hazard:AVOID CONTACT WITH HIGH ENERGY SOURCES
SUCH AS SPARKS, FLAME OR HIGH INTENSITY HEAT. IF IN AEROSOL CANS
MAY ERUPT WITH FORCE AT TEMPERATURES ABOVE 120F. HAZARDOUS
COMBUSTION PRODUCTS: HBR, BROMINE, SM OKE, FUMES AND OXIDES OF
CARBON.
================== Accidental Release Measures ==================
Spill Release Procedures:LAND SPILL: EVACUATE AREA. VENTILATE AREA WELL
AND AVOID BREATHING VAPORS. VAPOR CONCENTRATION WILL BE HIGHEST
ALONG FLOOR AND IN LOW LYING AREAS. PICK UP LIQUID ON SUITABLE
ABSORBENT AND STORE IN SEA LED CONTAINERS. SHUT OFF FIRE SOURCES.
WORKERS SHOULD WEAR PROPER EQUIPMENT TO WORK IN CLEAN UP AREA.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORAGE TEMPERATURE: AMBIENT. STORAGE
PRESSURE: ATMOSPHERIC. KEEP CONTAINER CLOSED WHEN NOT IN USE. STORE
IN COOL, WELL VENTILATED PLACE OUT OF DIRECT SUNLIGHT & AWAY FROM
INCOMPATIBLE MATERIALS (SEE STABILITY & REACTIVITY SECTION).
FOLLOW ALL MSDS & LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF CONCENTRATIONS ARE OVER THE EXPOSURE LIMIT
AND ARE KNOWN, NIOSH APPROVED AIR PURIFYING RESPIRATOR WITH ORGANIC
VAPOR CARTRIDGES MAY BE ACCEPTABLE. REFER TO CARTRIDGES FOR
ACCEPTABLE LEVELS. IF CONC ENTRATIONS ARE OVER EXPOSURE LIMIT AND
ARE UNKNOWN, USE A NIOSH APPROVED SUPPLIED AIR RESPIRATOR.
Ventilation:LOCAL EXHAUST VENTILATION ACCEPTABLE. SEE INGREDIENT
SECTION FOR COMPONENT EXPOSURE GUIDELINES.
Protective Gloves:SOLVEX, BUTY, NEOPRENE GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA .
Supplemental Safety and Health
PHYSICAL DATA: MOLECULAR WEIGHT: N/A. % SOLIDS: 0. PHYSICAL STATE:
LIQUID. OTHER INFO: USE: DEGREASER/CLEANER. PRODUCT DESCRIPTION:
STABLILIZED N-PROPYLBROMIDE AZEOTROPE.
================== Physical/Chemical Properties ==================
Boiling Pt:=68.C, 154.4F
Melt/Freeze Pt:M.P/F.P Text:NIF
Vapor Pres:139 MM HG @ 25C
Spec Gravity:1.25
Evaporation Rate & Reference:>1 (H*2O=1)
Solubility in Water:<1
Appearance and Odor:CLEAR WATER-WHITE MOBILE LIQUID WITH SLIGHT
ETHEREAL ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
REACTIVE ALKALI METALS, STRONG ACIDS AND BASES.
Stability Condition to Avoid:CONTACT WITH OPEN FLAME, HEAT.
Hazardous Decomposition Products:HYDROGEN BROMIDE, BROMIDE, CARBON
DIOXIDE AND CARBON MONOXIDE.
=================== Toxicological Information ===================
Toxicological Information:RESULTS OF COMPONENT TOXICITY TEST PERFORMED:
N-PROPYL BROMIDE - LC50/RAT = 253,000 MG/M3/0.5 HOUR. 1,2
EPOXYBUTANE - LC50/DERMAL/RABBIT = 2,100 UL/KG. DIMETHOXYMETHANE -
LC50/RAT = 15,000 PPM. ALSO, SEE INGREDIENTS. HUMAN EXPERIENCE:
INFORMATION NOT AVAILABLE.
===================== Ecological Information =====================
Ecological:FURTHER INFORMATION: INFORMATION NOT AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:RCRA 40 CFR 261 CLASSIFICATION: NONE LISTED.
FEDERAL, STATE AND LOCAL LAWS GOVERNING DISPOSAL OF MATERIALS CAN
DIFFER. ENSURE PROPER DISPOSAL COMPLIANCE WITH PROPER AUTHORITIES
BEFORE DISPOSAL.
=================== MSDS Transport Information ===================
Transport Information:US DOT INFO - PROPER SHIPPING NAME: NON-HAZARDOUS
MATERIAL. HAZARD CLASS: N/A. PACKAGING GROUP: N/A. UN NUMBER: N/A.
LIMITATIONS: N/A. IATA - PROPER SHIPPING NAME: NON-HAZARDOUS
MATERIAL. HAZARD CLASS : N/A. PACKAGING GROUP: N/A. UN NUMBER: N/A.
LIMITATIONS: NONE. WHEN SHIPPING INTERNATIONAL PLEASE CONTACT TECH
SPRAY'S SHIPPING DEPARTMENT. IMO - PROPER SHIPPING NAME:
NON-HAZARDOUS MATERIAL. CLASS: N/A. UN NUMBER: N/A. PACKING GROUP:
N/A. EMS: N/A. MFAG: N/A. MAINE POLLUTANT: N/A. CANADIAN TDG: N/A.
IMDG PAGE: N/A.
===================== Regulatory Information =====================
SARA Title III Information:SECTIONS 302, 311, 312 AND 313: SECTION 302
- EXTREMELY HAZARDOUS SUBSTANCE (40 CFR 355): NONE OF THE CHEMICALS
ARE SECTION 302 HAZARDS. SECTION 311/312 - MSDS REQUIREMENTS (40
CFR 370) - BY MFR HAZAR D EVALUATION, THIS PRODUCT IS HAZARDOUS. IT
SHOULD BE REPORTED UNDER THE FOLLOWING EPA HAZARD: IMMEDIATE
(ACUTE) HEALTH HAZARD. SECTION 313 - LIST OF TOXIC CHEMICALS (40
CFC 372): THIS PRODUCT CONTAIN S NO CHEMICALS (AT LEVELS OF 1% OR
GREATER) WHICH ARE FOUND ON THE 313 LIST OF TOXIC CHEMICALS.
Federal Regulatory Information:US FEDERAL REGULATIONS: MSDS COMPLIES
WITH OSHA'S HAZARD COMMUNICATION RULE, 29 CFR 1910.1200.
CERCLA/SUPERFUND, 40 CFR 117, 302: 1,2-EPOXYBUTANE, 106-88-7, <1%.
TOXIC SUBSTANCE CONTROL ACT (TSCA): AL L SUBSTANCES ARE TSCA
LISTED. RESOURCE CONSERVATION AND RECOVERY ACT (RCRA 40 CFR 261)
SUBPART C & D: REFER TO SECTION 11 FOR RCRA CLASSIFCATION. FEDERAL
WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15
(FORMERLY SECTION 307), 40 CFR 116 (FORMERLY SECTION 311): NO
CHEMICALS LISTED. CLEAN AIR ACT: NO INFO. INTERNATIONAL REGS:
CANADA WHMIS: HC1.
State Regulatory Information:CALIFORNIA PROPOSITION 65: NONE OF THE
CHEMICALS ARE ON THE PROPOSITION 65 LIST.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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