===================== Product Identification =====================
MSDS NAME:MORPHOLINE 40, TECHNICAL
NIIN:00-419-4298
Status Code:A
MSDS Number: CJYHG
=== Responsible Party ===
Company:PHOENIX INDUSTRIES INC
Address:11028 LEADBETTER RD UNIT 10
City:ASHLAND
State:VA
ZIP:23005
Country:US
Info Phone Num:804-264-5183
Emergency Phone Num:804-264-5183
Chemtrec Ind/Phone:(800)424-9300
CAGE:0YED2
=== Contractor Identification ===
Company:PHOENIX INDUSTRIES INC
Address:1519 CHAMBERLAYNE PARKWAY
Box:City:RICHMOND
State:VA
ZIP:23222
Country:US
Phone:804-264-5183/FAX: 264-5535
Contract Num:SP0450-00-M-D258
CAGE:0YED2
============= Composition/Information on Ingredients =============
Name:MORPHOLINE
CAS:110-91-8
RTECS #:QD6475000
> Wt:40.
OSHA PEL:70 MG/M3;20 PPM
ACGIH TLV:71 MG/M3;20 PPM
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
= Wt:60.
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL RAT LD50: 1450 MG/KG
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: EXTREMELY DESTRCUTIVE TO
THE MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. INGESTION:
CORROSIVE; MAY CAUSE BURNS OF THE MOUTH, THROAT & STOMACH, LEADING
TO DEATH. SKIN CONTACT: CORROSIVE. CAUSTIC VAPORS MAY CAUSE
IRRITATION. CONTACT MAY CAUSE SKIN BURNS & ABSORPTION. DEATH MAY
OCCUR FROM PROLONGED EXPOSURE. EYES: CORROSIVE. CAUSTIC VAPORS MAY
CAUSE IRRITATION, CORNEAL EDEMA, EYE DAMAG E.
Explanation of Carcinogenicity:MORPHOLINE IS LISTED BY IARC AS A CLASS
3 CARCINOGEN.
Effects of Overexposure:INHALED: BURNING SENSATION, COUGHING, WHEEZING,
LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA, VOMITING.
INGESTION: SORE THROAT, VOMITING, DIARRHEA. SKIN: HYPOACTIVITY,
TRMORS, LACRIMATION, SALIVA TION. EYES: REDNESS, PAIN, FOGGY
VISION, CORNEAL EDEMA.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS OR EYE PROLEMS OR IMPAIRED LIVER, KIDNEY OR RESPIRATORY
FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.
======================= First Aid Measures =======================
First Aid:IN CASE OF CONTACT, FLUSH EYES OR SKIN IMMEDIATELY WITH LOTS
OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED
CLOTHES. IF INHALED, REMOVE TO FRESH AIR AND RESTORE BREATHING. IF
SWALLOWED, DO NOT INDUCE VOMITING! GIVE LARGE QUANTITIES OF WATER.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IN ALL CASES
GET IMMEDIATE MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Extinguishing Media:NONE SPECIFIED BY RESPONSIBLE PARTY.
Fire Fighting Procedures:IN AN EVENT OF A FIRE, WEAR FULL PROTECTIVE
CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH
FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND OR OTHER POSITIVE
PRESSURE MODE.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY RESPONSIBLE PARTY.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA OF LEAK/SPILL. REMOVE ALL
SOURCES OF IGNITION. WEAR APPROPRIATE PERSONAL PROTECTIVE GEAR.
ISOLATE HAZARD AREA. KEEP UNECESSARY AND UNPROTECTED PERSONNEL FROM
ENTERING. CONTAIN & RECOVER LIQUID WHEN POSSIBLE. USE NON-SPARKING
TOOLS & EQUIPEMNT. COLLECT LIQUID IN AN APPROPRIATE CONTAINER OR
ABSORB WITH INERT MATERIAL & PLACE IN A CHEMICAL WASTE CONTAINER.
DO NOT FLUSH TO SEWER.
Neutralizing Agent:NONE SPECIFIED BY RESPONSIBLE PARTY.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY WELL-VENTILATED
LOCATION. SEPARATE FROM INCOMPATIBLES. CONTAINERS OF THIS MATERIAL
MAY BE HAZARDOUS WHEN EMPTYSINCE THEY RETAIN PRODUCT RESIDUES
(VAPORS, LIQUID); OBSERVE ALL WARN INGS & PRECAUTIONS LISTED FOR
THE PRODUCT.
Other Precautions:NONE SPECIFIED BY RESPONSIBLE PARTY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF THE EXPOSURE LIMIT IS EXCEEDED, A FULL
FACEPIECE RESPIRATOR WITH DUST/MIST FILTER MAY BE WORN UP TO 50
TIMES THE EXPOSURE LIMIT OR THE MAXIMUM USE CONCENTRATION SPECIFIED
BY THE APPROPRIATE REGULAT ORY AGENCY OR RESPIRATOR SUPPLIER,
WHICHEVER IS LOWEST. FOR EMERGENCIES/EXPOSURE LEVEL UNKNOWN, WEAR
FULL-FACEPIECE POSITIVE-PRESSURE, AIR-SUPPLIED RESPIRATOR.
Ventilation:A SYSTEM OF LOCAL AND/OR GENERAL EXHAUST IS RECOMMENDED TO
KEEP EMPLOYEE EXPOSURES BELOW THE AIRBORNE EXPOSURE LIMITS.
Protective Gloves:WEAR IMPERVIOUS PROTECTIVE GLOVES.
Eye Protection:CHEMICAL SAFETY GOGGLES AND/OR A FULL FACE SHIELD WHERE
SPLASHING IS POSSIBLE.
Other Protective Equipment:WEAR IMPERVIOUS PROTECTIVE CLOTHING,
INCLUDING BOOTS, LAB COAT, APRON OR COVERALLS, AS APPROPRIATE, TO
PREVENT SKIN CONTACT. MAINTAIN EYE WASH FOUNTAIN AND QUICK-DRENCH
FACILILTIES IN WORK AREA.
Work Hygienic Practices:NONE SPECIFIED BY RESPONSIBLE PARTY.
Supplemental Safety and Health
WARNING: AIR PURIFYING RESPIRATORS DO NOT PROTECT WORKERS IN
OXYGEN-DEFICIENT ATMOSPHERES.
================== Physical/Chemical Properties ==================
HCC:B2
Boiling Pt:=102.C, 215.6F
Melt/Freeze Pt:=-5.C, 23.F
Spec Gravity:1.0 @ 20/4 C.
pH:CA.11 FOR 25%
Solubility in Water:MISCIBLE IN WATER.
Appearance and Odor:CLEAR,COLORLESS LIQUID.CHARACTERISTIC AMINE
ODOR.ODOR DETECTABLE ABOVE 0.1PPM
================= Stability and Reactivity Data =================
CELLULOSE NITRATE, NITROMETHANE, OTHER NITRO COMPOUNDS, STRONG ACIDS,
AND OXIDIZING AGENTS. CORROSIVE TO METALS.
Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE
AND STORAGE. CONDITIONS TO AVOID: HEAT, FLAMES, IGNITIION SOURCES
AND INCOMPATIBLES.
Hazardous Decomposition Products:BURNING MAY PRODUCE CARBON MONOXIDE,
CARBON DIOXIDE, NITROGEN OXIDES.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:ORAL RAT LD50: 1450 MG/KG; INHALATION LC50:
8000 PPM/8HR; SKIN RABBIT LD50: 1220 MG/KG. INVESTIGATED AS A
TUMORIGEN, MUTAGEN. (MORPHOLINE). CANCER LISTS: MORPHOLINE: NTP-NO;
IARC CATEGORY: 3.
===================== Ecological Information =====================
Ecological:ENVIRONMENTAL FATE: WHEN RELEASED INTO THE SOIL, THIS
MATERIAL MAY BIODEGRADE TO A MODERATE EXTENT. WHEN RELEASED INTO
THE SOIL, THIS MATERIAL IS EXPECTED TO LEACH INTO GROUND WATER.
WHEN RELEASED I NTO THE SOIL, THIS MATERIAL IS EXPECTED TO QUICKLY
EVAPORATE. WHEN RELEASED INTO WATERL, THIS MATERIAL IS NOT
EXPECTED TO BIODEGRADE. WHEN RELEASED INOT WATER, THIS MATERIAL MAY
EVAPORATE TO A MODERA TE EXTENT. THE MATERIAL HAS AN
EXPERMIMENTALLY-DETERMINED BIOCONCENTRATION FACTOR (BCF) OF LESS
THAN 100. THIS MATERIAL HAS A LOG OCTANOL-WATER PARTITION
COEFFICIENT OF LESS THAN 3.0.
==================== Disposal Considerations ====================
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY OR
RECYCLING SHOULD BE HANDLED AS HAZARDOUS WASTE & SENT TO A RCRA
APPROVED INCINERATOR OR DISPOSED IN A RCRA APPROVED WASTE FACILITY.
PROCESSING, USE OR CONTAMIN ATION OF THIS PRODUCT MAY CHANGE THE
WASTE MANAGEMENT OPTIONS. DISPOSE OF CONTAINER IAW FEDERAL, STA TE
& LOCAL REQUIREMENTS.
=================== MSDS Transport Information ===================
Transport Information:DOMESTIC, LAND, US DOT: PROPER SHIPPING NAME:
CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. HAZARD CLASS: 8; UN: UN
2054; PACKING GROUP: III. ICAO PROPER SHIPPING NAME: CORROSIVE
LIQUID, BASIC, ORGANIC, N. O.S.; HAZARD CLASS: 8; UN: UN 2054;
PACKING GROUP: III.
===================== Regulatory Information =====================
SARA Title III Information:MORPHOLINE, CAS# 110-91-8: SARA 302 RQ-NO,
SARA 302 TPQ-NO; SARA 313 LIST-NO, SARA 313 CHEMICAL CATEGORY-NO.
Federal Regulatory Information:MORPHOLINE, CAS# 110-91-8: CERCLA-NO;
261.33-NO, 8(D)-NO.
State Regulatory Information:NONE SPECIFIED BY RESPONSIBLE PARTY.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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