===================== Product Identification =====================
MSDS NAME:ABCITE 1060/60; XO545/X45 YELLOW 1021/23
NIIN:00N093405
Status Code:A
MSDS Number: CJYHL
=== Responsible Party ===
Company:CONTINENTAL INDUSTRIES, INC
Address:20757 SW 105TH AVE
Box:927
City:TUALATIN
State:OR
ZIP:97062
Country:US
Info Phone Num:503-692-3400
Emergency Phone Num:503-692-3400
Preparer's Name:J. F. BEHRENS
CAGE:TO414
=== Contractor Identification ===
Company:CONTINENTAL INDUSTRIES, INC
Address:20757 SW 105TH AVE
Box:927
City:TUALATIN
State:OR
ZIP:97062
Country:US
Phone:503-692-3400
CAGE:TO414
Company:NAVY ENVIRONMENTAL HEALTH CENTER
Address:2510 WALMER AVENUE
Box:City:NORFOLK
State:VA
ZIP:23513-2617
Country:US
Phone:804-444-4657, DSN 564-4657 X 272
CAGE:SO010
============= Composition/Information on Ingredients =============
Name:ETHYLENE COPOLYMER, PARTIAL ZINC SALT
> Wt:85.
Other REC Limits:N/K
OSHA PEL:15 MG/M3
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
Name:ZINC; (ZINC COMPOUNDS)
CAS:7440-66-6
RTECS #:ZG8600000
< Wt:5.
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:CADMIUM SULFIDE
CAS:1306-23-6
RTECS #:EV3150000
Minumum % Wt:1.6
Maxumum % Wt:2.
Other REC Limits:N/K
OSHA PEL:200 UG/M3
OSHA STEL:N/K
ACGIH TLV:10 UG/M3
ACGIH STEL:N/K
Name:BARIUM SULFATE
CAS:7727-43-7
RTECS #:CR0600000
Minumum % Wt:0.
Maxumum % Wt:.6
Other REC Limits:N/K
OSHA PEL:15 MG/M3
OSHA STEL:N/K
ACGIH TLV:10 MG/M3
ACGIH STEL:N/K
Name:ZINC SULFIDE (PNOC)
CAS:1314-98-3
RTECS #:ZH5400000
Minumum % Wt:0.
Maxumum % Wt:.4
Other REC Limits:N/K
OSHA PEL:15 MG/M3
OSHA STEL:N/K
ACGIH TLV:10 MG/M3
ACGIH STEL:N/K
Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
< Wt:12.
Other REC Limits:N/K
OSHA PEL:15 MG/M3
OSHA STEL:N/K
ACGIH TLV:10 MG/M3
ACGIH STEL:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT): > 10,000 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:NO INFO AVAIL FOR THIS ABCITE
RESIN/FOR THE ETHYLENE COPOLYMER PARTIAL METAL SALT. BASED ON ITS
SIMILARITY TO OTHER POLYMERS, THIS ABCITE RESIN IS PREDICTED TO
HAVE LOW TOXICITY. INHAL: EXCESS INHAL O F DUST MAY CAUSE ACUTE
PHYSICAL IRRIT OF RESP TRACT MUCOSAL MEMBS. AT PROCESSING TEMPS,
ESP > 300C (> 572F), FUMES WHICH ARE IRRITATING TO EYES, NOSE &
THROAT MAY BE RELEASED DUE TO POLYMER DEGRADATIO N & STABILIZER
VOLATILIZATION. EXPOS MAY RSLT IN REDNESS, ITCH, & TEARING OF EYES,
& SORENESS IN NOSE & THROAT TOGETHER W/COUGHING. EYES: PHYSICAL
IRRIT MAY RSLT FROM CONT W/DUST. SKIN: DUSTS MAY HAVE DRYING EFT
ON SKIN. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:CADMIUM SULFIDE: IARC MONOGRAPHS,
SUPPLEMENT, VOLUME 58, PAGE 119, 1993: GROUP 1. NTP 8TH ANNUAL
REPORT ON CARCINOGENS, 1998: REASONABLY ANTICIPATED TO BE HUMAN
CARCINOGEN. HUMAN: LUNG AND PROSTATE CA NCER, RENAL SYSTEM EFFECTS.
Effects of Overexposure:HLTH HAZ: NO UNUSUAL DERM PROBLEM IS EXPECTED
FROM ROUTINE HNDLG. MOLTEN POLYMER CONTACTING SKIN WILL CAUSE
THERMAL BURNS. INGEST: NOT A PROBABLE RTE OF EXPOS. TOXICITY IS
EXPECTED TO BE LOW. CADMIUM PIGMENT IS NOT TOX FOR ACUTE EXPOS TO
ANIMALS. CARCIN: OSHA HAS CHOSEN TO REGULATE OCCUP EXPOS TO ALL
CADMIUM CMPDS, INCL PIGMENTS, AS SINGLE CATEGORY. STD STATES THAT
SUBSTANCES CONTAINING CADMIUM AR E A CANCER HAZ & CAN CAUSE LUNG &
KIDNEY DISEASE. CADMIUM & CADMIUM CMPDS ARE LISTED IN ANNUAL NTP
RPT AS CARCIN TO ANIMALS, BUT W/ONLY LIM EVIDENCE OF CARCIN TO
HUMANS. IARC CLASSIFIES CADMIUM & CADM IUM CMPDS AS CARCIN TO
HUMANS. (SUP DAT)
======================= First Aid Measures =======================
First Aid:INHALATION: NO SPECIFIC TREATMENT IS NECESSARY. IF EXPOSED TO
EXCESSIVE LEVELS OF DUST, REMOVE TO FRESH AIR. CONSULT A PHYSICIAN
IF NECESSARY. EYES: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES. IF IRRITATION PERSISTS, SEEK MEDICAL ATTENTION. SKIN:
WASH WITH MILD SOAP AND WATER. INGESTION: GIVE ONE OR TWO GLASSES
OF WATER TO DRINK AND THEN INDUCE VOMITING. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:WATER, FOAM, DRY CHEMICAL, CO*2.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT . KEEP PERSONNEL REMOVED
AND UPWIND OF FIRE.
Unusual Fire/Explosion Hazard:SOLID POLYMER CAN BE COMBUSTED ONLY
W/DFCLTY. HAZ GASES/VAPS PRDCED IN FIRE: CARBON MONOXIDE, HAZ
OXIDATION PRODS, INCL ORG ACIDS, ALDEHYDES, ALCOHOLS & ZINC OXIDES.
IF HEATED TO TEMPS > 700C IN AIR, CADMIUM PIGMENT WILL DECOMP TO
FORM FUMES OF CADMIUM OXIDE & ZINC OXIDE, AS WELL AS SULFUR DIOXIDE
& SELENIUM DIOXIDE.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP, OR USE DRY VACUUM OR WET PROCEDURES.
AVOID GENERATING DUST DURING CLEANUP. RECOVER UNDAMAGED AND
MINIMALLY CONTAMINATED MATERIAL FOR REUSE AND RECLAMATION. MINIMIZE
RUN-OFF INTO STORM SEWERS AN D DITCHES WHICH LEAD TO NATURAL
WATERWAYS.
====================== Handling and Storage ======================
Handling and Storage Precautions:SEE FIRST AID AND PERSONAL PROTECTION
SECTIONS. MINIMIZE DUST GENERATION AND ACCUMULATION. AVOID
BREATHING DUST. WASH HANDS BEFORE EATING AND SMOKING. KEEP AWAY
FROM FOOD OR DRINKING WATER. KEEP CONTA INER CLOSED TO PREVENT
CONTAMINATION. STORE IN A COOL, DRY PLACE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED RESPIRATORS WITH HEPA FILTER.
Ventilation:USE PROCESS ENCLOSURES AND LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE DUST LEVELS BELOW THE RECOMMENDED EXPOSURE LIMITS.
Protective Gloves:GLOVES MAY BE USED TO PROT SKIN FROM DRYING EFT. WEAR
IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER .
OSHA CADMIUM STD REQUIRES USE OF APPROP PROT WORK CLTHG & EQUIP
WHEN LEVEL OF AIRBORNE CADMIUM EXCEEDS PEL/WHEN EXPOS CAUSES
SKIN/EYE IRRIT.
Work Hygienic Practices:GOOD HOUSEKEEPING PROCS SHOULD BE FOLLOWED TO
PVNT DUST DURING PROCESSING. NEVER EAT, DRINK/SMOKE IN WORK AREAS.
PRACTICE GOOD PERS HYGIENE AFTER USING THIS MATL, ESP BEFORE
EATING, (ECOLOGICAL INFO)
Supplemental Safety and Health
EFTS OF OVEREXP: THIS INFO IS BASED ON TEST RSLTS FROM CADMIUM CMPDS
OTHER THAN PIGMENTARY FORMS. ALTHOUGH CERTAIN CADMIUM CMPDS ARE
KNOWN TO CAUSE KIDNEY DMG IN HUMANS & HAVE BEEN SHOWN TO CAUSE LUNG
CANCER IN LAB ANIMALS, NO CHRONIC HLTH EFTS HAVE BEEN SHOWN TO
RSLT FROM EXPOS TO CADMIUM PIGMENTS. (OTHER INFO)
================== Physical/Chemical Properties ==================
Solubility in Water:NEGLIGIBLE
Appearance and Odor:FINE YELLOW POWDER; MILD METHACRYLIC ACID ODOR.
Percent Volatiles by Volume:NEGLIGIBLE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE OR CAN REACT WITH OXIDIZING AGENTS. CADMIUM COMPOUNDS WILL
DECOMPOSE IN STRONG ACIDS.
Stability Condition to Avoid:STABLE AT NORMAL TEMPERATURES AND STORAGE
CONDITIONS. AVOID TEMPERATURES ABOVE 300C (> 572F). AVOID OXIDIZING
AGENTS AND STRONG ACIDS.
Hazardous Decomposition Products:IN ACID: HYDROGEN SULFIDE; HYDROGEN
SELENIDE; WATER SOL CADMIUM CMPDS. IN FIRE: CADMIUM OXIDE; SULFUR
DIOXIDE; CARBON MONOXIDE; HYDROCARBON OXIDATION PRODS, INCL ORG
ACIDS, ALDEHYDES, (ECOLOGICAL INFO)
=================== Toxicological Information ===================
Toxicological Information:ACUTE: NO MORTALITY WAS OBSERVED IN AN INHAL
STUDY IN WHICH RATS INHALED CADMIUM PIGMENT AT 100 MG/M3 (AS CD)
FOR 2 HRS. SIMILARLY NEG MORTALITY RSLTS WERE REPORTED FOR RATS
EXPOSED CONTINUOUSLY TO AI RBORNE CONC OF PIGMENT OF 1 MG/M3 (AS
CD) FOR 1 MONTH. NO MORTALITY WAS OBSERVED DURING A 7-DAY FEEDING
STUDY IN WHICH RATS CONSUMED FEED CONTAINING UP TO 50,000 MG/KG
PIGMENT. CHRONIC: IARC CLASSIFIE S CADMIUM & CADMIUM CMPDS UNDER
GROUP I - CARCIN TO HUMANS. ALTHOUGH CADMIUM PIGMENTS ARE INCLUDED
IN THIS GENERIC GROUP, CLASSIFICATION IS BASED ON STUDIES INVOLVING
OTHER CADMIUM CMPDS. (TRANSPORT I NFO)
===================== Ecological Information =====================
Ecological:NO SPECIFIC INFORMATION IS AVAILABLE. UNDER LABORATORY
CONDITIONS, WATER SOLUBILITY OF CADMIUM PIGMENT IS SLOWLY INCREASED
WHEN SUSPENSIONS ARE EXPOSED SIMULTANEOUSLY TO BOTH AIR AND LIGHT.
THE PRACTI CAL SIGNIFICANCE OF THIS PHENOMENON IS UNKOWN. TOXICITY
OF ABCITE IS EXPECTED TO BE LOW BASED ON INSOLUBILITY IN WATER. --
HYGIENE PRACTICES: DRINKING, SMOKING, USING THE TOILET OR APPLYING
COSMETICS. -- HAZARDOUS DECOMPOSITION PRODUCTS: ALCOHOLS AND ZINC
OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:PROD IS NEITHER A LISTED HAZ WASTE NOR A CHARACT
HAZ WASTE AS DEFINED BY U.S. ENVIRON PROT AGENCY. PREF OPTIONS FOR
DISP ARE RECYCLING, INCIN W/ENERGY RECOVERY, & LANDFILL. BEFORE
DISPOSING OF PROD IN NON-HAZ WASTE LANDFILL, USER MUST DETERMINE
THAT PROD SATISFIES ALL STATE & LOC REGS REGARDING IDEN TIFICATION
& CLASSIFICATION OF PROD (OTHER INFO)
=================== MSDS Transport Information ===================
Transport Information:D.O.T. SHIPPING NAME: NOT REGULATED. D.O.T.
HAZARD CLASS: NOT REGULATED. D.O.T.. LABEL: NOT REGULATED. UN/NA
NUMBER: NOT REGULATED. -- TOXICOLOGICAL INFORMATION: TWO LONG-TERM
INHALATION STUDIES INVOL VING CADMIUM PIGMENTS HAVE BEEN REPORTED.
IN THE FIRTS, MICE & HAMSTERS WERE EXPOSED TO PIGMENT UP TO 1,000
UG/M3 (AS CD) FOR 44 WEEKS. NO CARCINOGENIC RESPONSE WAS OBSERVED.
IN THE SECOND, RATS WERE EXPOSED TO PIGMENT AT AIRBORNE
CONCENTRATIONS UP TO 2,430 UG/M3 FOR UP TO 18 MONTHS. THE AUTHORS
REPORTED A CARCINOGENIC RESPONSE FOR PIGMENTS SIMILAR TO OTHER
CADMIUM COMPOUNDS TESTED. (STATE REGS)
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302/304 - NO EXTREMELY HAZARDOUS
SUBSTANCES. SECTION 311/312 - REPORTING REQUIREMENTS ARE APPLICABLE
FOR MATERIALS OR COMPONENTS IN INGREDIENTS SECTION OF THIS MSDS.
SECTION 313 - THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS
SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF THE
EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986 AND OF
40 CFR PART 372: "CADMIUM COMPOUND S", AND "ZINC COMPOUNDS".
INFORMATION REGARDING THE CHEMICAL ABSTRACT SERVICE (CAS) NUMBER(S)
AND PERCENTAGE COMPOSITION IS PROVIDED IN THE INGREDIENTS SECTION
OF THIS MSDS.
Federal Regulatory Information:OSHA: CADMIUM PIGMENTS ARE CONSIDERED
HAZARDOUS UNDER THE CRITERIA OF THE FEDERAL OSHA HAZARD
COMMUNICATION STANDARD 29 CFR 1910.1200. OCCUPATIONAL EXPOSURE TO
CADMIUM COMPOUNDS IS REGULATED UNDER 29 CFR 1910.1027. TSCA
INVENTORY STATUS: ALL INGREDIENTS ARE LISTED. CERCLA REPORTABLE
QUANTITY: NONE. EUROPEAN EINECS STATUS: ALL INGREDIENTS ARE LISTED.
NOTE: CONSULT STATE AND LOCAL REGULATIONS WHICH MAY APPLY.
State Regulatory Information:N/P -- TRANSPORTATION INFORMATION:
SUBSEQUENT INVESTIGATIONS BY THE ORIGINAL AUTHORS AND OTHERS HAVE
DETERMINED THE AEROSOL GENERATION TECHNIQUE EXPOSED THE RATS TO
OTHER FORMS OF CADMIUM. THE ORIGINA L FINDINGS OF THE RAT STUDY CAN
BE ENTIRELY EXPLAINED BY THE INADVERTENT EXPOSURE TO NON-PIGMENTARY
FORMS OF CADMIUM.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
|