===================== Product Identification =====================
MSDS NAME:C-39 CORROSION INHIBITOR
NIIN:00N093451
Status Code:A
MSDS Number: CJYFK
=== Responsible Party ===
Company:CALGON CORP
Box:1346
City:PITTSBURGH
State:PA
ZIP:15230-1346
Country:US
Info Phone Num:412-494-8000
Emergency Phone Num:412-494-8000
Resp. Party Other MSDS Num.:0554-09-08-92
Preparer's Name:P J MALONEY
CAGE:86035
=== Contractor Identification ===
Company:CALGON CORP
Address:RT 60 AND CAMPBELLS RUN RD
Box:1346
City:PITTSBURGH
State:PA
ZIP:15230-1346
Country:US
Phone:412-494-8000
Contract Num:N00406-99-M-N196
CAGE:86035
============= Composition/Information on Ingredients =============
Name:INORGANIC SOLID - SODIUM POTASSIUM ZINC POLYPHOSPHATE GLASS
= Wt:100.
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL,RAT): 5.84 G/KG
Routes of Entry: Inhalation:NO Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: LIKE OTHER FOREIGN BODIES,
PARTICLES MAY CAUSE MECH IRRIT OF EYE. SKIN: PROD IS NOT EXPECTED
TO CAUSE SKIN IRRIT UPON CNTCT BUT, IT HAS SHARP EDGES WHICH MAY
CAUSE SKIN CUTS & ABRASIONS. PROD IS NOT EXPECTED TO BE HAZ THRU
DERMAL ABSORPTION & NO CASES OF ALLERGIC SKIN RXN HAVE BEEN
REPORTED. INGEST: THIS PROD WOULD BE CONSIDERED PRACTICALLY NON-TOX
BY INGEST. IF INGESTED IN LRG AMTS, NAUS, VO MIT, & DIARR ARE
PROBABLE. SINCE PHOSPHATES ARE SLOWLY & INCOMPLETELY ABSORBED,
SYSTEMIC REACTIONS ARE UNLIKELY WHEN THESE SALTS ARE SWALLOWED.
POLYPHOSPHATES ARE THOUGHT TO BE HYDROLYZED TO ORTHOPHOS PHATES
BEFORE (EFTS OF OVEREXP)
Effects of Overexposure:HLTH HAZ: ABSORPTION, WHICH MAY INDUCE
METABOLIC ACIDOSIS. IF APPRECIABLE AMTS OF INTACT POLYMER ARE
ABSORBED FROM ALIMENTARY TRACT, HYPOCALCEMIC TETANY (MUSCULAR
CONTRACTIONS, PAINS, TINGLING, ETC. C AUSED BY DEFICIENCY OF
CALCIUM SALTS) MAY BE DANGER DUE TO BINDING OF IONIZED CALCIUM.
INHAL: THIS PROD IS NOT EXPECTED TO PRESENT INHAL HAZ. AS W/ANY
PARTICULATE MATTER, INHAL OF DUST OF THIS PROD MA Y CAUSE UPPER
RESP IRRIT DUE TO MECH ACTION. SUBCHRONIC, CHRONIC: NO APPLIC INFO
WAS FOUND CONCERNING ANY POTNTL HLTH EFTS RSLTG FROM
SUBCHRONIC/CHRONIC EXPOS TO PROD. SOME STUDIES HAVE BEEN CONDUCTE D
ON SODIUM POLYMETAPHOSPHATE, (SUPDAT)
======================= First Aid Measures =======================
First Aid:EYE CONTACT: NOT EXPECTED TO REQUIRE FIRST AID MEASURES.
HOWEVER, FOLLOW GOOD INDUSTRIAL HYGIENE PRACTICES AND, IN CASE OF
CONTACT, FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
SKIN CONT ACT: NOT EXPECTED TO REQUIRE FIRST AID MEASURES. HOWEVER,
FOLLOW GOOD INDUSTRIAL HYGIENE PRACTICES AND, IN CASE OF CONTACT,
WASH AFFECTED SKIN AREAS THOROUGHLY WITH SOAP AND WATER. INGESTION:
NOT AN E XPECTED ROUTE OF OVEREXPOSURE. IF SWALLOWED, DO NOT INDUCE
VOMITING. CALL A PHYSICIAN. THIS PRODUCT WOULD BE EXPECTED TO BE
PRACTICALLY NON-TOXIC BY INGESTION. INGESTION: NOT AN EXPECTED
ROUTE OF OVER EXPOSURE. CALL MD IMMEDIATELY .
===================== Fire Fighting Measures =====================
Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR THE
SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . EXERCISE CAUTION WHEN FIGHTING ANY CHEMICAL FIRE.
Unusual Fire/Explosion Hazard:RUNOFF FROM FIRE CONTROL OR DILUTION
WATER MAY CAUSE POLLUTION. DECOMPOSITION PRODUCTS: DISODIUM OXIDE,
PHOSPHORUS OXIDES, AND ZINC OXIDE. NFPA RATINGS: HEALTH=0,
FLAMMABILITY=0, REACTIVITY=0, SPECIAL HAZARD=NONE. HAZARD RATING
SCALE: 0=MINIMAL, 1=SLIGHT, 2=MODERATE, 3=SERIOUS, 4=SEVERE.
================== Accidental Release Measures ==================
Spill Release Procedures:WEARING APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT, SWEEP UP MATERIAL AND PLACE INTO SUITABLE CONTAINER.
AVOID DISCHARGE TO NATURAL WATERS.
====================== Handling and Storage ======================
Handling and Storage Precautions:HANDLING: AS PART OF GOOD INDUSTRIAL
AND PERSONAL HYGIENE AND SAFETY PROCEDURE, AVOID ALL UNNECESSARY
EXPOSURE TO THE PRODUCT AND ENSURE PROMPT REMOVAL FROM EYES, SKIN
AND CLOTHING. KEEP CONTAINER CLO SED WHEN NOT IN USE. STORAGE: KEEP
WATER AND MOIST AIR OUT OF THE CONTAINER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NORMALLY NOT REQUIRED. NIOSH APPROVED RESPIRATOR
APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:NO SPECIFIC RECOMMENDATIONS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EFTS OF OVEREXP: SIMILAR PHOSPHATE GLASS PROD. FEEDING RATS DIET OF 3%
& 5% SODIUM POLYMETAPHOSPHATE RESULTED IN KIDNEY DMG. RATS FED DIET
OF 1.8% CMPD SHOWED NO OBSERVABLE DMG. SODIUM POLYMETAPHOSPHA TE
DID NOT EXHIBIT GENETIC ACTIVITY WHEN TESTED ACCORDING TO AMES
ESSAY. ORAL ADMIN OF UP TO 240 MG/KG (OTHER INFO)
================== Physical/Chemical Properties ==================
pH:7.5-8.5(5%SOLN)
Solubility in Water:MODERATE
Appearance and Odor:TRANSPARENT PLATES, 1/16 TO 1/4 INCHES THICK, WITH
NO ODOR.
Percent Volatiles by Volume:NEGLIGIBLE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS AND BASES.
Stability Condition to Avoid:KEEP WATER AND MOIST AIR OUT OF THE
CONTAINER.
Hazardous Decomposition Products:DISODIUM OXIDE, PHOSPHORUS OXIDES, AND
ZINC OXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:SEE LD50 LC50 MIXTURE.
===================== Ecological Information =====================
Ecological:ON PROD: AQUATIC TOX DATA: 48 HR LC50 (DAPHNIA MAGNA): 32
PPM. ENVIRON DATA: ALTHOUGH PRINCIPAL PROBLEM OF PHOSPHATES IN
ENVIRON IS NOT DIRECTLY RELATED TO HUMAN HLTH, THERE IS
CONSIDERABLE CONCERN AB OUT EFTS OF PHOSPHORUS FROM VARIOUS SOURCES
ON H*2O QUALITY. PHOSPHATE IS MAJOR CUASE OF EUTROPHICATION PROCESS
IN LAKES & PONDS. EXCESSIVE PHOSPHORUS I/A/W/OTHER NATURALLY
OCCURRING NUTRIENTS IS DIRE CTLY RESPONSIBLE FOR VARIOUS
UNDESIRABLE CHANGES IN SURF H*2O CHARACTERISTICS INCL INCRD AMTS OF
ALGAE & AQUATIC PLANTS, DECRD H*2O TRANSPARENCY, ALTERED H*2O
COLOR, & DECREASED DISSOVED OXYGEN CONC R EQD TO SUSTAIN LIVING
ORGANISMS.
==================== Disposal Considerations ====================
Waste Disposal Methods:RCRA STATUS: DISCARDED PRODUCT, AS SOLD, WOULD
NOT BE CONSIDERED A RCRA HAZARDOUS WASTE. DISPOSAL: DISPOSE OF IN
ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. KEEP FROM
ENTERING STREAMS OR LAK ES.
=================== MSDS Transport Information ===================
Transport Information:DOT CLASSIFICATION: CLASS/DIVISION: NOT
RESTRICTED UNLESS SHIPPED IN CONTAINER HOLDING>5000 LBS, THEN: 9.
PROPER SHIPPING NAME: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID,
N.O.S. (CONTAINS SODIUM PHOS PHATE, TRIBASIC), RQ. LABEL: CLASS 9,
PACKING GROUP: III. ID NUMBER: UN 3077.
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES:
THERE ARE NO SARA 302 EXTREMELY HAZARDOUS SUBSTANCES IN THIS
PRODUCT. SECTION 311 AND 312 HEALTH AND PHYSICAL HAZARDS:
IMMEDIATE: NO. DELAYED: NO. FIRE: NO. PRESSURE: NO. REACTIVITY:
NO. SECTION 313 TOXIC CHEMICALS: CHEMICAL NAME: ZINC COMPOUNDS. CAS
#: 7440-66-6. % BY WEIGHT 8 AS ZN.
Federal Regulatory Information:OSHA HAZARD COMMUNICATION STATUS:
NONHAZARDOUS. TSCA: THE INGREDIENTS OF THIS PRODUCT ARE LISTED ON
THE TOXIC SUBSTANCES CONTROL ACT (TSCA) CHEMICAL SUBSTANCES
INVENTORY. CERCLA REPORTABLE QUANTITY OF EPA HAZARDOUS SUBSTANCES
IN PRODUCT: CHEMICAL NAME: SODIUM ZINC POTASSIUM POLYPHOSPHATE. RQ:
5000 LB. PRODUCT RQ: 5000 LB (NOTIFY EPA OF PRODUCT SPILLS
EXCEEDING THIS AMOUNT.
State Regulatory Information:N/P. HMIS RATINGS: HEALTH =0,
FLAMMABILITY=0, REACTIVITY=0, PERSONAL PROTECTIVE EQUIPMENT=B.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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