===================== Product Identification =====================
MSDS NAME:SODIUM FLUORIDE
Status Code:A
MSDS Number: CKBRH
=== Responsible Party ===
Company:MALLINCKRODT CHEMICAL INC
Box:800
City:PARIS
State:KY
ZIP:40362
Country:US
Info Phone Num:314-539-1600
Emergency Phone Num:314-539-1600
Preparer's Name:NOT PROVIDED
CAGE:HO307
=== Contractor Identification ===
Company:MALLINCKRODT CHEMICAL INC
Box:800
City:PARIS
State:KY
ZIP:40362
Country:US
Phone:314-539-1600
CAGE:HO307
Company:WARDS NATURAL SCIENCE ESTABLISHMENT INC
Address:5100 W HENRIETTA RD
Box:92912
City:ROCHESTER
State:NY
ZIP:14692-9012
Country:US
Phone:(716) 359-2502
Contract Num:MDA414-99A-0024-0023
CAGE:63759
============= Composition/Information on Ingredients =============
Name:SODIUM FLUORIDE
CAS:7681-49-4
RTECS #:WB0350000
= Wt:100.
Code:F
OSHA PEL:2.5 MF (F)/M3 TWA
ACGIH TLV:2.5 MG (F)/M3 TWA
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:80 MG/KG, ORAL-RAT
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:INHALATION: MAY CAUSE CORROSIVE
EFFECTS TO RESPIRATORY TRACT. MAY BE ABSORBED THROUGH INHALATION OF
DUST. INGESTION: TOXIC. LETHAL DOSE MAY BE 5-10 GRAMS. MAY CAUSE
BRAIN AND KIDNEY DAMAGE. DEATH MAY OCCUR FROM RESPIRATORY
PARALYSIS. SKIN: SOLUTIONS ARE CORROSIVE. EYES: IRRITANT. MAY CAUSE
IRRITATION AND SERIOUS EYE DAMAGE. CHRONIC EXPOSURE: REPEATED
INGESTION OF SMALL AMOUNTS MAY CAUSE MOTTLING O F TEATH AND BONE
DAMAGE (OSTEOSCLEROSIS).
Explanation of Carcinogenicity:NOT PROVIDED
Effects of Overexposure:INHALATION: COUGHING, SORE THROAT & LABORED
BREATHING. SYMPTOMS PARALLEL INGESTION EXPOSURE. INGESTION:
SALIVATION, NAUSEA, VOMITING, DIARRHEA & ABDOMINAL PAIN. SYMPTOMS
OF WEAKNESS, TREMORS, SHALLOW RESPIRATION, CARDOPEDAL SPASM,
CONVULSIONS & COMA MAY FOLLOW. SKIN: IRRITATION WITH REDNESS &
PAIN. SOLUTIONS ARE CORROSIVE. EYES: IRRITATION & SERIOUS EYE
DAMAGE.
Medical Cond Aggravated by Exposure:NO INFORMATION FOUND
======================= First Aid Measures =======================
First Aid:INHALATION: MOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING DIFFICULT, GIVE OXYGEN. CALL
PHYSICIAN. INGESTION: IF PATIENT IS CONSCIOUS, IMMEDIATELY GIVE 2
TABLESPOONS O F MAGNESIUM SULFATE & GLASS OF WATER. REPEAT 3 TIMES.
FOLLOW WITH 2 TABLESPOONS OF MILK OF MAGNESIA & GLASS OF WATER.
REPEAT DOSAGES IN 10 MINUTES. NEVER GIVE ANYTHING BY MOUTH TO
UNSCIOUS PERSON. GE T MEDICAL ATTENTION IMMEDIATELY. SKIN: REMOVE
CONTAMINATED CLOTHES. WIPE EXCESS AWAY. WASH SKIN WITH PLENTY SOAP
& WATER FOR AT LEAST 15 MIN. APPLY BANDAGE SOAKED IN MILK OF
MAGNESIA. GET MEDICAL ATTN IMMEDIATELY. SEE SUPPLEMENTAL DATA.
===================== Fire Fighting Measures =====================
Flash Point:NOT FIRE HAZARD
Extinguishing Media:WATER SPRAY
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING & NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN
THE PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE
Unusual Fire/Explosion Hazard:NOT PROVIDED
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. USE PROTECTIVE CLOTHING &
RESPIRATORY PROTECTION FROM DUST. SPILLS: PICK UP & PLACE IN
SUITABLE CONTAINER. FOR RECLAMATION/DISPOSAL METHOD THAT DOES NOT
CREATE DUST.
Neutralizing Agent:NOT PROVIDED
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP IN TIGHTLY CLOSED CONTAINER,
STORED IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL
DAMAGE. SEPARATE FROM ACIDS AND OXIDIZING MATERIALS
Other Precautions:NOT RELEVANT
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF TLV IS EXCEEDED, A DUST/MIST RESPIRATOR WITH
CHEMICAL GOGGLES MAY BE WORN, IN GENERAL, UP TO 10 TIMES THE TLV.
CONSULT RESPIRATOR SUPPLIER FOR LIMITATIONS. ALTERNATIVELY, A
SUPPLIED AIR FULL FACEPL ACE RESPIRATOR OR AIRLINED HOOD MAY BE
USED.
Ventilation:LOCAL AND/OR GENERAL EXHAUST RECOMMENDED WITH LOCAL BEING
THE PREFERRED
Protective Gloves:IMPERVIOUS
Eye Protection:CHEMICAL SAFETY GOGGLES OFULL FACE SHIELD
Other Protective Equipment:IMPERVIOUS PROTECTIVE CLOTHING, BOOTS, LAB
COAT, APRON, COVERALLS AS APPROPRIATE. EYE WASH FOUNTAIN AND
QUICK-DRENCH FACILITY
Work Hygienic Practices:DO NOT WEAR CONTACT LENSES. WASH HANDS AND FACE
AFTER HANDLING.
Supplemental Safety and Health
EMER FIRST AID CON'T: EYES: WASH WITH PLENTY WATER FOR AT LEAST 15 MIN
LIFTING LOWER/UPPER EYELIDS OCCASIONALLY. FOR PAIN USE 2-3 DROPS
0.5% PONTOCAINE IN EACH EYE. CONTINUE WASHING 15 MIN LONGER. SEE
OPTHALMOLOGIST AFTER FIRST AID. GET MED ATTN IMMEDIATELY.
================== Physical/Chemical Properties ==================
HCC:T4
Boiling Pt:=1700.C, 3092.F
Melt/Freeze Pt:=992.8C, ######F
Vapor Pres:1 MM HG @ 1077 C
Vapor Density:NO DATA
Spec Gravity:2 @ 41 C (106 F)
Evaporation Rate & Reference:NO DATA FOUND
Solubility in Water:4 G/100 ML WATER @ 18 C
Appearance and Odor:WHITE CRYSTALS, ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
REACTS TO ACIDS TO FORM HYDROGEN FLUORIDE
Stability Condition to Avoid:NOT PROVIDED
Hazardous Decomposition Products:EMITS TOXIC FUMES OF FLUORIDES AND
SODIUM OXIDE WHEN HEATED TO DECOMPOSITION
=================== Toxicological Information ===================
Toxicological Information:ORAL RAT LD50: 80 MG/KG. MUTATION REFERENCES
CITED. REPRODUCTIVE EFFECTS CITED. IRRITATION: EYE - RABBIT: 20
MG/2H - SEVERE
===================== Ecological Information =====================
Ecological:NOT PROVIDED
==================== Disposal Considerations ====================
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECLAMATION MAY BE
DISPOSED IN A RCRA APPROVED HAZARDOUS WASTE FACILITY. SMALL AMOUNTS
OF RESIDUE MAY BE FLUSHED TO SEWER WITH PLENTY WATER. ENSURE
COMPLIANE WITH LOCAL, S TATE AND FEDERAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:SEE TRANSPORTATION DATA.
===================== Regulatory Information =====================
SARA Title III Information:SECTION 311/312 CATEGORIES: ACUTE, CHRONIC
HEALTH HAZARD, NOT A 313 CHEMICAL
Federal Regulatory Information:CERCLA RQ IS 1000 LBS
State Regulatory Information:NOT PROVIDED
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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