===================== Product Identification =====================
MSDS NAME:ISOPROPANOL, ANHYDROUS - FEDERAL GRADE
NIIN:01-016-3482
Status Code:A
MSDS Number: CKTNM
=== Responsible Party ===
Company:ASHLAND CHEMICAL CO
Box:2219
City:COLUMBUS
State:OH
ZIP:43216
Country:US
Info Phone Num:614-790-3333
Emergency Phone Num:800-274-5263
Resp. Party Other MSDS Num.:MSDS NO.: 999.000 1444-008.006
CAGE:81355
=== Contractor Identification ===
Company:ASHLAND INC
Address:1409 WINCHESTER AVE
Box:391
City:ASHLAND
State:KY
ZIP:41114
Country:US
Phone:800-622-6846
CAGE:81355
Company:C AND H ENTERPRISES INC
Address:222 STARKEY ST
Box:City:SAINT PAUL
State:MN
ZIP:55107
Country:US
Phone:651-227-4343/FAX: 651-227-2485
Contract Num:SP0450-00-M-SJ27
CAGE:0ZAU9
============= Composition/Information on Ingredients =============
Name:ISOPROPANOL
CAS:67-63-0
RTECS #:NT8050000
= Wt:100.
OSHA PEL:980 MG/M3;400 PPM
ACGIH TLV:983 MG/M3;400 PPM
ACGIH STEL:1230 MG/M3;500 PPM
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE PROVIDED BY MFR.
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: CAN CAUSE EYE IRRITATION. SKIN:
MAY CAUSE MILD SKIN IRRITATION. PROLONGED OR REPEATED CONTACT MAY
DRY THE SKIN. SWALLOWING: SWALLOWING SMALL AMOUNTS OF THIS MATERIAL
DURING NORMAL HANDLING IS NO T LIKELY TO CAUSE HARMFUL EFFECTS.
SWALLOWING LARGE AMOUNTS MAY BE HARMFUL. INHALATION: BREATHING OF
VAPOR OR MIST IS POSSIBLE. BREATHING SMALL AMOUNTS OF THIS MATERIAL
DURING NORMAL HANDLING IS NOT L IKELY TO CAUSE HARMFUL EFFECTS.
BREATHING LARGE AMOUNTS MAY BE HARMFUL. TARGET ORGANS: OVEREXPOSURE
IN LABORTORY ANIMALS CAUSED MILD, REVERSIBLE LIVER EFFECTS.
Explanation of Carcinogenicity:BASED ON THE AVAILABLE INFORMATION, THIS
MATERIAL CANNOT BE CLASSIFIED WITH REGARD TO CARCINOGENICITY. THIS
MATERIAL IS NOT LISTED AS A CARCINOGEN BY THE INTERNATIONAL AGCNCY
FOR RESEARCH ON CANCER, N ATIONAL TOXICOLOGY PROGRAM, OR
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION.
Effects of Overexposure:EYES: IRRITATION, STINGING, TEARING, REDNESS,
SWELLING. SKIN: IRRITATION, REDNESS, BURNING, DRYING AND CRACKING
OF SKIN, SKIN BURNS. INGESTION/INHALATION: STOMACH OR INTESTINAL
UPSET (NAUSEA, VOMITING , DIARRHEA), IRRITATION (NOSE, THROAT,
AIRWAYS), CENTRAL NERVOUS SYSTEM DEPRESSION (DIZZINESS, DROWSINESS,
WEAKNESS, FATIGUE, NAUSEA, HEADACHE, UNCONSCIOUSNESS), LOW BLOOD
PRESSURE, MILD, TEMPORARY C HANGES IN LIVER, EFFECTS ON HEART RATE,
RESPIRATORY DEPRESSION (SLOWING OF BREATHING RATE), LOSS OF
COORDINATION, CONFUSION, LUNG EDEMA (FLUID BUILDUP IN THE LUNG
TISSUE), KIDNEY DAMAGE, COMA.
Medical Cond Aggravated by Exposure:PREEXISTING DISORDERS OF THE
FOLLOWING ORGANS (OR ORGAN SYSTEMS) MAY BE AGGRAVATED BY EXPOSURE
TO THIS MATERIAL: SKIN, LUNG (FOR EXAMPLE, ASTHMA-LIKE CONDITIONS),
KIDNEY.
======================= First Aid Measures =======================
Eyes: FLUSH EYES GENTLY WITH WATER FOR 15 MINUTES WHILE
HOLDING EYELIDS APART; SEEK MEDICAL ATTENTION. SKIN: REMOVE
CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH SOAP AND WATER. IF
SYMPTOMS PERSIST, S EEK MEDICAL ATTENTION. LAUNDER CLOTHING BEFORE
REUSE. SWALLOWING: SEEK MEDICAL ATTENTION. DO NOT GIVE ANYTHING BY
MOUTH TO UNCONSCIOUS OR DROWSY PERSON. PLACE INDIVIDUAL ON LEFT
SIDE WITH HEAD DOWN. C ONTACT PHYSICIAN OR MEDICAL FACILITY FOR
ADVICE ABOUT WHETHER TO INDUCE VOMITING. INHALATION: MOVE TO FRESH
AIR. SEEK MEDICAL ATTENTION. IF NOT BREATHING GIVE ARTIFICAL
RESPIRATION. IF BREATHING IS DI FFICULT, GIVE OXYGEN.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:=11.7C, 53.F
Autoignition Temp:=398.9C, 750.F
Lower Limits:2.0
Upper Limits:12.0
Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WATER MAY BE INEFFECTIVE. WATER MAY BE USED TO
KEEP FIRE-EXPOSED CONTAINERS COOL UNTIL FIRE IS OUT. WEAR A SELF
CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE OPERATED IN THE
POSITIVE PRESSURE DE MAND MODE WITH APPROPRIATE TURN-OUT GEAR AND
CHEMICAL RESISTANT PERSONAL PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:VAPORS HEAVIER THAN AIR AND MAY TRAVEL
ALONG GROUND OR MAY BE MOVED BY VENTILATION AND IGNITED BY DISTANT
IGNITION SOURCES. NEVER USE WELDING OR CUTTING TORCH ON OR NEAR
DRUM (EVEN EMPTY) BECAUSE PRO DUCT (EVEN JUST RESIDUE) CAN IGNITE
EXPLOSIVELY.
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL SPILL: ABSORB ON VERMICULITE, OTHER
ABSORBENT. LARGE SPILL: ELIMINATE IGNITION SOURCES. STOP SPILL.
PREVENT FROM ENTERING DRAINS, SEWERS, STREAMS OR BODIES OF WATER.
PREVENT SPREADING. IF RUNOFF OCCURS, NOTIFY AUTHORITIES AS
REQUIRED. PUMP OR VACUUM SPILLTO CLEAN CONTAINERS FOR RECOVERY.
ABSORB RESIDUE. TRANSFER CONTAMINATED ABSORBENTS, SOIL AND OTHER
MATERIALS TO CONTAINERS FOR DISPOSAL.
Neutralizing Agent:NONE PROVIDED BY MFR.
====================== Handling and Storage ======================
Handling and Storage Precautions:EMPTY CONTAINERS OF THIS MATERIAL MAY
BE HAZARDOUS, RETAINING RESIDUES (VAPOR, LIQUID, AND/OR SOLID). ALL
PRECAUTIONS GIVEN IN DATA SHEET MUST BE OBSERVED. ALL 5-GAL PAILS
AND LARGER METAL CONTAINERS, INCLUDING TANK CARS AND TANK TRUCKS,
SHOULD BE GROUNDED AND/OR BONDED WHEN MATERIAL IS TRANSFERRED.
Other Precautions:SUDDEN RELEASE OF HOT ORGANIC VAPORS OR MISTS FROM
PROCESS EQUIPMENT OPERATING AT ELEVATED TEMP. AND PRESS., OR SUDDEN
INGRESS OF AIR INTO VACUUM EQUIPMENT, MAY RESULT IN AUTOIGNITION.
USE OF THIS PRO DUCT IN ELEVATED TEMP. PROCESSES SHOULD BE
THOROUGHLY EVALUATED TO ESTABLISH AND MAINTAIN SAFE OPER ATING
CONDITIONS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF WORKPLACE EXPOSURE LIMIT(S) OF PRODUCT OR ANY
COMPONENT IS EXCEEDED, A NIOSH/MSHA APPROVED AIR SUPPLIED
RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL.
OSHA REGULATIONS ALSO PERMI T OTHER NIOSH/MSHA RESPIRATORS
(NEGATIVE PRESSURE TYPE) UNDER SPECIFIED CONDITIONS. ENGINEERING
CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERALAND/OR LOCAL EXHAUST)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:WEAR RESISTANT GLOVES TO PREVENT REPEATED OR
PROLONGED SKIN CONTACT.
Eye Protection:CHEMICAL SPLASH GOGGLES
Other Protective Equipment:WEAR IMERVIOUS CLOTHING AND BOOTS TO PREVENT
REPEATED OR PROLONGED SKIN CONTACT.
Work Hygienic Practices:NONE PROVIDED BY MFR.
Supplemental Safety and Health
NONE PROVIDED BY MFR.
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:=82.2C, 180.F
B.P. Text:@ 760MMHG
Melt/Freeze Pt:=-88.7C, -128.F
Decomp Temp:Decomp Text:C/CE. PLEASE FILL OUT THI
Vapor Pres:20.8 MMHG @ 68F
Vapor Density:2.07(AIR=1
Volatile Org Content %:100
Spec Gravity:.789 @ 60F(6.58 LBS/GAL
pH:NO DATA
Viscosity:2.4 CPS
Evaporation Rate & Reference:7.70 (ETHYL ETHER)
Solubility in Water:100%
Appearance and Odor:TRANSPARENT LIQUID, CLEAR COLOR, SLIGHT ETHANOL/
ACETONE-LIKE ODOR
Percent Volatiles by Volume:100
Corrosion Rate:NONE PROVIDED BY MFR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH: ACETALDEHYDE, ACIDS, CHLORINE, ETHYLENE OXIDE,
ISOCYANATES, STRONG OXIDIZING AGENTS. DO NOT USE ALUMINUM EQUIPMENT
ABOVE 120F.
Stability Condition to Avoid:DO NOT USE WITH ALUMINUM EQUIPMENT AT
TEMPERATURES ABOVE 120F.
Hazardous Decomposition Products:MAY FORM: CARBON DIOXIDE AND CARBON
MONOXIDE.
Conditions to Avoid Polymerization:PRODUCT WILL NOT UNDERGO HAZARDOUS
POLYMERIZATION.
=================== Toxicological Information ===================
Toxicological Information:EXPOSURE GUIDELINES: ISOPROPANOL (57-63-0):
OSHA VPEL 400.000 PPM - TWA; OSHA VPEL 500.00 PPM - STEL; ACGIH TLV
400.000 PPM - TWA; ACGIH TLV 500.000 PPM - STEL.
===================== Ecological Information =====================
Ecological:NO DATA.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
LOCAL, STATE, AND FEDERAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:DOT OMFORMATION - 49 CFR 172.101: ISOPROPANOL,
CLASS 3, UN 1219, PKG I I. CONTAINER/MODE: 55 GAL DRUM/ TRUCK
PACKAGE. RQ (REPORTABLE QUANTITY - 49 CFR 172.101: NOT APPLICABLE.
===================== Regulatory Information =====================
SARA Title III Information:SARA 302 COMPONENTS - 40 CFR 355 APPENDIX A:
NONE. SECTION 311/312 HAZARD CLASS - 40 CFR 370-Z: IMMEDIATE;
DELAYED; FIRE. SARA 313 COMPONENTS - 40 CFR 372.65: NONE
Federal Regulatory Information:TSCA (TOXIC SUBSTANCES CONTROL ACT)
STATUS: TSCA (UNITED STATES) THE INTENTIONAL INGREDIENTS OF THIS
PRODUCT ARE LISTED. CERCLA RQ - 40 CFR 302.4(A): NONE LISTED.
State Regulatory Information:CALIFORNIA PROPOSITION 65: NONE. NEW
JERSEY RTK LABEL INFORMATION: ISOPROPYL ALCOHOL, 67-63-0.
PENNSYLVANIA RTK LABEL INFORMATION: 2-PROPANOL, 67-63-0.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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