===================== Product Identification =====================
MSDS NAME:HYPOCHLORITE SOLUTION A.K.A. SODA BLEACH SOLUTION
NIIN:00-169-5163
Status Code:A
MSDS Number: CKTNR
=== Responsible Party ===
Company:KREVIT H CO INC
Address:73 WELTON STREET
Box:9433
City:NEW HAVEN
State:CT
ZIP:06534
Country:US
Info Phone Num:203-772-3350
Emergency Phone Num:(800)424-9300
Resp. Party Other MSDS Num.:0236
Chemtrec Ind/Phone:(800)424-9300
CAGE:66894
=== Contractor Identification ===
Company:COMPTECH CORP
Address:15944 DERWOOD RD
Box:City:ROCKVILLE
State:MD
ZIP:20855
Country:US
Phone:800-284-5279; 301-519-3401
Contract Num:SP0450-01-M-D146
CAGE:0BR38
Company:INDUSTRIAL CHEMICAL COMMODITIES INC
Address:15944 DERWOOD RD
Box:City:ROCKVILLE
State:MD
ZIP:20855
Country:US
Phone:800-284-5279
Contract Num:SP0450-00-M-SJ34
CAGE:1ELU0
Company:KREVIT H CO INC
Address:73 WELTON STREET
Box:9433
City:NEW HAVEN
State:CT
ZIP:06534
Country:US
Phone:203-772-3350
CAGE:66894
============= Composition/Information on Ingredients =============
Name:SODIUM HYPOCHLORITE (AS AVAIL.CHLORINE)
CAS:7681-52-9
RTECS #:NH3486300
Minumum % Wt:5.
Maxumum % Wt:15.
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Name:SODIUM HYDROXIDE
CAS:1310-73-2
RTECS #:WB4900000
= Wt:1.
OSHA PEL:2 MG/M3
ACGIH STEL:C2 MG/M3
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: BALANCE
===================== Hazards Identification =====================
LD50 LC50 Mixture:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: INHALATION OF MIST OR
FUMES CAN CAUSE BRONCHIAL IRRITATION, COUGH, DIFFICULT BREATHING,
INFLAMMATION OF THE MOUTH, NAUSEA, AND IN SEVERE EXPOSURES,
PULMONARY EDEMA. EYE/SKIN: LIQUEFIED CON TACT CAN PRODUCE
IRRITATION OF THE SKIN WITH BLISTERING AND EXEMA. DIRECT CONTACT
WITH EYES MAY CAUSE REDNESS, PAIN AND IN THE CASE OF CONCENTRATE
HYPOCHLORITE (15%) PERMANENT DAMAGE. INGESTION: INGES TION OF A FEW
OUNCES CAN CAUSE CORROSION OF MUCOUS MEMBRANES. SWELLING OF THE
THROAT , PERFORATION OF THE ESOPHAGUS AND STOMACH, VOMITING,
COLITIC HYPOTENSION AND CIRCULATORY COLLAPSE. MAY LEAD TO CON
VULSIONS, COMA OR DEATH.
Explanation of Carcinogenicity:THE CARCINOGENIC POTENTIAL OF SODIUM
HYPOCHLORITE WAS STUDIED IN F344 RATS. AFTER 104 WEEKS OF DRINKING
WATER CONTAINING 2000 PPM OF SODIUM HYPOCHLORITE, THERE WAS NO
EVIDENCE THAT THIS CHEMICAL PRODU CED ANY CARCINOGENIC RESPONSE. IN
ADDITION, THIS EXPOSURE DID NOT RESULT IN ANY ADVERSE EFFECTS IN
BLOOD, CLINICAL CHEMISTRY OR OTHER TARGET ORGANS.
Effects of Overexposure:INHALATION: BRONCHIAL IRRITATION, COUGH,
DIFFICULT BREATHING, INFLAMMATION OF THE MOUTH, NAUSEA, AND IN
SEVERE EXPOSURES, PULMONARY EDEMA. EYE/SKIN: LIQUEFIED CONTACT CAN
PRODUCE IRRITATION OF THE SKI N WITH BLISTERING AND EXEMA. DIRECT
CONTACT WITH EYES MAY CAUSE REDNESS, PAIN AND IN THE CASE OF
CONCENTRATE HYPOCHLORITE (15%) PERMANENT DAMAGE. INGESTION:
INGESTION OF A FEW OUNCES CAN CAUSE CORROSI ON OF MUCOUS MEMBRANES.
SWELLING OF THE THROAT , PERFORATION OF THE ESOPHAGUS AND STOMACH,
VOMITING, COLITIC HYPOTENSION AND CIRCULATORY COLLAPSE. MAY LEAD TO
CONVULSIONS, COMA OR DEATH.
Medical Cond Aggravated by Exposure:NONE KNOWN.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. CALL A PHYSICIAN. EYE OR SKIN: FLUSH EYES &
SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING
CONTAMINATED CLOTHING & SHOES. IF IRRITATION OCCURS, CONSULT A
PHYSICIAN. THOROUGHLY CLEAN CLOTHING & SHOES BEFORE REUSE OR
DISCARD. INGESTION: IF CONSCIOUS: DRINK LARGE QUANTITIES OF WATER.
DO NOT INDUCE VOMITING. TAKE IMMEDIATELY TO A HOSPITAL OR
PHYSICIAN. IF UNCONSCIOUS, OR IN CONVULSIONS: TAKE IMMEDIATELY TO A
HOSPITAL DO NOT GIVE ANYTHI NG BY MOUTH TO AN UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point:NON-FLAMMABLE
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR NIOSH/MSHA APPROVED
PRESSURE-DEMAND, SELF CONTAINED BREATHING APPARATUS. USE WATER
SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:CAN DECOMPOSE TO FORM IRRITATING CHLORINE
GAS AND OXYGEN.
================== Accidental Release Measures ==================
Spill Release Procedures:IMMEDIATELY EVACUATE THE AREA AND PROVIDE
MAXIMUM VENTILATION. UNPROTECTED PERSONNEL SHOULD MOVE UPWING OF
SPILL. ONLY PERSONNEL EQUIPPED WITH PROPER RESPIRATORY AND SKIN/EYE
PROTECTION SHOULD BEPERMI TTED IN AREA. DIKE AREA TO CONTAIN SPILL.
TAKE PRECAUTIONS AS NECESSARY TO PREVENT CONTAMINATION OF GROUND
AND SURFACE WATERS.
Neutralizing Agent:NO DATA PROVIDED BY RESPONSIBLE PARTY.
====================== Handling and Storage ======================
Handling and Storage Precautions:HANDLING: WHEN HANDLING, WEAR GLOVES,
SAFETY GOGGLES AND RESPIRATORY PROTECTION. STORAGE: STORE IN A
COOL, DRY, WELL-VENTILATED AREA. AVOID EXCESSIVE STORAGE
TEMPERATURES AND DIRECT SUNLIGHT. STORE AW AY FROM ACIDS AND
ORGANICS. STORE ONLY IN CLOSED, PROPERLY LABELED CONTAINERS.
Other Precautions:AVOID CONTACT WITH EYES AND SKIN. MAY CAUSE BURNS TO
EYES AND SKIN. AVOID INHALATION OF VAPORS, MISTS AND FUMES. USE
WITH ADEQUATE VENTILATION. VENTILATION MUST BE SUFFICIENT TO
MINIMIZE EMPLOYEE EXPO SURE TO SODIUM HYPOCHLORITE. WASH THOROUGHLY
AFTER HANDLING. DO NOT SWALLOW. DO NOT EAT, DRINK OR SM OKE IN WORK
AREA.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USA A HALF OR FULL FACEPIECE ACID GAS CHEMICAL
CARTRIDGE RESPIRATOR WHEN EXPOSURES TO SODIUM HYPOCHLORITE ARE
LIKELY. AN APPROPRIATE PARTICULATE PRE-FILTER IS ALSO REQUIRED WHN
MISTS ARE PRESENT. SIMI LAR PROTECTION SHOULD BE WORN WHILE
CLEANING UP SPILLS OR LEAKS IF IRRITATION OCCURS. RESPIRATORS MUST
BE APPROVED BY NIOSH OR MSHA.
Ventilation:USE LOCAL OR GENERAL VENTILATION TO MINIMIZE EMPLOYEE
EXPOSURES AS NECESSARY.
Protective Gloves:NEOPRENE OR NITRIL GLOVES.
Eye Protection:SPLASH-PROOF CHEMICAL GOGGLES.
Other Protective Equipment:USE RUBBER/PLASTIC BOOTS, APRON OR CHEMICAL
SUITS WHEN NECESSARY TO PREVENT SKIN CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
RESPIRATOR: THE RESPIRATOR USE LIMITATIONS MADE BY NIOSH/MSHA AND BY
THE MANUFACTURER MUST BE OBSERVED.
================== Physical/Chemical Properties ==================
HCC:B1
Boiling Pt:B.P. Text:DECOMPOSES
Melt/Freeze Pt:=-14.C, 6.8F
Vapor Pres:17.5 MM HG @20 C
Spec Gravity:1.21 @ 20 C
pH:13 APPROX
Evaporation Rate & Reference:1 (WATER=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, PALE YELLOW OR GREENISH LIQUID WITH A
CHLORINE ODOR.
Percent Volatiles by Volume:COMPLETE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID MIXING WITH ACIDS (LIBERATES CHLORINE), AMMONIA, UREA, OXIDIZING
MATERIALS, AND METALS SUCH AS NICKEL, COPPER, TIN, MAGANESE AND
IRON (WHICH CAUSE LIBERATION OF OXYGEN).
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:IN A FIRE, SODIUM HYPOCHLORITE MAY
DECOMPOSE PRODUCING IRRITATING CHLORINE GAS AND OXYGEN.
=================== Toxicological Information ===================
Toxicological Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.
===================== Ecological Information =====================
Ecological:NO DATA PROVIDED BY RESPONSIBLE PARTY.
==================== Disposal Considerations ====================
Waste Disposal Methods:H. KREVIT & COMPANY, INC. RECOMMENDS DISPOSAL IN
AN APPROVED HAZARDOUS WASTE MANAGEMENT FACILITY. CARE MUST BE TAKEN
WHEN USING OR DISPOSING OF CHEMICAL MATERIALS AND/OR THEIR
CONTAINERS TO PREVENT EN VIRONMENTAL CONTAMINATION. DISPOSE OF THE
CHEMICAL MATERIALS AND/OR THEIR CONTAINERS IN ACCORDANCE W ITH ALL
REGULATIONS REGARDING DISPOSAL.
=================== MSDS Transport Information ===================
Transport Information:US DOT SHIPPING NAME: HYPOCHLORITE SOLUTION. US
DOT HAZARD CLASS: CORROSIVE MATERIAL. SUBSIDIARY RISK: N/A. ID
NUMBER: UN1791. REPORTABLE QUANTITY (RQ): 100 LBS/45.4 KG. CANADIAN
DANGEROUS GOODS DESCR IPTION - SHIPPING NAME: HYPOCHLORITE
SOLUTION. PRINARY CLASSIFICATION: CLASS 8, SUBSIDIARY CLASS: 9.2.
PIN NUMBER: UN1791, PACKING GROUP III.
===================== Regulatory Information =====================
SARA Title III Information:SARA TITLE III A) SECTION 311/312
CATAGORIES: ACUTE & REACTIVITY; B) NOT LISTED IN SECTION 313; C)
NOT LISTED AS AN "EXTREMELY HAZARDOUS SUBSTANCE" IN SECTION 302.
Federal Regulatory Information:CERCLA: LISTED IN TABLE 302.4 OF 40 CFR
PART 302 AS A HAZARDOUS SUBSTANCE WITH A REPORTABLE QUANTITY OF 100
POUNDS. RELEASES TO AIR, LAND OR WATER WHICH EXCEED THE RQ MUST BE
REPORTED TO THE NATIONAL RESPONSE CENTER, 1-800-424-8802. TSCA:
SODIUM HYPOCHLORITE IS ON THE TSCA INVENTORY UNDER CAS# 7681-52-9.
State Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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