===================== Product Identification =====================
MSDS NAME:129 2069,KODAK AERATION TEST SOLUTION
Status Code:A
MSDS Number: CKTPS
=== Responsible Party ===
Company:EASTMAN KODAK COMPANY
Address:343 STATE STREET
City:ROCHESTER
State:NY
ZIP:14650
Country:US
Info Phone Num:716-722-5151/(800) 242-2424
Emergency Phone Num:716 722-5151
Preparer's Name:NOT PROVIDED
CAGE:19139
=== Contractor Identification ===
Company:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS
Address:343 STATE ST
Box:City:ROCHESTER
State:NY
ZIP:14650-1115
Country:US
Phone:716-722-5151/(800) 242-2424
CAGE:19139
============= Composition/Information on Ingredients =============
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:85.
Maxumum % Wt:90.
Other REC Limits:NOT PROVIDED
Code:F
Code:F
Name:METHANOL
CAS:67-56-1
RTECS #:PC1400000
= Wt:11.
Other REC Limits:NOT PROVIDED
OSHA PEL:260 MG/M3;200 PPM
ACGIH TLV:262 MG/M3;200 PPM
ACGIH STEL:328 MG/M3;250 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:ACETIC ACID
CAS:64-19-7
RTECS #:AF1225000
< Wt:1.
Other REC Limits:NOT PROVIDED
OSHA PEL:25 MG/M3;10 PPM
ACGIH TLV:25 MG/M3;10 PPM
ACGIH STEL:37 MG/M3;15 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:SODIUM ACETATE
CAS:127-09-3
RTECS #:AJ4300010
< Wt:1.
Other REC Limits:NOT PROVIDED
OSHA PEL:NOT PROVIDED
ACGIH TLV:NOT PROVIDED
Name:1,10-PHENANTHROLINE
CAS:66-71-7
RTECS #:SF8300000
< Wt:1.
Other REC Limits:NOT PROVIDED
OSHA PEL:NOT PROVIDED
ACGIH TLV:NOT PROVIDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT PROVIDED
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: CONTAINS:
METHANOL. PROLONGED AND REPEATED EXPOSURE TO HIGH VAPOR
CONCENTRATIONS, SKIN ABSORPTION OR INGESTION OF METHYL ALCOHOL MAY
RESULT IN VISUAL DISTURBANCES, METABOLIC ACID OSIS, HEADACHE,
GIDDINESS, NAUSEA, INSOMNIA, GASTRIC DISTURBANCE, DIZZINESS, AND
SLOW BREATHING. THERE HAVE BEEN SEVERAL CASES REPORTED OF
BLINDNESS, COMA AND DEATH DUE TO THE INGESTION OF METHYL ALCO HOL.
INHALATION: HARMFUL IF INHALED. EYES: CAUSES IRRITATION. VAPOR
IRRITATING. SKIN: HARMFUL IF ABSORBED THROUGH SKIN. CAUSES
IRRITATION. INGESTION: POISON. MAY BE FATAL OR CAUSE BLINDNESS IF
SWALLOW ED. CANNOT BE MADE NONPOISONOUS.
Explanation of Carcinogenicity:INTERNATIONAL AGENCY FOR RESEARCH ON
CANCER (IARC): NONE AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL
HYGIENISTS (ACGIH): NONE NATIONAL TOXICOLOGY PROGRAM (NTP): NONE
OCCUPATIONAL SAFETY AND HEALT H ADMINISTRATION (OSHA): NONE
Effects of Overexposure:PROLONGED AND REPEATED EXPOSURE TO HIGH VAPOR
CONCENTRATIONS, SKIN ABSORPTION OR INGESTION OF METHYL ALCOHOL MAY
RESULT IN VISUAL DISTURBANCES, METABOLIC ACIDOSIS, HEADACHE,
GIDDINESS, NAUSEA, INSOMN IA, GASTRIC DISTURBANCE, DIZZINESS, AND
SLOW BREATHING. THERE HAVE BEEN SEVERAL CASES REPORTED OF
BLINDNESS, COMA AND DEATH DUE TO THE INGESTION OF METHYL ALCOHOL.
INHALATION: HARMFUL IF INHALED. EYES : CAUSES IRRITATION. VAPOR
IRRITATING. SKIN: CAUSES IRRITATION.
Medical Cond Aggravated by Exposure:NOT PROVIDED
======================= First Aid Measures =======================
First Aid:INHALATION: MOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET
MEDICAL ATTENTION. EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR
AT LEAST 1 5 MINUTES. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST.
SKIN: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. GET MEDICAL
ATTENTION IF SYMP TOMS OCCUR. INGESTION: CALL A PHYSICIAN OR POISON
CONTROL CENTER IMMEDIATELY. INDUCE VOMITING AS DIRECTED BY MEDICAL
PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
ONLY INDUCE VOMIT ING AT INSTRUCTION OF MEDICAL PERSONNEL.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:=53.9C, 129.F
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE (CO2), DRY CHEMICAL,
ALCOHOL FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL. FLASH POINT: 54?C (129?F) SETAFLASH CLOSED CUP.
60.6?C (141?F) SETAFLASH CLOSED CUP, AFTER EVAPORATED 10% OR 4
HOURS
Unusual Fire/Explosion Hazard:CLASSIFIED AS COMBUSTIBLE. MATERIAL
CONTAINS A COMBUSTIBLE SOLVENT THAT MAY ACCUMULATE IN THE CONTAINER
HEADSPACE.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. ABSORB SPILL
WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN A CONTAINER
FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL
CONTAMINATION.
Neutralizing Agent:NOT RELEVANT
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED. KEEP AWAY FROM
FOOD, DRINK AND ANIMAL FEEDING STUFFS. KEEP AWAY FROM INCOMPATIBLE
SUBSTANCES. KEEP FROM CONTACT WITH OXIDIZING MATERIALS. KEEP AWAY
FROM HEAT AND FLAME.
Other Precautions:AVOID BREATHING VAPOR AT CONCENTRATIONS GREATER THAN
THE EXPOSURE LIMITS. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING.
USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE
CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, AN APPROVED
RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: FULL-FACE
POSITIVE-PRESSURE AIR-SUPPLIED. IF RE SPIRATORS ARE USED, A PROGRAM
SHOULD BE INSTITUTED TO ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR
1910.134.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:WEAR IMPERVIOUS GLOVES AND PROTECTIVE CLOTHING
APPROPRIATE FOR RISK OF EXPOSURE
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE
LIMITS. NOTE TO PHYSICIANS: SYMPTOMS OF POISONING MAY NOT APPEA R
FOR SEVERAL HOURS. KEEP UNDER MEDICAL SUPERVISION FOR AT LEAST 48
HOURS.
================== Physical/Chemical Properties ==================
HCC:F5
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:=65.C, 149.F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:(68F): 49 MBAR (38 MM HG)
Vapor Density:.8
Spec Gravity:0.98
pH:5
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:NOT PROVIDED
Solubility in Water:COMPLETE
Appearance and Odor:BLUE LIQUID. ODOR: NOT AVAILABLE.
Percent Volatiles by Volume:95-100 WT
Corrosion Rate:NOT PROVIDED
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS
Stability Condition to Avoid:NOT PROVIDED
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE
=================== Toxicological Information ===================
Toxicological Information:TOXICOLOGICAL PROPERTIES OF
1,10-PHENANTHROLINE HAVE NOT BEEN INVESTIGATED. CONTAINS METHANOL.
EXPOSURE TO HIGH VAPOR CONCENTRATIONS, SKIN ABSORPTION OR INGESTION
OF METHYL ALCOHOL MAY RESULT IN VISUA L DISTURBANCES, METABOLIC
ACIDOSIS, HEADACHE, GIDDINESS, NAUSEA, INSOMNIA, GASTRIC
DISTURBANCE, DIZZINESS, SLOW BREATHING, BLINDNESS, COMA AND DEATHL.
DATA FOR METHANOL: ORAL LD-50 (RAT): 6.2 G/KG. DE RMAL LD-50: 20
ML/KG. INHALATION LC-50 (RAT): >22,500 PPM/8 HOUR(S). SKIN
IRRITATION: MODERATE. EYE IRRITATION: SLIGHT TO MODERATE. DATA FOR
1,10-PHENANTHROLINE:ORAL LD-50 (RAT):100 MG/KG. DERMAL LD-5 0: >
1.0 G/KG. SKIN IRRITATION: SLIGHT
===================== Ecological Information =====================
Ecological:FISH LC50 MG/L: >100. DAPHNID EC50 MG/L:
>100. ALGAL IC50 MG/L: >100. ORGANICS
READILY DEGRADABLE (>70%): YES (7 DAYS). POTENTIAL BIOACCUMULATION:
LO G POW <1. COD (APPROXIMATE G/L): 170. BOD5 (APPROXIMATE
G/L): 130. WASTE TREATMENT MICROORGANISMS EC50 (MG/L):
>100
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL IS SUBJECT TO
NATIONAL, STATE, OR LOCAL LAWS. INCINERATE. SINCE EMPTIED
CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS EVEN AFTER
CONTAINER IS EMPTIED.
=================== MSDS Transport Information ===================
Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME),
MONDAY THROUGH FRIDAY .
===================== Regulatory Information =====================
SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART
372: METHANOL
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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