===================== Product Identification =====================
MSDS NAME:86-1281, 86-1285; ETHANOL, 95% (SEE SUPP)
Status Code:A
MSDS Number: CKTRL
=== Responsible Party ===
Company:CAROLINA BIOLOGICAL SUPPLY CO
Address:2700 YORK RD
City:BURLINGTON
State:NC
ZIP:27215-3387
Country:US
Info Phone Num:800-227-1150
Emergency Phone Num:800-227-1150
Chemtrec Ind/Phone:(800)424-9300
CAGE:59896
=== Contractor Identification ===
Company:CAROLINA BIOLOGICAL SUPPLY CO
Address:2700 YORK RD
Box:City:BURLINGTON
State:NC
ZIP:27215-3387
Country:US
Phone:800-227-1150/910-584-0381
Contract Num:MDA414-00-P-1174
CAGE:59896
Company:CAROLINA BIOLOGICAL SUPPLY CO
Address:2700 YORK RD
Box:City:BURLINGTON
State:NC
ZIP:27215-3387
Country:US
Phone:800-227-1150/910-584-0381
Contract Num:MDA414-00-P-4815
CAGE:59896
Company:CAROLINA BIOLOGICAL SUPPLY CO
Address:2700 YORK RD
Box:City:BURLINGTON
State:NC
ZIP:27215-3387
Country:US
Phone:800-227-1150/910-584-0381
Contract Num:MDA414-00-P-4816
CAGE:59896
============= Composition/Information on Ingredients =============
Name:ETHYL ALCOHOL (ETHANOL)
CAS:64-17-5
RTECS #:KQ6300000
Minumum % Wt:88.
Maxumum % Wt:95.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM; 9596
Name:METHANOL (SARA 313) (CERCLA)
CAS:108-10-1
RTECS #:SA9275000
= Wt:5.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM
ACGIH TLV:200 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT) IS 7,060 MG/KG (ETHANOL)
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS: EYES, LIVER, KIDNEYS,
NERVES. ACUTE: CONCENTRATIONS BELOW 1,000 PPM USUALLY PRODUCE NO
SIGNS OF INTOXICATION. EXPOSURE TO CONCENTRATIONS OVER 1,000 PPM
MAY CAUSE HEADACHE, IRRITATION OF THE EYES, NOSE, AND THROAT, AND
IF CONTINUED FOR AN HOUR, DROWSINESS AND LASSITUDE, LOSS OF
APPPETITE AND INABILITY TO CONCENTRATE.
Explanation of Carcinogenicity:NOT LISTED AS CAUSING CANCER BY IARC,
NTP, OR OSHA.
Effects of Overexposure:CONCENTRATIONS BELOW 1,000 PPM USUALLY PRODUCE
NO SIGNS OF INTOXICATION. EXPOSURE TO CONCENTRATIONS OVER 1,000 PPM
MAY CAUSE HEADACHE, IRRITATION OF THE EYES, NOSE AND THROAT, AND IF
CONTINUED FOR AN HOUR, DROWSINESS AND LASSITUDE, LOSS OF APPETITE
AND INABILITY TO CONCENTRATE.
Medical Cond Aggravated by Exposure:PRE-EXISTING CONDITIONS OF THE
SKIN, EYES, THROAT, LIVER.
======================= First Aid Measures =======================
Eyes: FLUSH WITH WATER FOR 15 MINUTES, RAISING AND LOWERING
EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION IF IRRITATION PERSISTS.
SKIN: REMOVE CONTAMINATED CLOTHES. WASH EXPOSED SKIN AREA
THOROUGHLY FO R AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IF
IRRITATION PERSISTS. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
INHALATION: MOVE TO FRESH AIR. GIVE OXYGEN IF BREATHING IS
DIFFICULT. GIVE ARTIFICIAL R ESPIRATION IF BREATHING HAS STOPPED.
GET MEDICAL ATTENTION. INGESTION: IF CONSCIOUS, GIVE PLENTY OF
WATER. GET IMMEDIATE MEDICAL ATTENTION OR CALL POISON CONTROL FOR
ASSISTANCE. NEVER GIVE ANYTHINNG B Y MOUTH TO AN UNCONSCIOUS
PERSON.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:>13.C, 55.4F
13-16C
Lower Limits:3.3 ETHANOL
Upper Limits:19 ETHANOL
Extinguishing Media:USE DRY CHEMICAL, CARBON DIOXIDE OR
ALCOHOL-RESISTANT FOAM. WATER MAY BE INEFFECTIVE.
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE
EQUIPMENT AND NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:EXTREMELY FLAMMABLE. VAPORS ARE HEAVIER
THAN AIR AND CAN TRAVEL DISTANCES TO IGNITION SOURCES AND FLASH
BACK.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA OF SPILL. ELIMINATE ALL SOURCES
OF IGNITION. CONTAIN SPILLED MATERIAL. DILUTE TO NONFLAMMABLE
MIXTURE WITH WATER. VENTILATE THE SPILL AREA. CONTAIN AND COLLECT
FOR DISPOSAL.
====================== Handling and Storage ======================
Handling and Storage Precautions:THIS MATERIAL SHOULD BE KEPT IN AN
AREA SUITABLE FOR STORAGE OF FLAMMABLE LIQUIDS. BOND AND GROUND
CONTAINERS WHEN TRANSFERRING LIQUID.
Other Precautions:KEEP OXIDIZING MATERIALS AND STRONG ACIDS AWAY. WEAR
SPLASH PROOF CHEMICAL SAFETY GOGGLES AND RUBBER GLOVES AT ALL TIMES
DURING CLEANUP PROCESS. TAKE CARE IN HANDLING EMPTY CONTAINERS AS
RESIDUE CAN P RESENT FIRE AND EXPLOSION HAZARDS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A NIOSH/MSHA CHEMICAL CARTRIDGE RESPIRATOR
SHOULD BE WORN IF PEL OR TLV IS EXCEEDED.
Ventilation:LOCAL EXHAUST- FOR HIGH CONCENTRATIONS. MECHANICAL
(GENERAL) VENTILATION - REQUIRED. SPECIAL -. EXPLOSION PROOF IF
WITHIN EXPLOSION LIMITS.
Protective Gloves:RUBBER, NEOPRENE, PVC OR EQUIVALENT.
Eye Protection:SPLASH PROOF CHEMICAL SAFETY GOGGLES SHOULD BE WORN AT
ALL TIMES.
Other Protective Equipment:LAB COAT, EYE WASH STATION AND SAFETY
SHOWER.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
95% ETHANOL / PART# 86-1281, 500ML. ALSO, 15-4708A, 15-4708CA,
15-4724A, 89-2301, 89-2305, 19-1184, 19-1176, 15-4725, 19-1177,
76-6200, 86-1281, 86-1283, 86-1285, 84-1135, 10-1026, 10-1036,
84-0887.
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:=78.C, 172.4F
B.P. Text:ETHANOL
Vapor Pres:44 MMHG ETHANOL
Vapor Density:1.6 ETHANO
Spec Gravity:0.79-0.81
Evaporation Rate & Reference:5.9 (BUAC=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR LIQUID WITH ALCOHOL ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS. IN ADDITION, METHANOL MAY ATTACK SOME FORMS OF
PLASTIC.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:TO THE BEST OF OUR KNOWLEDGE, THE
TOXICOLOGICAL PROPERTIES OF THIS MIXTURE HAVE NOT BEEN THOROUGHLY
EVALUATED. DATA IS LISTED FOR INDIVIDUAL COMPONENTS. ETHANOL:
ORL-RAT LD50: 7060 MG/KG; IHL-RAT LC5 0: 20000 PPM/10H. METHANOL:
ORL-RAT LD50: 5628 MG/KG; IHL-RAT LC560: 64000 PPM/4H. EFFECTS OF
OVEREXPOSURE: CHRONIC: ETHYL ALCOHOL: MUTATION DATA CITED.
REPRODUCTIVE EFFECTS DATA CITED. TURMORIGENIC DATA CITED.
===================== Ecological Information =====================
Ecological:EPA WASTE NUMBERS: ETHANOL(D001): METHANOL (U154).
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL REGULATIONS. ALWAYS CONTACT A PERMITTED
WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE.
=================== MSDS Transport Information ===================
Transport Information:ETHANOL SOLUTIONS, 3, UN1170, II.
===================== Regulatory Information =====================
SARA Title III Information:HAZARD CATEGORY FOR SARA SECTION 311/312
REPORTING: ACUTE, FIRE. SARA SECTION 313 CHEMICALS: METHANOL.
Federal Regulatory Information:CERCLA SEC. 103 RQ LBS: 5000, METHANOL.
RCRA SEC. 261.33: YES, METHANOL. EPA TSCA STATUS: ON TSCA
INVENTORY.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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