===================== Product Identification =====================
MSDS NAME:AQUAMICRON AX
Status Code:A
MSDS Number: CKTRF
=== Responsible Party ===
Company:MITSUBISHI CHEMICAL CORPORATION
Address:5-2 MARUNOUCHI 2-CHOME
City:CHIYODA-KU, TOKYO 100
ZIP:11111-1111
Country:JA
Info Phone Num:(914) 286-3600
Emergency Phone Num:(800) 424-9300
Resp. Party Other MSDS Num.:310
Chemtrec Ind/Phone:(800)424-9300
CAGE:TO731
=== Contractor Identification ===
Company:MITSUBISHI CHEMICAL AMERICA
Address:ONE NORTH LEXINGTON AVENUE
Box:City:WHITE PLAINS,
State:NY
ZIP:10601
Country:US
Phone:(914) 286-3600
CAGE:TO764
Company:MITSUBISHI CHEMICAL CORPORATION
Address:5-2 MARUNOUCHI 2-CHOME
Box:City:CHIYODA-KU, TOKYO 100
ZIP:11111-1111
Country:JA
Phone:(914) 286-3600
CAGE:TO731
============= Composition/Information on Ingredients =============
Name:METHANOL
CAS:67-56-1
RTECS #:PC1400000
Other REC Limits:(OTHER INFO)
OSHA PEL:262 MG/M3;200 PPM
OSHA STEL:NONE ESTAB.
ACGIH TLV:262 MG/M3;200 PPM
ACGIH STEL:328 MG/M3;250 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:PROPYLENE CARBONATE
CAS:108-32-7
RTECS #:FF9650000
Name:DIETHANOLAMINE
CAS:111-42-2
RTECS #:KL2975000
Other REC Limits:(OTHER INFO)
OSHA PEL:NONE ESTABLISHED
OSHA STEL:NONE ESTABLISHED
ACGIH TLV:2 MG/M;0.46 PPM
ACGIH STEL:NONE ESTABLISHED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:SULFUR DIOXIDE
CAS:7446-09-5
RTECS #:WS4550000
Other REC Limits:(OTHER INFO)
OSHA PEL:5 MG/M;2 PPM
OSHA STEL:5PPM;13MG/M
ACGIH TLV:5 MG/M;2 PPM
ACGIH STEL:13 MG/M;5 PPM
Name:IODINE. (IODIDE)
CAS:7553-56-2
RTECS #:NN1575000
Other REC Limits:(OTHER INFO)
OSHA PEL:C1 MG/M3;C0.1 PPM
ACGIH STEL:C1.0 MG/M3;C0.1 PPM
Name:1,3-DIMETHYL-2-IMIDAZOLIDINONE
CAS:80-73-9
Name:1,3-DI-(4-PYRIDYL)PROPANE
CAS:17252-51-6
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LDLO (RAT) 2000 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:PRIMARY ENTRY ROUTES: INHALATION,
ABSORPTION. TARGET ORGANS: RESPIRATORY TRACT, CENTRAL NERVOUS
SYSTEM, SKIN AND EYES. ACUTE EFFECTS:INHALATION: IRRITATION,
RINGING IN EARS, DIGESTIVE DISORDERS & VISU AL DISTURBANCES. MAY
ALSO CAUSE SOME OFTHE EFFECTS LISTED FOR INGESTION. EYES:
IRRITATION, EYE DAMAGE. SKIN: IRRIT. MAY ALSO CAUSE SOME OF THE
EFFECTS LISTED FOR INGESTION. INGEST: NAUSEA, VOMITING, DIARRHEA,
DIFF BREATHING, IRREGULAR HEARTBEAT, HEADACHE, DROWSINESS, SYMPTOMS
OF DRUNKENNESS, DISORIENTATION, HEARING LOSS, BLINDNESS, BLUISH
SKIN COLOR, LUNG CONGESTION, NERVE DAMAGE, CONVULSIONS, CO MA.
CHRONIC EFFECTS: NONE NOTED.
Explanation of Carcinogenicity:IARC, NTP, AND OSHA DO NOT LIST
AQUAMICRON AX AS A CARCINOGEN.
Effects of Overexposure:RESPIRATORY TRACT IRRIT, SKIN IRRIT, EYE IRRIT
AND CENTRAL NERVOUS DEPRESSION.
Medical Cond Aggravated by Exposure:MEDICAL CONDITIONS AGGRAVATED BY
LONG-TERM EXPOSURE: EYE DISORDERS, KIDNEY DISORDERS, SKIN
DISORDERS, RESPIRATORY DISORDERS AND HORMONAL DISORDERS.
======================= First Aid Measures =======================
First Aid:INHALATION: PROTECT YOURSELF WITH APPROPRIATE PPE, REMOVE
EXPOSED PERSON TO FRESH AIR, DECONTAMINATE & ASSIST BREATHING AS
NEEDED. EYE CONTACT: DO NOT ALLOW VICTIM TO RUB OR KEEP EYES
TIGHTLY SHUT. GE NTLY LIFT EYELIDS & FLUSH IMMEDIATELY &
CONTINUOUSLY W/FLOODING AMOUNTS OF WATER FOR 15-20 MINUTES & THEN
TRANSPORT TO AN EMERGENCY MEDICAL FACILITY. SEEK EMERGENCY CARE
IMMEDIATELY. SKIN CONTACT: REM OVE CONTAIMINATED CLOTHING. RINSE
WITH FLOODING AMOUNTS OF WATER FOR AT LEAST 15-20 MINUTES. WASH
EXPOSED AREA WITH SOAP & WATER. (ECOLOGICAL).
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:=13.5C, 56.3F
Lower Limits:NONE REPORT
Upper Limits:NONE REPORT
Extinguishing Media:ALCOHOL RESISTANT FOAM, CARBON DIOXIDE, REGULAR DRY
CHEMICAL, WATER. FIRE-FIGHTING EQUIPMENT: BECAUSE FIRE MAY PRODUCE
TOXIC THERMAL DECOMPOSITION PRODUCTS, WEAR A (REG. SARA/FED).
Fire Fighting Procedures:FLAMMABILITY CLASSIFICATION: 1B. MOVE
CONTAINER FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. COOL
CONTAINERS WITH WATER SPRAY UNTIL WELL AFTER THE FIRE IS OUT. FLOOD
WITH FINE WATER SPRAY. DO NOT S CATTER SPILLED MATERIAL WITH
HIGH-PRESSURE WATER SPRAY. AVOID INHALATION OF MATERIAL (REG.
STATE)
Unusual Fire/Explosion Hazard:HIGHLY FLAMMABLE: WILL BE EASILY IGNITED
BY HEAT, SPARKS OR FLAMES. VAPORS MAY FORM EXPLOSIVE MIXTURES WITH
AIR. VAPORS MAY TRAVEL TO SOURCE OF IGNITION & FLASH BACK. MOST
VAPORS ARE HEAVIER THAN AIR. THEY WILL SPREAD ALONG GROUND &
COLLECT IN LOW OR CONFINED AREAS (SEWERS, BASEMENTS, TANKS). (REG.
STATE)
================== Accidental Release Measures ==================
Spill Release Procedures:KEEP UNNECESSARY PEOPLE AWAY, ISOLATE HAZARD
AREA & DENY ENTRY. STAY UPWIND & AND KEEP OUT OF LOW AREAS.
ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS OR
FLAMES IN IMMEDIATE AREA). ALL EQ UIPMENT USED WHEN HANDLING THE
PRODUCT MUST BE GROUNDED. DO NOT TOUCH OR WALK THROUGH SPILLED
MATERIAL. STOP LEAK IF YOU CAN DO IT WITHOUT RISK. PREVENT ENTRY
INTO (OTHER INFO)
Neutralizing Agent:CHEM/PHYS DATA: ODOR THRESHOLD, FORM WT, DENSITY,
OTHER SOLUBILITIES, REFRACT IND, & SURFACE TENS: NOT AVAIL.
====================== Handling and Storage ======================
Handling and Storage Precautions:HANDLING PRECAUTIONS: GROUND & BOND
WHEN TRANSFERRING. USE ONLY IN WELL-VENTILATED AREAS. DO NOT BREATH
VAPOR. AVOID CONTACT WITH EYES, SKIN OR CLOTHES. USE PROPER
PERSONAL PROTECTIVE EQUIPMENT (PPE). STORAGE REQUIREMENTS: STORE
IN A COOL (RECOMMENDED: 59-77C), (REGULATORY STATE).
Other Precautions:WASTE DISPOSAL: WASTE & ALL APPLICABLE FED, STATE &
LOCAL REGS SHOULD BE FOLLOWED. CONTAINER CLEANING & DISPOSAL:
EMPTY CONTAINER SHOULD COMPLY W/REQUIREMENTS OF 40 CFR 261.7 PRIOR
TO DISPOSAL OR R EUSE. AVOID EXPOS TO RESIDUAL MATL & COMPLY W/ALL
FED, STATE AND LOCAL LAWS & REGS CONCERNING SOLID WASTE &
CONTAINERS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SEEK PROFESSIONAL ADVICE PRIOR TO RESP SELECTION
& USE. FOLLOW OSHA RESPR REGS (29 CFR 1910.134) &, IF NECESSARY,
WEAR A NIOSH-APPROVED RESP. SELECT RESP BASED ON ITS SUITABILITY TO
PROVIDE ADEQUATE W ORKER PROTECTION FOR GIVEN WORKING CONDTN, LEVEL
OF AIRBORNE CONTAM, & PRESENCE OF SUFFICIENT OXYG. FOR EMERGENCY OR
NONROUTINE (SEE SARA/FED REGS)
Ventilation:PROVIDE GENERAL OR LOCAL EXHAUST VENTILATION SYSTEMS TO
MAINTAIN AIRBORNE CONCENTRATIONS BELOW OSHA PELS. LOCAL EXHAUST
VENTILATION (FED REG)
Protective Gloves:WEAR CHEMICALLY PROTECTIVE GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES AND FULL
FACESHIELD . (FED REG)
Other Protective Equipment:WEAR CHEMICALLY PROTECTIVE BOOTS, APRONS, &
GAUNTLETS TO PREVENT PROLONGED/REPEATED SKIN CONTACT.
EYEWASH/DELUGE SHOWER MEETING ANSI DESIGN CRITERIA
Work Hygienic Practices:NEVER EAT, DRINK, OR SMOKE IN WORK AREAS.
PRACTICE GOOD PERSONAL HYGIENE AFTER USING THIS MATERIAL,
ESPEACIALLY BEFORE EATING, DRINKING, SMOKING, USING THE TOILET, OR
APPLYING COSMETICS.
Supplemental Safety and Health
SAFETY STATIONS: MAKE EMERGENCY EYEWASH STATIONS, SAFETY/QUICK-DRENCH
SHOWERS, AND WASHING FACILITIES AVAILABLE IN WORK AREA.
CONTAMINATED EQUIPMENT: SEPARATE CONTAMINATED WORK CLOTHES FROM
STREET CLO THES. LAUNDER BEFORE REUSE. REMOVE THIS MATERIAL FROM
YOUR SHOES & CLEAN PERSONAL PROTECTIVE EQUIPMENT.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:NOT AVAILABLE
Melt/Freeze Pt:M.P/F.P Text:NOT AVAILABLE
Vapor Pres:NOT AVAILABLE
Vapor Density:NOT AVAIL
Spec Gravity:(AT 20C): 0.957
pH:NOT AVAILABLE
Viscosity:2.16 CP (14C)
Evaporation Rate & Reference:NOT AVAILABLE
Solubility in Water:SOLUBLE
Appearance and Odor:YELLOWISH, CLEAR LIQUID. FAINT ODOR. (SEE
NEUTRALIZING AGENT)
Percent Volatiles by Volume:NOT AVAILBLE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CHEMICAL INCOMPATIBILITIES: INDIVIDUALLY THE CONSTITUENTS OF AQUAMICRON
AX ARE INCOMPATIBLE WITH A NUMBER OF CHEMICAL COMPOUNDS. USES OTHER
THAN THOSE FOR WHICH AQUAMICRON AX IS PRODUCED SHOULD BE EVALUATED
TO DETERMINE WH
Stability Condition to Avoid:HEATING, OPEN FLAMES, IGNITION SOURCES.
AQUAMICRON AX IS STABLE AT ROOM TEMPERATURE IN CLOSED CONTAINERS
UNDER NORMAL STORAGE AND HANDLING CONDITIONS FOR AT LEAST TWO
YEARS.
Hazardous Decomposition Products:THERMAL OXIDATIVE DECOMPOSITITION CAN
PRODUCE CARBON MONOXIDE, SULFUR OXIDES, NITROGEN OXIDES. MATERIALS
TO AVOID: ADDITIONAL PROCESSES AND CHEMICAL SUBSTANCES ARE
COMPATIBLE WITH AQUAMICRON AX.
Conditions to Avoid Polymerization:HAZARDOUS POLYMERIZATION CANNOT
OCCUR.
=================== Toxicological Information ===================
Toxicological Information:METHANOL:IRRIT DATA. EYE:(RABBIT) 100 MG/2411
MODERATE. SKIN:(RABBIT) 20 MG/24H MODERATE. ACUTE TOX:ORAL LD50
(RAT) 5.63 G/KG. ORAL LDLO (HUMAN) 143 MG/KG. INHAL LCLO (HUMAN)
300MG/M3. REPROD EFFECTS: REPROD EFFECTS REPORTED IN ANIMALS. SEE
NIOSH, RTECS (PC1400000), FOR ADD'L TOX DATA. PROPYLENE
CARBONATE:IRRIT DATA: EYE:(RABBIT) 60 MG SEV. SKIN:(RABBIT) 500 MG
MODERATE. ACUTE TOX:ORAL LD50 (RAT) 2 9 G/KG.
1,3-DIMETHYL-2-IMIDAZOLIDINONE: IRRIT DATA: EYE:(RABBIT) 100 MG
SEVERE. ACUTE TOX:ORAL LD50 (RAT) 1.19 G/KG. SKIN LD50 (RABBIT) 930
L/KG. SEE NIOSH, RTECS (NJ0660000), FOR ADD'L TOX DATA. (CO NTACT
NEHC FOR ADD'L TOX INFO, )
===================== Ecological Information =====================
Ecological:ECOTOXICITY:NOT REPORTED (N/R). ENVIR FATE:N/R. ENVIR
DEGRADATION:METHANOL, PROPYLENE CARBONATE & DIETHANOLAMINE IS
READILY BIODEGRADABLE. SOIL ABSORPTION/MOBILITY:N/R. FIRST AID:
FOR REDDENED SKIN O THER THAN FROM WASHING,CONSULT PHYSICIAN.
INGESTION:NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS OR
CONVULSING PERSON. CONTACT POISON CTRL CENTER (PCC). UNLESS PCC
ADVISES OTHERWISE, GIVE CONSCIOUS/ ALERT PERSON 1 TO 2 GLASSES OF
WATER. INDUCE VOMITING ONLY AFTER RECENT INGESTIONS DUE TO POSS OF
SEIZURES. AFTER FIRST AID, GET APPROP MEDICAL SUPT. SPECIAL
PRECAUTIONS/PROCEDURES: WHEN TREATING CONT AM VICTIMS, USE APPROP
PPE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL: CONTACT AN ENVIR PROFESSIONAL OR
LICENSED CONTRACTOR FOR DETAILED RECOMMEND. FOLLOW APPLICABLE FED,
STATE, & LOCAL REGS. DISPOSAL REG REQUIREMENTS: IF PROD BECOMES A
WASTE, IT MEETS THE CRI TERIA OF A HAZ WASTE DEFINED IN 40 CFR 261
FOR IGNITABILITY (D001). IF PROD BECOMES A WASTE AFTER I NTENDED
USE, IT COULD BECOME A HAZ (OTHER PREC).
=================== MSDS Transport Information ===================
Transport Information:D.O.T. TRANSPORTATION DATA (49 CFR 172.101):
SHIPPING NAME: FLAMMABLE LIQUID, TOXIC N.O.S. (CONTAINS METHYL
ALCOHOL). SHIPPING SYMBOLS: NONE. HAZARD CLASS: 3. SUBSIDIARY
HAZARD: 6.1. ID NO: UN1992. PA CKING GROUP: II. LABEL: 3.6.1
(SUBSIDIARY LABEL). SPECIAL PROVISIONS (172.102): T18. PACKAGING
AUTHORIZATIONS: (A) EXCEPTIONS: NONE (B) NON-BULK PACKAGING:
173.202 (C) BULK PACKAGING: 173.243. QUANTIT Y LIMITATIONS: (A)
PASSENGER, AIRCRAFT, OR RAILCAR: 1L (B) CARGO AIRCRAFT ONLY: 60L.
VESSEL STOWAGE REQUIREMENTS: (A) VESSEL STOWAGE: B. (B) OTHER :40.
===================== Regulatory Information =====================
SARA Title III Information:EXTINQ. MEDIA: SELF-CONTAINED BREATHING
APPARATUS (SCBA) WITH A FULL FACEPIECE OPERATED IN PRESSURE-DEMAND
OR POSITIVE-PRESSURE MODE. RESPIRATORY PROT: OPERATIONS (CLEANING
SPILLS, REACTOR VESSELS, OR STORAGE TANKS), WEAR AN SCBA. WARNING!
AIR-PURIFYING RESPIRATORS DO NOT PROTECT WORKERS IN
OXYGEN-DEFICIENT ATMOSPHERES. IF RESPIRATORS ARE USED, OSHA
REQUIRES A WRITTEN RESPIRATORY PROTECTION PROGR AM THAT INCLUDES
AT LEAST: MEDICAL CERTIFICATION, TRAINING, FIT-TESTING, PERIODIC
ENVIRONMENTAL MONITORING, MAINTENANCE, INSPECTION, CLEANING, &
CONVENIENT, SANITARY STORAGE AREAS.
Federal Regulatory Information:(CONTACT NEHC FOR REGULATORY INFO, ).
VENTILATION REQ: IS PREFERRED BECAUSE IT PREVENTS CONTAMINANT
DISPERSION INTO THE WORK AREA BY CONTROLLING IT AT ITS SOURCE.
VENTILATION EQUIPMENT SHOULD BE E XPLOSION-RESISTANT IF EXPLOSIVE
CONCENTRATIONS OF MATERIAL ARE PRESENT. EYE PROTECTION: WEAR
PROTECTIVE CHEMICAL SAFETY GOGGLES, PER OSHA EYE - AND
FACE-PROTECTION REGULATIONS (29 CFR 1910.133). CONTA CT LENSES ARE
NOT EYE PROTECTIVE DEVICES. APPROPRIATE EYE PROTECTION MUST BE WORN
INSTEAD OF, OR IN CONJUNCTION WITH CONTACT LENSES.
State Regulatory Information:HANDLING AND STORAGE: DARK,
WELL-VENTILATED AREA. TIGHTLY CLOSED. KEEP AWAY FROM SOURCES OF
IGNITION OR HEAT. STORAGE MUST COMPLY WITH THE REQUIRMENTS OF 29
C.F.R. 1910.106. REGULATORY REQUIREMENTS: F OLLOW ALL APPLICABLE
LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS. FIRE FIGHTING
PROCEDURES: OR COMBUSTION BY-PRODUCTS. STAY UPWIND AND KEEP OUT OF
LOW AREAS. DO NOT RELEASE RUNOFF FROM FIRE CONTROLS METHODS TO
SEWERS OR WATERWAYS. UNUSAL FIRE HAZARD/EXPLOSION: VAPOR EXPLOSION
HAZARD INDOORS, OUTDO ORS OR IN SEWERS. RUNOFF TO SEWER MAY CREATE
FIRE OR EXPLOSION HAZARD. CONTAINERS MAY EXPLODE WHEN HEATED.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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