===================== Product Identification =====================
MSDS NAME:139 0913,A,EKTACOLOR PRIME BLEACH FIX (SEE SUPPL DATA)
NIIN:01-387-7805
Status Code:A
Kit Part:Y
MSDS Number: CKTSP
=== Responsible Party ===
Company:EASTMAN KODAK COMPANY
Address:343 STATE STREET
City:ROCHESTER
State:NY
ZIP:14650
Country:US
Info Phone Num:716-722-5151/(800) 242-2424
Emergency Phone Num:716 722-5151
Preparer's Name:NOT PROVIDED
CAGE:19139
=== Contractor Identification ===
Company:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS
Address:343 STATE ST
Box:City:ROCHESTER
State:NY
ZIP:14650-1115
Country:US
Phone:716-722-5151/(800) 242-2424
CAGE:19139
============= Composition/Information on Ingredients =============
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:55.
Maxumum % Wt:60.
Other REC Limits:NOT PROVIDED
Code:F
Code:F
Name:AMMONIUM THIOSULFATE
CAS:7783-18-8
RTECS #:XN6465000
= Wt:30.
Other REC Limits:NOT PROVIDED
OSHA PEL:NOT PROVIDED
ACGIH TLV:NOT PROVIDED
Name:SODIUM BISULFITE
CAS:7631-90-5
RTECS #:VZ2000000
Minumum % Wt:5.
Maxumum % Wt:10.
Other REC Limits:NOT PROVIDED
OSHA PEL:NOT PROVIDED
ACGIH TLV:5 MG/M3
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:AMMONIUM BISULFITE
CAS:10192-30-0
RTECS #:WT3595000
= Wt:1.
Other REC Limits:NOT PROVIDED
OSHA PEL:NOT PROVIDED
ACGIH TLV:NOT PROVIDED
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:AMMONIUM SULFITE
CAS:10196-04-0
= Wt:1.
Other REC Limits:NOT PROVIDED
OSHA PEL:NOT PROVIDED
ACGIH TLV:NOT PROVIDED
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT PROVIDED
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: EXPECTED LOW HAZARD FOR
RECOMMENDED HANDLING. IN CONTACT WITH STRONG ACIDS OR HEATED,
SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE GAS IS
IRRITATING TO RESPIRATORY TRACT. ASTHM ATICS OR HYPERSENSITIVE
INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES
IRRITATION. SKIN: MATERIAL HAS LOW POTENTIAL TO CAUSE ALLERGIC SKIN
REACTIONS; CASES OF HUMAN SKIN SENSITIZATION RE PORTED. INGESTION:
MAY BE HARMFUL IF SWALLOWED. ASTHMATICS OR SULFITE-SENSITIVE
INDIVIDUALS MAY EXPERIENCE WHEEZING, CHEST TIGHTNESS, STOMACH
UPSET, HIVES, FAINTNESS, WEAKNESS AND DIARRHEA. MAY CAUSE
IRRITATION OF GASTROINTESTINAL TRACT.
Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION
(COMPONENTS PRESENT AT 0.1% OR MORE): - INTERNATIONAL AGENCY FOR
RESEARCH ON CANCER (IARC): NONE - AMERICAN CONFERENCE OF
GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): NON E - NATIONAL
TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION (OSHA): NONE
Effects of Overexposure:INHALATION: IN CONTACT WITH STRONG ACIDS OR
HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE
GAS IS IRRITATING TO RESPIRATORY TRACT. ASTHMATICS OR
HYPERSENSITIVE INDIVIDUALS MAY EXPERI ENCE DIFFICULT BREATHING.
EYES: CAUSES IRRITATION. INGESTION: ASTHMATICS OR SULFITE-SENSITIVE
INDIVIDUALS MAY EXPERIENCE WHEEZING, CHEST TIGHTNESS, STOMACH
UPSET, HIVES, FAINTNESS, WEAKNESS AND DIARRH EA. MAY CAUSE
IRRITATION OF GASTROINTESTINAL TRACT.
Medical Cond Aggravated by Exposure:SOME ASTHMATICS, HYPERSENSITIVE OR
SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING,
WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS,
WEAKNESS AND DIARRHEA.
======================= First Aid Measures =======================
First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTEN TION IF SYMPTOMS OCCUR. SKIN: WASH WITH SOAP AND
WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. INGESTION: DRINK
1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION. NEVER GIVE ANYTHING
BY MOUTH TO AN UNCO NSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:FLOOD WITH WATER.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:SOLUTION CONTAINS A STRONG REDUCING
AGENT. DRIED PRODUCT RESIDUE CAN ACT AS A REDUCING AGENT.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NOT PROVIDED
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED TO
PREVENT THE LOSS OF WATER. KEEP FROM CONTACT WITH OXIDIZING
MATERIALS, HIGHLY OXYGENATED OR HALOGENATED SOLVENTS, ORGANIC
COMPOUNDS CONTAINING REDUCIBLE FUNCTIONAL GRO UPS.
Other Precautions:AVOID BREATHING MIST OR VAPOR. AVOID CONTACT WITH
EYES AND PROLONGED OR REPEATED CONTACT WITH SKIN. USE WITH ADEQUATE
VENTILATION. WASH THOROUGHLY AFTER HANDLING. DO NOT STORE OR SHIP
TOGETHER WITH CO MBUSTIBLE MATERIAL. STORE IN ORIGINAL
CONTAINER.KEEP AWAY FROM INCOMPATIBLE SUBSTANCES
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED. A RESPIRATOR SHOULD BE
WORN IF HAZARDOUS DECOMPOSITION PRODUCTS ARE LIKELY TO BE OR HAVE
BEEN RELEASED. RESPIRATOR TYPE: ACID GAS. SEE STABILITY AND
REACTIVITY SECTION. IF RESP IRATORS ARE USED, A PROGRAM SHOULD BE
INSTITUTED TO ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:FOR PROLONGED OR REPEATED SKIN CONTACT: IMPERVIOUS
GLOVES SHOULD BE WORN.
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
Other Protective Equipment:EYE BATH, SAFETY SHOWER, WASHING FACILITIES
Work Hygienic Practices:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE SKIN CONTACT.
Supplemental Safety and Health
CONTINUED FROM PRODUCT ID: AND REPLENISHER. A = PART A.
================== Physical/Chemical Properties ==================
HCC:N1
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:(68F):24 MBAR 18 MM HG
Vapor Density:0.6
Spec Gravity:1.23
pH:5.3
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:NOT PROVIDED
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS LIQUID. ODOR: AMMONIA
Percent Volatiles by Volume:55-60 WT
Corrosion Rate:NOT PROVIDED
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, STRONG OXIDIZING AGENTS, COMBUSTIBLE MATERIAL,
HALOGENATED MATERIALS, BASES, SODIUM HYPOCHLORITE (BLEACH). CONTACT
WITH BASE LIBERATES FLAMMABLE MATERIAL.
Stability Condition to Avoid:NOT PROVIDED
Hazardous Decomposition Products:AMMONIA, SULFUR DIOXIDE, CHLORAMINE,
CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF NITROGEN, OXIDES OF
SULFUR.
=================== Toxicological Information ===================
Toxicological Information:INHALATION: EXPECTED LOW HAZARD FOR
RECOMMENDED HANDLING. IN CONTACT WITH STRONG ACIDS OR HEATED,
SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE GAS IS
IRRITATING TO RESPIRATORY TRACT. ASTHM ATICS OR HYPERSENSITIVE
INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES
IRRITATION. SKIN: MATERIAL HAS LOW POTENTIAL TO CAUSE ALLERGIC SKIN
REACTIONS; CASES OF HUMAN SKIN SENSITIZATION RE PORTED. INGESTION:
MAY BE HARMFUL IF SWALLOWED. ASTHMATICS OR SULFITE-SENSITIVE
INDIVIDUALS MAY EXPERIENCE WHEEZING, CHEST TIGHTNESS, STOMACH
UPSET, HIVES, FAINTNESS, WEAKNESS AND DIARRHEA. MAY CAUSE
IRRITATION OF GASTROINTESTINAL TRACT.
===================== Ecological Information =====================
Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS
OF THE PREPARATIONS. POTENTIAL TOXICITY: FISH LC50 MG/L: >100.
DAPHNID EC50 MG/L: >100. ALGAL IC50 MG/L: NOT AVAILABLE.
ORGANICS READ ILY DEGRADABLE (>70%): YES (7 DAYS). POTENTIAL
BIOACCUMULATION: LOG POW <1. COD (APPROXIMATE G/L): 190. BOD5
(APPROXIMATE G/L): 160. POTENTIAL TOXICITY: WASTE TREATMENT
MICROORGANISMS EC50 (MG/L) : NOT AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS E VEN AFTER CONTAINER IS EMPTIED.
=================== MSDS Transport Information ===================
Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD
TIME), MONDAY THROUGH FR IDAY.
===================== Regulatory Information =====================
SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR
PART 372: AMMONIUM THIOSULFATE, AMMONI UM SULFITE, AMMONIUM
BISULFITE (AS CHEMICAL SOURCE OF AQUEOUS AMMONIA)
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE
(METAL)
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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